• Title/Summary/Keyword: seawater concentration

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Separation Reaction Characteristics of Boron Ion by Ion Exchange Method (이온교환법을 이용한 해수 중 붕소이온 분리 반응 특성)

  • Jung Boo-Young;Kang Suk-Hwan;Lee Jae-Chun;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.45-49
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    • 2006
  • In this study, it was investigated on the boron separation ken synthetically prepared seawater. ion exchange resin used in the experiments was Amberlite IRA 743, containing glucamine functional group. The experiments were carried out as a function of the conditions of the pH, boron initial concentration and temperature of seawater in a batch reactor. As a result, optimum conditions for boron adsorption were at pH 8.5 and 313 K, respectively. The adsorption rate was increased very fast with increasing the temperature, but decreased with increasing the initial concentration of boron. Also, the kinetics for boron adsorption applied the pseudo-second order model, as follows: $$\frac{X}{1-X}=780[C_0]^{-1.65}t^{1.48}\;exp\;({-\frac{17883}{RT}}\)\;;\;pH8.5$$

Estimation of Nutrient Mass Balance in a Phragmites Australis Community in Jinudo Through a Mesocosm Experiment (메조코즘 실험을 통한 진우도 갈대군락의 영양염 물질수지 산정)

  • RYU, Sung Hoon;LEE, In cheol
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.5
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    • pp.545-552
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    • 2018
  • In this study, we performed a mesocosm experiment to estimate the mass balance of Nutrients (DIN, DIP) in a phragmites australis community. We developed 4 mesocosm tanks which is available to circulate seawater with adjustable tide levels and flooding times. Each of the mesocosm tanks were filled with phragmites australis and sediment from Jinudo in Nakdong Estuary. We investigated DIN, DIP concentrations in three layers (seawater-phragmites australis-sediment) to estimate the mass balance of Nutrients and biomass. Growth rates were also investigated. The results can be summarized as follows. 1) In spring, rhizome biomass was higher than that of aerial stem by about 6.3~9.7%. In summer, aerial stem biomass was higher than that of rhizome about 19.2~21.2 %. 2) Th Growth rate of phragmites in Mesocosm Tank A was faster than in Mesocosm Tank D by about 2 to 3 times for aerial stem and rhizome. 3) The Concentration of nutrients (DIN, DIP) in each mesocosm Tank showed 2~3 % variance in spring and summer. 4) The biomass in each mesocosm varied by about 23 % which was higher than the concentration variance for each mesocosm tanks.

Effect of Underground Dam for the Prevention of Seawater Intrusion at the Seom-jin River (지하댐 설치 시 섬진강 하류 염수침입 방지 효과의 모델기반 분석)

  • Kim, Sungyun;Kim, Gyoobum;Park, Joonhyeong;Shin, Seonho
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.8
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    • pp.51-57
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    • 2011
  • Surface water at the lower part of the Seom-jin river has a high salinity because the erosion at river bottom has made sea water move upstream continuously since 1978. The effect of underground dam on the prevention of sea water intrusion was modelled in this study. Present chloride concentration in surface water decreases exponentially along a river and in groundwater is about one-tenth of surface water's. The finite element method model, FEFLOW, was conducted on the assumption that the underground dam with a height of 25m over a bedrock is located under a water surface at the site of 4.6km from an estuary. The result shows that the position with chloride concentration of 0.25psu moves downstream from the sites of 25km to 22km, if an enough sedimentation with 5m thickness happens in the upper reservoir of underground dam. On the other side, the underground dam is little effective for the prevention of sea water intrusion in case of non-sedimentation.

Performance Evaluation of a Closed-Loop Pressure Retarded Membrane Distillation for Brackish Water Desalination and Power Generation (기수담수화와 전력 생산을 위한 폐루프형 압력 지연식 막 증류 공정의 성능 평가)

  • Cho, Gyu Sang;Lee, Jun-Seo;Park, Kiho
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.525-534
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    • 2022
  • In this study, we investigated the applicability and optimal operating strategy of a closed-loop pressure retarded membrane distillation (PRMD) for brackish water desalination. For effective operation with net power generation, high temperature of heat source over 90 ℃ and feed flow rate at 0.6 kg/s are recommended. At 3 g/L of feed concentration, the average permeate flux and net energy density showed 8.04 kg/m2/hr and 2.56 W/m2, respectively. The average permeate flux and net energy density were almost constant in the range of feed concentration from 1 to 3 g/L. Compared to the case with seawater feed, the PRMD with brackish water feed showed higher average permeate flux and net energy density. Thus, PRMD application using brackish water feed can be more effective than that using seawater feed in terms of power generation.

Removal Efficiency of Settleable Solids in Seawater Aquaculture Farm Wastewater (하이드로싸이클론을 이용한 해수 양식장 침전 고형물의 제거 효율 평가)

  • Junhyuk Seo;Pyongkih Kim;Jeonghwan Park
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.1
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    • pp.116-123
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    • 2023
  • Flow-through aquaculture systems generate large amounts of wastewater containing compounds such as solids that can settle near aquafarms and cause eutrophication. The settled solids are often reintroduced into flow-through systems, and aquatic animals can be affected by the solids and pathogens associated with these solids. For a sustainable aquaculture operation, adequate wastewater treatment is required. Hydrocyclones are one of the most promising technologies for the removal of solids in aquaculture wastewater. In this study, a model for performance prediction of hydrocyclones was investigated under three different operating conditions: water temperature, solids concentration, and water inlet velocity. The synthetic solids solution was prepared using settled solids from abalone aquaculture farms. The daily solids removal rates of the tested hydrocyclones ranged from 0.18 to 26.0 g solids-m-3-day-1, and removal efficiency ranged from 5.1 to 34.4%. The inlet water velocity had the greatest effect on solids removal and hydrocyclone efficiencies. The following multiregression model equation was derived from the daily solids removal rate (g solids-m-3-day-1) results for water temperature (T, ℃), solids concentration (SS, mg-L-1), and tangential inlet water velocity (TIV, m-sec-1): daily solids removal rate: f(z)=4.465+0.809TIV-0.375T+0.217SS (r2=0.976).

Nitrification Performance of a Moving Bed Bioreactor (MBBR) at Different Ammonia and Hydraulic Air-Loading Rates under Seawater Conditions (해수 조건에서 총암모니아성 질소 부하량과 수리학적 공기 부하량에 따른 유동상 여과조의 질산화 성능 평가)

  • Jaegeon Lee;Younghun Lee;Jeonghwan Park
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.6
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    • pp.870-877
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    • 2023
  • The purpose of this study was to assess the efficiency of nitrification based on ammonia loading rates and hydraulic air-loading rates in a moving bed bioreactor (MBBR) under seawater conditions. The goal was to provide foundational data for the design of these bio reactors. At an ammonia loading rate of 0.2 g TAN·m-2 surface area·day-1, the influent TAN concentration was determined to be 1.76±0.33 mg·L-1, which is below the safe concentration for fish survival (2 mg·L-1). Considering operational aspects, the optimal ammonia-loading rate was derived. Subsequently, experimental results for nitrification efficiency at the optimal ammonia-loading rate revealed that the optimum hydraulic air-loading rate was 1.8 L·air·m-2 surface area·min-1. This condition resulted in the lowest concentrations of TAN and NO2-N in the influent water, thus establishing the optimal hydraulic air-loading rate. A regression equation was derived for the ammonia-removal rate (Y) based on the ammonia-loading rate (x) and expressed as a 0.5-order equation (Y=ax0.5+b). Specifically, for TAN concentrations of 0-6 mg·L-1, the regression equation Y=0.1683x0.5-0.13628, was established.

Distribution of Nonylphenol in Gwangyang Bay and the Surrounding Streams (광양만 및 주변 하천에서의 노닐페놀 화합물 분포)

  • 이동호;김민선;심원준;임운혁;홍상희;오재룡
    • Korean Journal of Environmental Biology
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    • v.22
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    • pp.71-77
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    • 2004
  • Alkylphenols (8), chlorophenols (2), bisphenol A, eoprostanols (2) and cholesterol compounds were analyzed in the surface water and surface sediment taken from Gwangyang Bay and surrounding streams in 2001. Among the target analytes, nonylphenol and dihydrocholesteyol compounds were detected with high concentration and high frequency. t-Octylphenol, bisphenol A and coprostanols were detected only in some sediment samples from the stream. The highest concentration of nonylphenol was determined in stream sample, and concentrations of nonylphenol in the inner part of Gwangyang Bay were higher than those in the out part. Nonylphenol concentrations in the surface seawater and surface sediment samples ranged from 4.0 to 74.0 ng l$\^$-1/ and from 3.1 to 74.3 ng g$\^$-1/ dry wt., respectively. Partition coefficient (LogK$\_$oc/) of nonylphenol between sediment and water was 4.8. Nonylphenol nnd dihydrocholesteol concentrations in the stream surface sediment samples ranged from 4.6 to 808.6 and from 78.4 to 1133.6 ng g$\^$-1/ dry wt., respectively. Relatively high concentrations of nonylphenol were found in the stream samples which aye flowing through industrial complex area, while dihydrocholesterol concentration was relatively high in the stream samples which are flowing through only municipal area. Seaward decreasing tyend in nonylphenol concentration was observed from the Seomjin River estuary to the Gwanyang Bay. Such trend was best supported by the strong correlation between nonylphenol concentration and salinity in water samples.

Evaluation and Consideration on Environmental Radiation Analysis of Yeong-Gwang Nuclear Power Plant Site Inside&Outside(2000~2009 year) (영광원전 부지 내.외부의 환경방사능 분석에 대한 평가 및 고찰(2000~2009년))

  • Han, Sang-Jun;Lee, Seung-Jin;Lee, Goung-Jin;Lee, Na-Young;Kim, Hee-Gang;Mun, Ji-Yeon
    • Journal of Radiation Protection and Research
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    • v.36 no.2
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    • pp.71-78
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    • 2011
  • Yeong-Gwang N.P.P Private Environment Supervisory Organization analyzed over 3,000 samples including 10 marine and 24 land samples from the year 2,000 to 2009. According to the results of the analysis, artificial nuclides that resulted from the effect of Yeong-Gwang Nuclear Power Plant operations were not detected in most samples. However, from the rain and seawater samples, which were taken from inside the plants such as the intake, the discharge and the observatory, $^3H$ was detected although it was below the regulation level. The $^3H$ concentration detected in the rain taken from the observatory, by the yearly average criterion, was 30.5~40.0 $Bq{\cdot}L^{-1}$, which is around 20 times the $^3H$ concentration detected in the surroundings of the power plants, but it is 0.1% of the regulation level of 40,000 $Bq{\cdot}L^{-1}$. Also, $^3H$ concentration detected in the seawater taken from the intake and the discharge, by the yearly average criterion, was 2.75~17.8$Bq{\cdot}L^{-1}$, which means the concentration detected in the discharge is about 140~280% higher than that detected in the intake except the year 2006. Based on these results, it was determined that, although lower than the regulation level, the $^3H$ in gas and liquid form detected in the rain and seawater sampled from the observatory and the discharge was released into the environment from the power plants. Therefore, regular monitoring and analysis is required on the level of $^3H$ in the observatory and the discharge.

A Rough Estimation of Environmental Capacity in the Yellow Sea using a Numerical Hydrodynamic Model (해수운동모델을 이용한 황해 환경용량의 개략 산정)

  • Kim Gwang Su;Kim Dong Myung;Park Chung Kil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.2 no.1
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    • pp.63-73
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    • 1999
  • The results of residual currents simulation by a three-dimensional hydrodynamic model showed the water volume transport and the residence time to be about 4km³ per tidal cycle and about 6 years through the line of latitude, 34° 25' N in the Yellow Sea, and to be about 13km³ per tidal cycle and about 2.5 years through the southeastern boundary line of the Yellow Sea, respectively. On the bases of the entire seawater volume of the Yellow Sea and dissolved oxygen (DO) in summer, the environmental capacity of the Yellow Sea for reception of the maximum pollution load without reducing DO concentration below 5.0mg/ℓ in seawater may be estimated to be about 58×10/sup 6/tons of chemical oxygen demand (COD), which is equivalent to the load about 8 times as high as the annual organic pollution load from 14 major rivers. On the bases of DO transports by residual currents calculated on the line of 34° 25' N latitude and on the southeastern boundary line of the Yellow Sea being about 57×10³tons and about 203×10³tons of DO per day, respectively, the environmental capacities of the Yellow Sea for reception of the maximum pollution loads without reducing DO concentration in seawater nay be equivalent to COD loads about 3 times and 10 times, respectively, as high as the existing organic pollution loads from 14 major rivers.

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On Board Comparison of Total Hydrogen Ion Concentration (pH) and Total Alkalinity Measurements in Seawater (해수의 총수소이온농도(pH)와 총알칼리도 측정방법에 대한 선상 비교 연구)

  • Kang, Dong-Jin;Tishchenko, Pavel Ya;Kahng, Sung-Hyun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.3
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    • pp.205-211
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    • 2011
  • On board comparison of pH and total alkalinity measurement in seawater was carried out during the JES expedition on R/V Roger Revelle in the East Sea using 550 real seawater samples from the surface to the bottom. Spectrophotometry and potentiometry without liquid junction were compared for pH measurement. The pH values of two methods are generally in a good agreement. Spectrophotometry with a pipette provides higher value compare with the potentiometry in the deep layer, where pH values are lower. However, spectrophotometry without a pipette shows same values with potentiometry within their precision range. The pipetting procedure may remove of $CO_2$ in the sample, which causes increase of pH. Potentiometric titration methods using a closed-cell and an open-cell were compared for the total alkalinity measurement. Values from open cell method are smaller by about 5~10 ${\mu}mol\;kg^{-1}$ than those from closed cell method. This may be caused by the bubble formed in the closed cell during the experiment. Although any analytical method compared in this study for the pH or TA measurement can be applied, special attentions should be paid for satisfactory results.