• Journal of Electrochemical Science and Technology
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• v.1 no.2
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• pp.121-126
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• 2010

An amperometric ascorbic acid selective sensor utilizing the transfer reaction of proton liberated from the dissociation of ascorbic acid in aqueous solution across an elliptic micro-hole water/organic gel interface is demonstrated. This redox inactive sensing platform offers an alternative way for the detection of ascorbic acid to avoid a fouling effect which is one of the major concerns in redox based sensing systems. The detection principle is simply measuring the current change with respect to the assisted transfer of protons by a proton selective ionophore (e.g., ETH 1778) across the micro-hole interface between the water and the polyvinylchloride-2-nitrophenyloctylether gel phase. The assisted transfer reaction of protons generated from ascorbic acid across the polarized micro-hole interface was first characterized using cyclic voltammetry. An improved sensitivity for the quantitative analysis of ascorbic acid was achieved using differential pulse stripping voltammetry with a linear response ranging from 1 to $100\;{\mu}M$ concentrations of ascorbic acid. As a demonstration, the developed sensor was applied for analyzing the content of vitamin-C in different types of commercial pharmaceutical tablets and syrups, and a satisfactory recovery from these samples were also obtained.

• Rapid Communication in Photoscience
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• v.4 no.4
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• pp.88-90
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• 2015

The design and development of fluorescent chemosensors have recently been intensively explored for sensitive and specific detection of environmentally and biologically relevant metal ions in aqueous solution and living cells. Herein, we report the photophysical results of rhodamine B based fluorogenic and chromogenic receptor for selective copper detection in the complete organic or mixed aqueous-organic media at neutral pH under ambient condition. The ligand exhibited the remarkable increment in the fluorescence emission and UV-visible absorption signal intensities at 587 and 547 nm, respectively, on induction of copper ion while the ligand solution remain completely silent on addition of varieties of other metal ions.

• Bulletin of the Korean Chemical Society
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• v.23 no.3
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• pp.481-487
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• 2002

A selective enzyme-linked immunosorbent assay (ELISA) for the insecticide chlorpyrifos was developed. Four haptens for chlorpyrifos were synthesized and two of them were used as immunogens after coupling to keyhole limpet hemocyanin by two differe nt approaches. Rabbits were immunized with either of them and the sera were screened against 4 haptens coupled to ovalbumin (OVA). Using the sera of highest specificity, an antigencoated ELISA was developed, which shows an I50 of 160 ppb with a detection limit of 10 ppb. An antibody-coated ELISA was also developed, which shows an $I_{50}$ of 20 ppb with a detection limit of 0.1 ppb. The antibodies showed negligible cross-reactivity with other organophosphorus pesticides except for insecticides chlorpyrifos-methyl and bromophos-ethyl, which makes these assays suitable for the selective detection of chlorpyrifos.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.540-540
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• 2012

Selective detection of single nucleotide polymorphism (SNP) of Cytochrome P450 2C19 (CYP2C19) was carried out by the PNA chips which were electrically-interfaced with interdigitated nanogap electrodes (INEs). The INEs whose average gap distance and effective gap length were about ~70 nm and ${\sim}140{\mu}m$, respectively, were prepared by the combination of the photo lithography and the surface-catalyzed chemical deposition, without using the e-beam lithography which is almost inevitable in the conventional lab-scale fabrication of the INEs. Four different types of target DNAs were successfully detected and discriminated by the INE-based PNA chips.

• Bulletin of the Korean Chemical Society
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• v.23 no.4
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• pp.599-603
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• 2002

A selective enzyme-linked immunosorbent assay (ELISA) for the insecticide isofenphos was developed. Three different analogues (haptens) of isofenphos were synthesized and were coupled to carrier proteins through the pesticide thiophosphate group t o use as immunogens or coating antigens. Rabbits were immunized with one of the haptens coupled to BSA for production of polyclonal antibodies and the sera were screened against each of the other two haptens coupled to ovalbumin (OVA). Using the sera of highest specificity, an antigen-coated ELISA was developed, which showed an I50 of 96 ng/mL with the detection limit of 2 ng/mL. The antibodies showed negligible cross-reactivity with other organophosphorus pesticides and the phenol metabolite of isofenphos, which makes the developed assay suitable for the selective detection of isofenphos. An antibody-coated ELISA was also developed, which showed an I50 of 580 ng/mL with a detection limit of 70 ng/mL.

• Journal of the Institute of Electronics and Information Engineers
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• v.53 no.6
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• pp.15-20
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• 2016

In this paper, we consider selective mapping (SLM) based OFDM systems without side information, where SLM is one of the promising peak-to-average power ratio (PAPR) reduction techniques due to its simplicity and no distortion in the transmitted signal. First, we construct a new phase sequence where a part of phase sequence is replaced by an orthogonal sequence. Based on the proposed phase sequence, we propose a new scheme for detecting coherently the index of the phase sequence used in transmitter without side information. Computer simulation shows that the proposed detection scheme performs well in SLM-based OFDM systems, and specifically outperforms the existing ones when channel variation is relatively small between sub-carriers used in phase sequence detection.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.31 no.12A
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• pp.1198-1204
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• 2006

In this paper, we extend SVR-MMSE detection scheme which is proposed in MIMO system to MIMO-OFDM system, and evaluate performance of the system in frequency selective fading channel. First of all, we explain about typical MIMO-OFDM system and detection scheme of constant modulus signals in this system. And compare proposed SVR-MMSE with Zero Forcing, Minimum Mean Square Error which is conventional detection scheme. we identify that the performance of the proposed system is shown different by varying doppler frequency in frequency selective fading channel using jakes channel model. The result of detection performance by the proposed SVR-MMSE in this simulation, it shows that proposed algorithm have a good performance in MIMO-OFDM systems.

• Journal of Communications and Networks
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• v.14 no.5
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• pp.501-509
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• 2012

This paper proposes a joint timing synchronization, channel estimation, and data detection for the impulse radio ultra-wideband systems. The proposed timing synchronizer consists of coarse and fine timing estimation. The synchronizer discovers synchronization points in two stages and performs adaptive threshold based on the maximum pulse averaging and maximum (MAX-PA) method for more precise synchronization. Then, iterative channel estimation is performed based on the discovered synchronization points, and data are detected using the selective rake (S-RAKE) detector employing maximal ratio combining. The proposed synchronizer produces two signals-the start signal for channel estimation and the start signal for start frame delimiter (SFD) detection that detects the packet synchronization signal. With the proposed synchronization, channel estimation, and SFD detection, an S-RAKE receiver with binary pulse position modulation binary phase-shift keying modulation was constructed. In addition, an IEEE 802.15.4a channel model was used for performance comparison. The comparison results show that the constructed receiver yields high performance close to perfect synchronization.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.30 no.7A
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• pp.628-638
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• 2005

The analysis of maximum diversity order and coding gain for multiple-input multiple-output orthogonal frequency division multiplexing (MIMO-OFDM) systems over time-and frequency-selective (or doubly-selective) channels is addressed in this paper. A novel channel time-space correlation function is developed given the spatially correlated doubly-selective Rayleigh fading channel model. Based on this channel-model assumption, the upper-bound of pairwise error probability (PEP) for MIMO-OFDM systems is derived under the maximum likelihood (ML) detection. For a certain space-frequency code, we quantify the maximum diversity order and deduce the expression of coding gain. In this wort the impact of channel time selectivity is especially studied and a new definition of time diversity is illustrated correspondingly

• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.571-574
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• 2008

The well-known Cu2+-selective chemodosimetric behavior of rhodamine B hydrazide was successfully switched to selectivity for Hg2+. The fluorescence signaling is remarkably selective toward Hg2+ ions compared to other common biologically and environmentally important metal ions, including Cu2+ ions. The detection limit was 0.2 mM in an acetate-buffered aqueous 10% methanol solution at pH 5. The OFF-ON type of signaling is due to the selective Hg2+-induced hydrolysis of the lactam ring of the hydrazide as has been reported for the standard Cu2+-signaling process of the same compound. A simple change in medium resulted in clear switching of selective signaling from Cu2+ to Hg2+, which extends the applicability of the easily accessible hydrazide derivative.