• Resources Recycling
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• 제25권3호
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• pp.63-73
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• 2016

With the purpose of concentrating the magnesium from seawater, in this study, we have conducted experiments to precipitate the magnesium using three precipitants (NaOH, cement kiln dust, and paper sludge ash), and then extract it using sulfuric acid. Results show that the precipitation and extraction performance does not depend so significantly on the kind of precipitant: for all the precipitants used, the precipitation efficiency is measured almost 100% and the extraction efficiency is in the short range of 77 - 89%. The magnesium concentration in the extract is measured 4975 - 5775 mg/L, implying that the magnesium in seawater should be 3.8 - 4.4 times concentrated through the precipitation and extraction reactions. The reaction efficiency of the industrial by-product used as a precipitant in this study is almost 100% similar to those of the other existing expensive precipitants.

• Journal of Korean Society of Water and Wastewater
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• 제25권6호
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• pp.917-922
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• 2011

Adsorption characteristics of boron on activated carbon was investigated in order to evaluate the use of activated carbon for the removal of boron in desalination processes using SWRO. Boron was removed ranging from 54~60% when the concentration of activated carbon was 1,000 mg/L in 6 hours under the initial boron concentration of 5 mg/L. The removal of boron increased by 20~22% with the increase of pH from 5 to 9. Organic matter had adverse effect on the adsorption of boron on activated carbon. Boron removal decreased by 10-12% when EDTA was added at 1 mg/L under 5 mg/L of boron and 200mg/L of activated carbon. In this results, activated carbon would be a good candidate for a pretreatment of desalination processes by SWRO from the view of mitigating the feed boron concentration to RO and meeting the effluent boron concentration without post-treatment after RO.

• Journal of Environmental Science International
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• 제12권3호
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• pp.345-358
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• 2003

Jindong bay at the northwestern part of Jinhae bay suffers from the occurrence of red tides in summer every year. In order to study the management methods of coastal environments, an ecological numerical model has been developed. The model experiments was forecasted that the load of nutrients from the land and field concentration will be cut down per 10% each. When we cut down 57.2% nitrogen load in the inner bay and 38.4% phosphorous load in the outer bay of bottom layer of the nutrients load from land and field concentration, the seawater quality standard levels up first grade. When we cut down 86.5% nutrients in the inner bay and 93.0% nutrients in the outer bay, the concentration of chlorophyll a decreases below 3.2 $\mu\textrm{g}$/(equation omitted)(an individual concentration of phytoplankton : 10,000cel1/ml), i.e. the red tides do not occur.

• Korean Journal of Environmental Biology
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• 제18권1호
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• pp.21-31
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• 2000

We investigated seasonal variation of microalgal assemblages, sea water temperature, salinity and suspended solid and the parameters measured daily from January 1998 to October 1999 at a nearshore shallow-water in Marian Cove, Maxwell Bay, King George Island, the Antarctic. Annual mean surface water temperature was -0.3$0^{\circ}C$ and the highest water temperature was 4.53$^{\circ}C$ (22 January 1999) and the lowest water temperature was -2.07$^{\circ}C$ (23 August 1998). Annual mean salinity was 33.38 psu, ranging from 42.80 psu (6 January 1999) to 19.50 psu (6 June 1999). Annual mean suspended solid (SS) during two years was 34.14 mgㆍ1$^{-1}$, ranging from 60.62 mgㆍ1$^{-1}$(7 March 1998) to 12.90 mgㆍ1$^{-1}$ (26 December 1998). Chlorophyll $\alpha$ (Chl $\alpha$) concentrations were measured in order to know seasonal variations of microalgae in the surface seawater. Annual mean of total Chl a concentration was 0.55$\mu\textrm{g}$ㆍ1$^{-1}$, the highest Chl $\alpha$ concentration (12.16$\mu\textrm{g}$ㆍ1$^{-1}$) appeared in 4 October 1998, the lowest Chl $\alpha$ concentration appeared 0.19$\mu\textrm{g}$ㆍ1$^{-1}$, Monthly mean total Chl $\alpha$ concentration was high in October 1998 (1.32$\mu\textrm{g}$ㆍ1$^{-1}$) and low in July on 1998 (0.28$\mu\textrm{g}$ㆍ1$^{-1}$). Annual mean nano-sized Chl $\alpha$ concentration was 0.40$\mu\textrm{g}$ㆍ1$^{-1}$, monthly mean nano -sized Chl $\alpha$ concentration was high in November 1998 (0.90$\mu\textrm{g}$ㆍ1$^{-1}$), and low in July 1999 (0.22$\mu\textrm{g}$ㆍ1$^{-1}$). Annual mean micro-sized Chl $\alpha$ concentration was 0.15$\mu\textrm{g}$ㆍ1$^{-1}$ monthly mean micro-sized Chl $\alpha$ concentration was high in October 1998 (0.81$\mu\textrm{g}$ㆍ1$^{-1}$), and low July 1998, January, February and September 1999 (0.05$\mu\textrm{g}$ㆍ1$^{-1}$). More than 65% of total Chl $\alpha$ was concentrated during spring and summer time between October and March. Microalgal variation appeared to be due to physical factors of seawater in the Antarctic nearshore from 1998 to 1999. The reason why micro-sized Chl $\alpha$ did not increase during austral summer was the bay had been frozen by decrease of water temperature. We think that total microalgal abundance was decreased because the summer microalgal abundance was determined by variation of water temperature during winter season. [Chl $\alpha$ concentration, Microalgal assembalges, Seasonal variation, the Antarctic nearshore].

• The Korean Journal of Malacology
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• 제32권3호
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• pp.203-209
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• 2016

Growth and survival of the hard shelled mussel spat were investigated to confirm the possibe spat culture in seawater pond from September 2014 to April 2015. Also, we measured simultaneously environmental factors including water temperature, salinity, dissolved oxygen, pH, DIN, DIP, chlorophyll a, and abundance and dominant species of phytoplankton in seawater pond every month. Ranges of water temperature and salinity were $4.0-23.4^{\circ}C$ and 18.8-25.2 psu, respectively, which were rather lower than the reported optimal level. Monthly measured survival rates in all the spat cages were over 90%. Concentration of chlorophyll-a and abundance of phytoplankton were very high, and dominant species phytoplankton were cryptomonads and nanoflagellates. These dominant species were considered to be good food organisms for the bivalve spat. The experimental cage stocked 100 individuals per basket ($2,700ind.\;m^{-2}$) hanging in bottom of seawater pond revealed the highest growth in shell height ($7.63{\pm}4.65mm$), but all experimental cages stocked below 200 individuals per basket ($5,400ind.\;m^{-2}$) did not show statistically significant difference. We may expect that seawater pond would be one of the best culture ground for bivalve spats when appropriate measures are available.

• Economic and Environmental Geology
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• 제34권5호
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• pp.447-460
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• 2001

The geothermal waters from the Busan area belong to Na-CI type and are characterized by much higher EC (921 ~6,520${\mu}$S/cm) and TDS (608-3,390 mg/L) than other geothermal waters in Korea. The concentration of majorions shows a weakly positive relationship with temperature except for Mg ion. The concentrations of the major cat ions have the order of Na>Ca>K>Mg. Ca ion is enriched and Mg ion is depleted compared with seawater. All Br concentrations of geothermal water are lower than those of seawater, showing a positive relationship with temperature. Generally geochemical characteristics of geothermal waters of the Busan area indicate that these waters have relatively increased Ca and Sr contents and depleted Mg, Na and K contents caused by seawater interaction with wall rock at depth during deep circulation of seawater. Base on the relationship between major ions and temperature, saline geothermal waters are diluted and are cooled by mixing of groundwaters during ascent. Isotope study and reaction path modeling of the overall geochemical system are required in order to better quantify the evolution and origin of geothermal waters in the Busan area.

• Journal of the Korean Society of Food Science and Nutrition
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• 제34권9호
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• pp.1450-1458
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• 2005

Quality characteristics of mul-kimchi prepared using eastern deep seawater added with $0.1\%$ chitosan-ascorbate (CA) were investigated during fermentation for 12 days at $10^{\circ}C$, in an effort to effectively utilize the eastern deep seawater in Korea. Four water sources were considered for preparation of mul-kimchi; (1)distilled water added with $1\%$ mineral salt (DW), (2) eastern deep seawater (containing $6\%$ salt) diluted to $1\%$ salt concentration with distilled water (ED), (3) DW+CA (DW-CA), and (4) ED+CA (ED-CA). Juice of mul-kimchi prepared with ED-CA as a water source showed higher PH and antioxidant activity, and lower acidity, total microbe numbers, turbidity and alcohol insoluble substance compared with those Prepared with other three water sources. The former also showed higher overall acceptability compared with the latter. This study demonstrated the possibility of use of eastern deep seawater added with chitosan-ascorbate as a water source for extension of shelf-life of mul-kimchi.

• Journal of Aquaculture
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• 제19권3호
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• pp.149-156
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• 2006

Stress responses, osmoregulation and growth of black porgy reared in freshwater or seawater were investigated by supplying the feed (10 mg/kg feed) treated with the $T_3$ (3,5,3'-triiodo-L-thyronine) for 90 days. Plasma $T_3$ in black porgy reared for 60 days in freshwater with (FT) or without (FN) $T_3$, treatment was lower than that in black porgy reared in seawater with (ST) or without (SN) $T_3$ treatment. The concentration of $T_3$ in FT was significantly more than that in FN. Plasma cortisol in FT, at the same day, was 4 times higher than that in FN, whereas the differences of the hormone between ST and SN was not significant. Although the levels of plasma glucose in FN and FT tended to be lower than that in ST and SN, no differences were found between fish reared in freshwater and seawater after $T_3$ treatment. Aspartate aminotransferase (AST) and alanine aminotransferase (ALT) of black porgy reared in seawater showed no difference throughout the experimental period. However, at the beginning stages of the experiment, the plasma levels of these enzymes in FN and FT were higher than in SN and ST. Recovering of AST level to the level of SN or FT was laster in FT than in FN. However, no effects of the exogenous $T_3$ treatment on osmoregulatory capacity and growth of black porgy reared in freshwater or seawater were observed in this study.

• Korean Chemical Engineering Research
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• 제57권4호
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• pp.539-546
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• 2019

Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

• Korean Journal of Fisheries and Aquatic Sciences
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• 제34권4호
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• pp.291-298
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• 2001

Seawater, sediment and biota in the Kwangyang Bay were analyzed by gas chromatography/quartz furnace atomic absorption spectroscopy (GC-QFAAS) to investigate concentrations and distribution pattern of butyltin compounds (TBT, DBT, MBT) during February, April and July, 1996, Marine biota analyzed were Tapes japcnicus and Crassostrea gigas. The concentrations of tributyltin (TBT) in seawater were in the range of ND-15.7 ng/L for the surface and ND-68.5 ng/L for the bottom. The highest concentration of TBT in seawater was detected in April for the both, surface and bottom water. The maximum value of $TBT_{(bottom)}/TBT_{(surface)}$, 3.6 in April showed the increased input of TBT from the surface water in April compared to February (2.1) and July (0.9). The concentrations of TBT in the sediment were in the range of ND-8.5 ng/g dry wt. The highest concentration of TBT in the sediment was measured in July, This result seems to attributed to the removal of TBT from water column via sorption onto particulate matters to the relatively undisturbed underlying sediment and increased input of TBT by increased fluxes of detritus of marine plankton after spring bloom, in July. The mean values of partitioning coefficient ($K_d$) of TBT between seawater and sediment were $3.0\times10^3$(February), $7.4\times10^3$(April) and $9.4\times10^3$(July). The concentrations of TBT in biosamples were in the range of ND-93.30 ng/g dru wt. (T. japonicus) and ND-138.53 ng/g dry wt. (C. gigas). The seasonal variation of TBT contents in biota was remarkable. The $K_d$ (biological concentration factor) was $7-41\times10^3$ for T. japonicus. and $5-34\times10^3$ for C. gigas. The measured TBT concentrations in seawater in the study area was sufficient to cause the imposex of shellfish and to retard the growth of aquatic organisms including oyster upon chronic exposure.