• Title/Summary/Keyword: scrubbing

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Optimization of In-Line Dry Scrubbing FGD process using Calcium Hydroxide and Effect of Additives (소석회를 사용한 In-Line형 건식탈황공정의 최적화와 첨가제의 영향)

  • 박재만;신창섭
    • Journal of the Korean Society of Safety
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    • v.12 no.2
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    • pp.102-111
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    • 1997
  • An In-line dry scrubbing FGD process was investigated. Calcium hydroxide was entrained in flue gas and the SO$_2$ removal efficiency by humidity and additives were examined. The range of reaction temperature was $200^{\circ}C$~$500^{\circ}C$ and the concentration of $SO_2$ was around 900ppm. By the increase of humidity in flue gas, the removal efficiency was increased. The effect of NaOH as a additive was very high and got high conversion of $Ca(OH)_2$, however in case of RH 90%, it was reverse. The effect of particle size and flow rate were examined. And the reaction rate constant and effective diffusivity also calculated.

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Extraction of nitrate salts from de-NOx waste scrubbing solution (탈질 스크러버의 폐세정액으로부터 질산염 추출 연구)

  • Kim, Wooram;Ha, Taeyoung;Park, Yeonsoo;Lee, Hyunsuk;Jo, Youngmin
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.210-216
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    • 2017
  • Recovery of low level nitric acid and sulfuric acid ions, which were contained in wastewater of a wet scrubber for de-NOx and de-SOx from ship engines, was attempted as fertilizing materials. This study utilized a selective extraction method using four organic solvents to precipitate the solid salts of ammonium nitrate and ammonium sulfate. The IR analysis showed almost same composition of the extracted ammonium salts with a commercial product, and recovery rate of nitrogen and sulfuric ions was 89% and 80% respectively. It was found that the selectivity and solubility consequently could be the crucial factors to recover the low level ions from the waste scrubbing water.

Wet Purification for the Selective Separation of Montmorillonite from Bentonite (벤토나이트로부터 몬모릴로나이트의 선택적 분리를 위한 습식 고순도화)

  • 김완태;채영배;정수복;임정한
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.4
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    • pp.293-304
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    • 2002
  • Wet purification process for the selective separation of montmorillonite from Gampo 13 and 35 bentonite ores was studied using physical processes such as ultrasonic scrubbing, decantation and centrifugation. Ultrasonic Scrubbing of Gampo 13 and 35 bentonite ores was revealed excellent result at 7 wt.% of slurry density and was almost finished within 30 minutes in the sample of Gampo 13 and 10 minutes in the sample of Gampo 35, respectively After decantation, approximately 52 wt.% from the bentonite of Gampo 13 and 64wt.% from the bentonite of Gampo 35 were recovered as purified products and the CEC was reached up to 119.4 meq/100 g and 124.5 meq/100 g, respectively. Particle separation by centrifugation showed that most of the impurity minerals such as quartz and feldspar were removed within the condition of 1,000 rpm.

Some Issues on the International Regulations Associated with the Air Pollution Caused by the SOx Emission at Sea (해양에서 황산화물 오염 규제에 대한 소고)

  • Lee, G.H.;Song, Mu-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.221-226
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    • 2008
  • Air pollution associated with the SOx emission from the shipboard propulsion and generation engines is becoming one of the major environmental concerns these days. Lead by the international organizations including IMO and European Union, a significantly strengthened air pollution related regulations have been introduced and they are becoming in practice as scheduled. Such rules are basically giving the guidelines for permissible SOx emission which can be only met by using high quality fuel oils with less sulfur content or operating scrubbing systems aiming at reducing SOx at the engine exhaust. Since both countermeasures can lead to the cost increase in ship building and operation, Korean shipbuilding industries, leading the world's market, need to be well aware of the ever changing regulations and be prepared with proper solutions. Here, we briefly summarize such latest rules and regulations on the air pollution at sea, and review some technical issues on the scrubbing systems available with some suggestions.

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An application of the electrostatic spray technology to increase scrubbing efficiency of SO$_{2}$ emitted from thermal systems (열시스템에서 생성된 SO$_{2}$ 가스의 배출저감을 위한 정전기 분무 원리의 응용)

  • Jeong, Jae-Yun;Byeon, Yeong-Cheol;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.8
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    • pp.1068-1076
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    • 1997
  • Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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Beneficiation of Low Grade Sericite Using Attrition Scrubbing and Sedimentation (해쇄 및 침강분리에 의한 저품위 견운모의 품위향상 특성)

  • Chae, Sungki;Kim, Hyunsoo;Kim, Sangbae;Kim, Wantae
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.137-147
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    • 2017
  • Sericite is a clay mineral that has a wide applications in the industry, depending on its purity. To maintain sericite's purity as high as possible it is necessary to remove its gangue minerals or control their contents prior to use for high value-added products and applications. In this study, the wet beneficiation of sericite by applying selective grinding and sedimentation techniques, were investigated. The ore mineral was composed mainly of sericite, quartz and calcite. Analysis showed that the content of sericite increased along with the particle size decrease, but the contents of impurity minerals as quartz and calcite were tended to decrease relatively with particle size decrease. The results of liberation tests using an attrition scrubber showed that the increase in residence time and slurry density have increased the generation of fine particles in -325 mesh size range. It was observed, however, that the contents of impurities such as quartz and calcite in such fine particles also increased during prolonged scrubbing. In the dispersed form without breaking, the yield of the recovered concentrate was 15.4 wt% and the $K_2O$ content was 9.84 wt%, after the dispersed slurry was allowed to settle for 20 minutes. On the other hand, the concentrate yield was increased to 23.4 wt% after 10 minute attrition scrubbing and 40 minute sedimentation, while its $K_2O$ content was decreased to 9.71 wt%. Most of final products were observed as platelet-shaped particles containing Si, Al and K which are main component of sericite.

Design of Counter current Extraction Process for the Separation of [Pr, Nd, Sm]/[La] using Cyanex 572 (Cyanex 572를 사용하여 [Pr, Nd, Sm]/[La]분리에 대한 향류추출공정 설계)

  • Lee, Joo-eun;So, Hong-Il;Jang, In-Hwan;Ahn, Jae-Woo;Kim, Hong-in;Lee, Jin-young
    • Resources Recycling
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    • v.27 no.4
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    • pp.50-56
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    • 2018
  • For the purpose of optimizing the counter current extraction process for separation of [Pr, Nd, Sm] group and [La] in mixed solution using Cyanex 572 as an extractant, the theory of Xu Guangxian was derived for calculating the optimized extraction factors. From the basic batch test result, the separation factor was 16.80 at extraction process and 21.48 at scrubbing process, and the loading capacity of 1.0 M Cyanex 572 was 0.12 M of rare earth element. The process parameters such as the stage number at extraction and scrubbing process, the flow rate ratio of feed and solvent solution can be calculated using an equation of optimum extraction ratio proposed by Xu Guangxian. From the result of calculation, 7 extraction stages and 4 scrubbing stages were required for rare earth separation, and the flow rate ratio of feed solution, solvent solution, scrubbing solution was 25 : 5.67 : 12.27.