• Horticultural Science & Technology
• /
• v.19 no.3
• /
• pp.342-347
• /
• 2001

The experiment was carried out to examine the effect of culture media and seawater on growth and mineral concentrations in Glasswort (Salicornia herbacea). Glassworts were grown in a greenhouse with 0, 10, 30 and 90% seawater and with or without nutrient media. The salinity tolerance affected on shoot height and Na, K and Ca concentrations significantly. The shoot height was increased with 10 and 30% seawater concentrations. At the higher seawater concentrations, more Na accumulated in a shoot was obserbed. The application of seawater concentration was effective on increasing Na, Mg, and Fe, concentrations and green leaf area rate and on decreasing K concentration. K/Na ratio of shoot was decreased at high seawater concentration, whereas Na concentrations was lowered at a low seawater concentrations. The mineral concentrations were changed according to the growing season. Na, K and Mg were high in June and Ca and P in September, respectively.

• Economic and Environmental Geology
• /
• v.41 no.4
• /
• pp.383-392
• /
• 2008

This study aims to evaluate the mechanical-chemical stability of used coal ash blocks, for improving fishing grounds. The surface of weathered ash blocks in seawater showed a decrease in the Ca and an increase in the Mg contents, compared to that of fresh blocks. This result reflects the substitution of Ca by Mg in seawater. The compressive strengths of ash blocks submerged into seawater during 12 months ranged from 235.23 to $447.43\;kgf/cm^2$; this is higher than the standard strength of wave-absorbing blocks($180\;kgf/cm^2)$ that are used for harbor construction. In addition, the compressive strength of ash blocks tends to increase with increasing installation time in seawater. The result of leaching experiments on coal ash blocks by Korean Standard Leaching Test(KSLT) method showed that leached concentrations of most metals except Cr(that leached up to 50 ppb, approaching standard concentration) do not exceed the seawater quality standards. A long-term(112 days) heavy metal leaching test to analyze seawater without mixing-dilution also showed that the concentrations of leached heavy metals, except for Cu, under anaerobic conditions do not exceed the seawater quality standards. Accordingly, the use of coal ash blocks in marine environments appears to be safe from chemical and mechanical factors that decrease the efficiency of concrete. Also, leaching concentration of Cu seems to be stable by decrease of leaching concentration due to dilution of seawater.

• Journal of environmental and Sanitary engineering
• /
• v.8 no.1
• /
• pp.67-80
• /
• 1993

This survey was carried out to take the status of seawater intrusion into groundwater wells located in the eastern area of Chejudo, to get the elementary data which may evaluate the level of would-be groundwater contamination, and to perform effective the effort that will supply the clear water for the residents. The sampling sites were northeastern districts of Haengwon, Handong, and Sangdo, southeastern districts of Susan, Nansan, and Samdal, and northwestern districts, as reference, of Aewol, Keumnung, Panpo, Kosan, Shindo, and Bosung. We collected the samples from the public tap water by month, and analysed electrical conductivity, sodium(Na), potassium(K), magnesium(Mg), calcium(Ca), bicarbonate($HC0_{3^-}$), and items of the criteria as drinking water. In the northeastern districts we also added the sampling sites to survey the fluctuations of dissolved solids according to distance from seashore, including two private boreholes and one public tap water of Dukchun. The result is as follows 1) In the northeastern district, the concentration of chloride ion showed large fluctations from 40mg/l to 100mg/l, but suitable for the criteria of drinking water. It was thought that the drought influenced. 2) In the Sangdo of the northeastern districts, similar tendancy to Hangwon and Handong was showed only in the concentration of chloride ion, but different tendancy was showed in chloride-bicarbonate ratio, calcium-magnesium ratio, and sodium adsorption ratio(SAR). Considering these facts, it was not thought that seawater intruded. 3) The components of Na and Cl showed rapid slope in the northeastern districts above 3km from seashore. 4) In the northwestern districts as reference, the concentration of chloride ion fluctuated slightly according to the sampling sites and dates, and the concentration of nitrate-nitrogen in some sites exceeded the criteria of drinking water. These were thought that the surface contaminants rather than the intrusion of seawater influenced mainly the groundwater, considering the correlation(r=0.732) of chloride ion and nitrate-nitrogen. 5) Then we must consider the regional characteristies of soil profile in order to prevent the contamination of groundwater, and moniter also the movement of main components within the sol1 profile, not only the research of the intrusion of seawater.

• Journal of Soil and Groundwater Environment
• /
• v.16 no.5
• /
• pp.53-66
• /
• 2011

Groundwater which infiltrated in recharge areas discharges in the forms of evapotranspiration, baseflow to streams, groundwater abstraction and eventually flows into the sea. This study characterized radon-222 concentration and electrical conductivity (EC) in coastal groundwater discharge, well groundwater, Ilkwang Stream water, and seawater in the coastal area of Busan Metropolitan City and subsequently estimated groundwater discharge rate to the sea. The median value of Rn-222 concentration is highest in well groundwater (18.36 Bq/L), and then decreases in the order of coastal groundwater discharge (15.92 Bq/L), Ilkwang Stream water (1.408 Bq/L), and seawater (0.030 Bq/L). The relationship between Rn-222 concentration and EC values is relatively strong in well groundwater and then in seawater. However, the relationship is not visible between coastal groundwater discharge and Ilkwang Stream water. The groundwater discharge rate to the sea is estimated as $3,130m^3$/day by using radon mass budget model and $16,788m^3$/day by using Darcy's law.

• Journal of Environmental Science International
• /
• v.9 no.3
• /
• pp.253-259
• /
• 2000

The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater, spring water are analyzed. The concentration of $Cl^-$ and Na^++K^+$/ contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, $HCO_3, Na-Cl-HCO_3$ and Ca-HCO$_3$. The concentration ratio of $SO_4^1 to Cl^- is 0.1354(R^2=0.972)$ at this area. This value is very similar with Dittomer's ratio of 0.13. For Na^+, K^+, and Mg^{2+}/ versus Cl^-$, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4km at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of $Na^+$ observed at field is 25~45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500$\mu$mhos/cm is located at 4~5km poing at Kosung-Susan area and 2.5km point at the other area. The equation of correlation between $Cl^-$ concentration and EC values is $Cl^-$=0.1927EC-16.683 for the area lower than 500 $\mu$mhos/cm and $Cl^-$=0.2773EC for the area beyond 500 $\mu$mhos/cm.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.16 no.4
• /
• pp.227-238
• /
• 2013

The purpose of this study is to develop a process technology to produce high hardness drinking water which meet drinking water standard, remaining useful minerals like magnesium and calcium in the seawater desalination process while removing the sulfate ions and chloride ions. Seawater have been separated the concentrated seawater and desalted seawater by passing on Reverse Osmosis membrane (RO). Using Nano-filtration membrane (NF), We were prepared primary mineral concentrated water that sodium chloride were not removed. By the operation of electro-dialysis (ED) having ion exchange membrane, we were prepared concentrated mineral water (Mineral enriched desalted water) which the sodium chloride is removed. We have produced the high hardness water to meet the drinking water quality standards by diluting the mineral enriched desalted water with deionized water by RO. Reverse osmosis membranes (RO) can separate dissolved material and freshwater from seawater (deep seawater). The desalination water throughout the second reverse osmosis membrane was completely removed dissolved substances, which dissolved components was removed more than 99.9%, its the hardness concentration was 1 mg/L or less and its chloride concentration was 2.3 mg/L. Since the nano-filtration membrane pore size is $10^{-9}$ m, 50% of magnesium ions and calcium ions can not pass through the nano-filtration membrane, while more than 95% of sodium ions and chloride ions can pass through NF membrane. Nano-filtration membrane could be separated salt components like sodium ion and chloride ions and hardness ingredients like magnesium ions and calcium ions, but their separation was not perfect. Electric dialysis membrane system can be separated single charged ions (like sodium and chloride ions) and double charged ions (like magnesium and calcium ions) depending on its electrical conductivity. Above electrical conductivity 20mS/cm, hardness components (like magnesium and calcium ions) did not removed, on the other hand salt ingredients like sodium and chloride ions was removed continuously. Thus, we were able to concentrate hardness components (like magnesium and calcium ions) using nano-filtration membrane, also could be separated salts ingredients from the hardness concentration water using electrical dialysis membrane system. Finally, we were able to produce a highly concentrated mineral water removed chloride ions, which hardness concentration was 12,600 mg/L and chloride concentration was 2,446 mg/L. By diluting 10 times these high mineral water with secondary RO (Reverse Osmosis) desalination water, we could produce high mineral water suitable for drinking water standards, which chloride concentration was 244 mg/L at the same time hardness concentration 1,260 mg/L. Using the linked process with reverse osmosis (RO)/nano filteration (NF)/electric dialysis (ED), it could be concentrated hardness components like magnesium ions and calcium ions while at the same time removing salt ingredients like chloride ions and sodium ion without heating seawater. Thus, using only membrane as RO, NF and ED without heating seawater, it was possible to produce drinking water containing high hardness suitable for drinking water standard while reducing the energy required to evaporation.

• Journal of Korean Society of Water and Wastewater
• /
• v.24 no.6
• /
• pp.735-741
• /
• 2010

A pilot test was carried out to investigate the long term operation characteristics of Microfiltration (MF) system as a pretreatment for seawater reverse osmosis (SWRO) processes for two years. A commercialized MF module with pressurized operation type was used to filter seawater to remove particles which can foul reverse osmosis (RO) membrane. Silt Density Index (SDI) values of filtered seawater by the MF system were ranged from 0.14 to 1.79, which meet the SDI standard for RO feed water as depicted in previous literatures. Although the tested seawater is quite clean (i.e., dissolved organic cabon (DOC) concentration and turbidity were about 1 mg/l and less than 1 NTU, respectively) enough not to foul the MF membrane, steep increase in trans-membrane pressure (TMP) with a constant flux were observed over a whole operation period. A set of operation and water analysis data implies that the steep increase in TMP was resulted from iron and maganese fouling by the combination of metal corrosion by seawater and oxidation state by aeration and residual chlorine.

• Food Science and Preservation
• /
• v.10 no.3
• /
• pp.417-420
• /
• 2003

In order to study optimum culture condition of yeast medium added deep seawater, we examed samples with 9 yeast strains. The growth rate were measured for Saccharomyces cerevisiae 10, 11, 12, 901 and RCY and Saccharomyces kluyvery DJ97, Saccharomyces cerevisiae YJK, JK99, CMY-28 etc.. The growth of S. cerevisiae 12 was found most active in the deep seawater(hardness 500). The growth rate of S. cerevisiae 901 on medium containing deep seawater(hardness 1000) was faster than that of the yeast on medium without deep seawater. The use of deep seawater on the growth of Sacch.cerevisiae kluyvery DJ97 revealed maximum growth under the condition of hardness 200 of deep seawater and 10％ of sugar concentration.

• Journal of Soil and Groundwater Environment
• /
• v.26 no.6
• /
• pp.95-105
• /
• 2021

Extensive groundwater abstraction has been recognized as one of the major challenges in management of coastal groundwater. The purpose of this study was to assess potential changes of groundwater distribution of northeastern Jeju Island over 10-year duration, where brackish water have been actively developed. To quantitatively estimate the coastal groundwater resources, numerical simulations using three-dimensional finite-difference density-dependent flow models were performed to describe spatial distribution of the groundwater in the aquifer under various pumping and recharge scenarios. The simulation results showed different spatial distribution of freshwater, brackish, and saline groundwater at varying seawater concentration from 10 to 90%. Volumetric analysis was also performed using three-dimensional concentration distribution of groundwater to calculate the volume of fresh, brackish, and saline groundwater below sea level. Based on the volumetric analysis, a quantitative analysis of future seawater intrusion vulnerability was performed using the volume-based vulnerability index adopted from the existing analytical approaches. The result showed that decrease in recharge can exacerbate vulnerability of coastal groundwater resources by inducing broader saline area as well as increasing brackish water volume of unconfined aquifers.

• ALGAE
• /
• v.26 no.3
• /
• pp.265-275
• /
• 2011

This study examined the bioaccumulation of the heavy metals copper (Cu) and zinc (Zn) by the giant kelp, Macrocystis pyrifera, by exposing meristematic kelp tissue to elevated metal concentrations in seawater within laboratory aquaria. Specifically, we carried out two different experiments. The first examined metal uptake under a single, ecologically-relevant elevation of each metal (30 ppb Cu and 100 ppb Zn), and the second examined the relationships between varying levels of the metals (i.e., 15, 39, 60, 120, 240, and 480 ppb Cu, and 50, 100, 200, 300, 500, and 600 ppb Zn). Both experiments were designed to contrast the uptake of the metals in isolation (i.e., when only one metal concentration was elevated) and in combination (i.e., when both metals' concentrations were elevated). Following three days of exposure to the elevated metal concentrations, we collected and analyzed the M. pyrifera tissues using inductively coupled plasma atomic emissions spectroscopy. Our results indicated that M. pyrifera bioaccumulated Cu in all treatments where Cu concentrations in the seawater were elevated, regardless of whether Zn concentrations were also elevated. Similarly, M. pyrifera bioaccumulated Zn in treatments where seawater Zn concentrations were elevated, but this occurred only when we increased Zn alone, and not when we simultaneously increased Cu concentrations. This suggests that elevated Cu concentrations inhibit Zn uptake, but not vice versa. Following this, our second experiment examined the relationships among varying seawater Cu and Zn concentrations and their bioaccumulation by M. pyrifera. Here, our results indicated that, as their concentrations in the seawater rise, Cu and Zn uptake by M. pyrifera tissue also rises. As with the first experiment, the presence of elevated Zn in the water did not appear to affect Cu uptake at any concentration examined. However, although it was not statistically significant, we observed that the presence of elevated Cu in seawater appeared to trend toward inhibiting Zn uptake, especially at higher levels of the metals. This study suggests that M. pyrifera may be useful as a bio-indicator species for monitoring heavy metal pollution in coastal environments.