• Title/Summary/Keyword: secondary phase

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Solution-based fabrication of germanium sulphide doped with or without Li ions for solid electrolyte applications

  • Jin, Byeong Kyou;Cho, Yun Gu;Shin, Dong Wook;Choi, Yong Gyu
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.110-113
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    • 2012
  • Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

Operational Characteristics in integrated Three-Phase a Flux-Lock type SFCL according to Fault Conditions (3상 일체화된 자속구속형 전류제한기의 동작특성)

  • Lee, Na-Young;Choi, Hyo-Sang;Jeong, Soo-Bok;Lee, Sang-Il;Nam, Gueng-Hyun;Lim, Sung-Hun
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2006.05a
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    • pp.467-470
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    • 2006
  • Superconducting fault current(SFCLs) are expected to improve not only reliability but also stability of real power systems. The analysis on the single line-to-ground fault current of the integrated three phase flux-lock type SFCL, which consists of three flux-lock reactor wound on an iron core in each single phase and three YBCO thin films, was investigated in current limiting operating characteristics. We compared additive polarity winding with the subtractive one in the flux lock reactor. Its turns ratio each phase between the primary and the secondary coils is 63:42. When a single line-to-ground fault occurred in any phase, the peak value of line current in the fault phase of the additive polarity winding increased up to 31.44[A] during first-half cycle. On the other hand, the peak value in the subtractive polarity winding increased up to 81.77[A] under the same conditions. This is because the current flow between the primary and the secondary windings becomes to be additive or subtractive in each winding direction. We confirmed that the current limiting behavior in the additive polarity winding was more effective for a single-line-to ground fault.

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Characteristic of fuel Cell DC-AC Inverter Using New Active Clamping Method (새로운 능동 클램핑방식을 이용한 연료전지용 DC-AC 인버터의 특성)

  • Kim, C.Y.;Cho, M.C.;Mun, S.P.;Kim, Y.J.;Nakaoka, Mutsuo;Kim, H.S.
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.11a
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    • pp.337-340
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    • 2007
  • In the dissertation, a power conversion system for fuel cell is composed of a PWM inverter with LC filter in order to convert fuel cell voltage to a single phase 220[V], In addition, new insulated DC-DC converters are proposed in order that fuel cell voltage is boosted to 380[V]. In this paper, it requires smaller components than existing converters, which makes easy control. The proposed DC-DC converter controls output power by the adjustment of phase-shift width using switch S5 and S6 in the secondary switch, which provides 93-97[%] efficiency in the wide range of output voltage. Fuel cell simulator is implemented to show similar output characteristics to actual fuel cell. Appropriate dead time td enables soft switching to the range where the peak value of excitation current in a high frequency transformer is in accordance with current in the primary circuit. Moreover, appropriate setting to serial inductance La reduces communication loss arisen at light-load generator and serge voltage arisen at a secondary switch and serial diode. Finally, TMS320C31 board and EPLD using PWM switching technique to act a single phase full-bridge inverter which is planed to make alternating current suitable for household.

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Piezoelectric Characteristics of PMW-PNN-PZT Ceramics according to Post-Annealing Process (Post annealing에 따른 PMW-PNN-PZT 세라믹스의 압전 특성)

  • Yoo, Kyung-Jin;Yoo, Ju-Hyun;Park, Chang-Yub;Lee, Hyung-Gyu;Kang, Hyung-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.212-213
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    • 2005
  • In this study, in order to develop low temperature sintering piezoelectric actuator, $Pb_{0.985}Bi_{0.01}(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.13}(Zr_{0.50},Ti_{0.50})_{0.84}$ (PMW-PNN-PZT) ceramic systems were fabricated using $CaCO_3-Li_2CO_3$, sintering aid through a post-annealing process. The sinterability of PMW-PNN-PZT ceranics was remarkably enhanced by liquid phase sintering of $CaCO_3$ and $Li_2CO_3$. But, it was confimed form the X-ray diffraction pattern that the secondary phase along grain boundaries, deteriorated the piezoelectric properties. The secondary phase along grain boundaries was significantly removed by annealing after sintering. The 0.2wt% $Li_2CO_3$-0.25wt% $CaCO_3$-added PMW-PNN-PZT ceramics post-annealed at 900$^{\circ}C$ for 90min exhibited the excellent electromechanical coupling factor($k_p$) of 63.3% and piezoelectric constant($d_{33}$) of 452pC/N, respectively, for multilayer piezoelectricactuatorapplication.

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Influences of Precipitation of Secondary Phase by Heat Treatment on Thermal Properties of Al-4.5%Cu Alloy (열처리에 따른 제2상 석출이 Al-4.5%Cu 합금의 열 물성에 미치는 영향)

  • Choi, Se-Weon
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.435-440
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    • 2020
  • The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al2Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.

Establishment of National Standard System for 20.000 A Current Transformer (20,000 A 전류변성기 국가표준 시스템 구축)

  • Jung, Jae-Kap;Lee, Sang-Hwa;Kang, Jean-Hong;Kim, Myung-Soo;Kim, Yoon-Hyoung;Han, Sang-Gil;Han, Sang-Ok
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.57 no.1
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    • pp.6-13
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    • 2008
  • National standard system for calibrating current transformer(CT) up to primary current of 20,000A have been established. The system consists of 20,000 A AC high current source, CT comparator, standard CT, CT under test and CT burden. An AC high current is applied tn the primary windings of both the standard CT and the CT under test, and then the CT comparator measures the ratio error and the phase displacement by comparing the secondary currents of the two transformers. As a validity check for 20,000 A CT calibration system, the comparison with the two national standard institutes(NMIs) has been performed using same CTs. The comparison results of the CTs are consistent with those measured at two NMIs within 0.004 % for ratio error and 0.1 min for phase displacement in the primary current ranges of Ip = 10 - 20,000 A with a secondary current of Is = 5 A.

A High-efficiency Method to Suppress Transformer Core Imbalance in Digitally Controlled Phase-shifted Full-bridge Converter

  • Yu, Juzheng;Qian, Qinsong;Sun, Weifeng;Zhang, Taizhi;Lu, Shengli
    • Journal of Power Electronics
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    • v.16 no.3
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    • pp.823-831
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    • 2016
  • A high-efficiency method is proposed to suppress magnetic core imbalance in phase-shifted full-bridge (PSFB) converters. Compared with conventional solutions, such as controlling peak current mode (PCM) or adding DC blocking capacitance, the proposed method has several advantages, such as lower power loss and smaller size, because the additional current sensor or blocking capacitor is removed. A time domain model of the secondary side is built to analyze the relationship between transformer core imbalance and cathode voltage of secondary side rectifiers. An approximate control algorithm is designed to achieve asymmetric phase control, which reduces the effects of imbalance. A 60 V/15 A prototype is built to verify the proposed method. Experimental results show that the numerical difference of primary side peak currents between two adjacent cycles is suppressed from 2 A to approximately 0 A. Meanwhile, compared with the PCM solution, the efficiency of the PSFB converter is slightly improved from 93% to 93.2%.

Contactless Power Transfer System using Voltage Phase (전압위상을 이용한 무접점 전원공급 시스템에 관한 연구)

  • Yu, Joo-Hee;Kim, Choon-Sam
    • The Transactions of the Korean Institute of Power Electronics
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    • v.16 no.3
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    • pp.219-226
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    • 2011
  • As the existing contactless power transfer system(CPTS) is adopting the principle of contactless transformer enables to supply power in contactless way using RFID(radio frequency identification)/ID communication method between primary and secondary sides of contactless transformer and detect the alien load. Such CPTS requires the circuit that generates ID in addition, and the ID identification and control generated from the secondary side is performed at the primary side, which cuases complexity of the circuit. Therefore, this study suggested the CPTS using voltage phase, and In order to verify the validity of this study, 3[W] class CPTS shall be designed, and the simulation and test of CPTS using current and voltage phases shall be carried out.

Design of 9 kJ/s High Voltage LiPo Battery based 2-stage Capacitor Charger (배터리 기반 2단 충전 9 kJ/s 고전압 충전기 설계)

  • Cho, Chan-Gi;Jia, Ziyi;Ryoo, Hong-Je
    • The Transactions of the Korean Institute of Power Electronics
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    • v.24 no.4
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    • pp.268-272
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    • 2019
  • A lithium polymer battery-based 9 kJ/s high-voltage capacitor charger, which comprises two stages, is proposed. A modified LCC resonant converter and resonant circuit are introduced at the first and second stages, respectively. In the first stage, the methods for handling low-voltage and high-current batteries are considered. Delta-wye three-phase transformers are used to generate a high output voltage through the difference between the phase and line-to-line voltages. Another method is placing the series resonant capacitor of the LCC resonant components on the transformer secondary side, which conducts considerably low current compared with the transformer primary side. On the basis of the stable operation of the first charging stage, the secondary charging stage generates final output voltage by using the resonance. This additional stage protects the rectifying diodes from the negative voltage when the output capacitor is discharged for a short time. The inductance and capacitance of the resonance components are selected by considering the resonance charging time. The design procedure for each stage with the aforementioned features is suggested, and its performance is verified by not only simulation but also experimental results.

Influence of Post-Sintering Annealing Conditions on the Microstructure and Magnetic Properties of Nd-Fe-B Magnet (Nd-Fe-B 소결자석의 소결 후 열처리 조건에 따른 미세조직 및 자기적 특성 변화)

  • Yunjong Jung;Soonjik Hong;Dong-Hwan Kim;Kyoung-Hoon Bae;Gian Song
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.1
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    • pp.9-15
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    • 2024
  • Nd-Fe-B permanent magnets have been utilized on various industrial fields such as electric vehicles, generator, robots with actuator, etc, due to their outstanding magnetic properties even 10 times better than conventional magnets. Recently, there are many researches that report magnetic properties improved by controlling microstructure through adjusting alloying elements or conducting various processing. Especially, post-sintering annealing (PSA) can significantly improve the coercivity by modifying the distribution and morphology of Nd-rich phase which formed at grain boundaries. In this study, Nd-Fe-B sintered magnets were subjected to primary heat treatment followed by secondary heat treatment at 460℃, 500℃, and 540℃ to investigate the changes in microstructure and magnetic properties with the secondary heat treatment temperature. EBSD analysis was conducted to compare anisotropic characteristics. Through the SEM and TEM observation for analyzing the morphology and distribution of Nd-rich phase, we investigated the relationship between microstructure and magnetic properties of sintered Nd-Fe-B magnets.