• Title/Summary/Keyword: scoria

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Removal of aqueous heavy metals (Pb, Cu, Zn, Cd) by scoria from Jeju, Korea

  • Kwon, Jang-Soon;Yun, Seong-Taek
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.380-383
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    • 2004
  • Heavy metal release from wastewater is a serious environmental problem, and therefore, various wastewater treatment techniques have been developed. Among the techniques, sorption technique is most attractive. Considerable researches have been recently focused on finding out inexpensive sorbents, especially from various natural materials. In order to evaluate the applicability of the scoria taken from the Jeju Island, Korea to remove heavy metals (Pb, Cu, Zn, Cd) from aqueous solutions, equilibrium sorption experiments were conducted in this study. In equilibrium tests, powdered activated carbon (PAC), one of the most commonly used sorbents, was also tested to compare the effectiveness of the Jeju scoria with that of PAC. The Jeju scoria had larger adsorption capacity and affinity for metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) than PAC. The sorption parameters of the two sorbents were evaluated by using both the Langmuir and Freundlich isotherms, and the sorption data were better fitted to the Freundlich isotherm. In addition, the sorption behavior of metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) onto the scoria displayed a typical characteristic of the cation sorption. The removal of metal ions decreased at a lower pH condition due to competition with hydrogen ions for the sorption sites of Jeju scoria, while the removal increased at a high pH condition due to hydroxide precipitation.

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Adsorption Behavior of Heavy Metals and Organics in the Mixed Packed Column of Scoria/Activated Carbon (스코리아/활성탄의 혼합 충전탑에서의 중금속 및 유기물의 흡착 거동)

  • Kim, Seung-Geon;Moon, Soo-Hyoung;Lee, Ho-Won
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.97-101
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    • 2021
  • Adsorption properties of heavy metals and organics in the mixed packed column of scoria and activated carbon, as well as physicochemical properties and functional groups of scoria were investigated. As the mixing ratio of scoria increased, the average removal ratios of cadmium, nickel, chromium, and lead ions increased, but that of benzene and toluene decreased. The mixed packed column of scoria and activated carbon could be effectively used for the simultaneous removal of heavy metals and organics. Scoria has Si-H and Si-O functional groups, and it was confirmed that Si-O functional groups greatly contributed to the adsorption of heavy metals.

An Experimental Study on the Application of Porous Scoria Concrete to Artificial Reefs for Soft Coral (연산호 육성용 어초 개발을 위한 송이 다공성 콘크리트의 적용성에 관한 실험적 연구)

  • HONG CHONG-HYUN;KIM MOON-HOON;KIM SEOK-CHEL;PARK SUNG-BAE;Ryu SEONG-PIL
    • Journal of Ocean Engineering and Technology
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    • v.19 no.4 s.65
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    • pp.28-34
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    • 2005
  • In the study application of volcanic scoria concrete to artificial reefs is investigated. Volcanic scoria is a natural volcanic product that shows light weight, mil/i-porous, and far-infrared irradiation characteristics. The properties of volcanic scoria concrete using Jeju scoria aggregate are evaluated by conducting a comprehensive series of tests on strength and void ratio. It is concluded that the volcanic scoria concrete has the sufficient strength of 4MPa-13MPa and adequate void ratio of $12\%-35\%$ to be accepted as artificial reef concrete. The field experiments are performed through observation by scuba diver's at the Seogwipo coast. Porous specimen and plane concrete specimen are prepared for comparison purposes. Seasonal changes of soft coral on the two series of test specimens were have been observed from Apr. 9, 2004 to Mar. 18, 2005. The soft coral is well grown on the porous specimen however there are no significant changes on the conventional plain concrete specimen. Thus it is concluded that the volcanic scoria concrete is highly suitable as artificial reef concrete.

Study on the Nutrient Solution Content and Growth of Cherry Tomato in Scoria Culture (제주 송이를 이용한 방울토마토 양액재배시 양액성분 및 생육에 관한 연구)

  • 장전익;오대민;현해남
    • Journal of Bio-Environment Control
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    • v.4 no.1
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    • pp.43-49
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    • 1995
  • The main purpose of these studies were to clarify differences in Cheju - scoria and other solid media on quantity and quality of cherry tomatoes and on shift of component of the nutrient solution, and to use Practically Cheju-scoria as an excellent solid culture medium. The results obtained were summarized as follows ; 1. Among scoria plots, the rates of dry weights, fruits and their sugar-acid ratio were higher in the plot that was drained well with deep flow for one hour once a day. 2. Fresh fruit weights were lighter in rockwool and deep flow technique, but larger in scoria, Hyugashi (artificial gravel, $\Phi$10-12mm) and perlite in moving to higher flower cluster. 3. The results of analysis on microelement among solution components showed decrease of concentrations of P and K in the period of growth and development. 4. Yields and brix of cherry tomato showed a tendency to increase in rockwool and Hyugashi than anothers. 5. The concentration of fertilizer base was increased in general solution culture. Transpiration and absorption were similar in scoria plot and other media. 6. More studies of the Cheju-scoria development is required in order to use it as a solid medium for solution culture.

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Meat Quality Changes in Aged Pork Loin using Jeju Volcanic Scoria Earthenware

  • DongGyun Kim;SangHoon Lee;GwangHeun Kim;KyoungBo Ko;YounChul Ryu
    • Food Science of Animal Resources
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    • v.43 no.5
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    • pp.901-913
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    • 2023
  • This study aimed to investigate changes in the quality of meat aged using Jeju scoria earthenware. Water-holding properties, pH, color, tenderization, fatty acid composition, and free amino acid characteristics of aged pork loin were evaluated to determine the effects of wet and dry (normal and Jeju Scoria) aging methods and aging time (0, 10, 20, 30, and 40 days) on meat quality. The aging methods altered pH and CIE L* after 10 days of aging. However, the aging method did not alter the pH and CIE L* of the aged pork loin after 10 days of aging. The shear force was significantly lower in the Scoria aging method than in the wet aging method after 10 and 20 days of aging. Both the normal and Scoria aging methods increased aging loss compared to the wet aging method, which could be attributed to longer air exposure times of the two non-packaged aging methods than in the packaged aging method. The scoria aging method had significantly higher contents and ratios of saturated (SFA) to mono-unsaturated fatty acids but lower ratios of poly-unsaturated fatty acids to SFA than the wet aging method. The content of most free amino acids significantly increased with aging time, especially those related to the sweet, and umami categories. In summary, this study suggests that the Scoria aging method provides positive aspects of eating quality, such as improvement of meat tenderness and taste, including umami, with minimum changes in the overall meat quality.

Dyeability and Functionality of Silk Fabrics Dyed with Jeju scoria (제주 송이를 이용한 견직물의 염색성 및 기능성)

  • Im, Eun-Suk;Lee, Hye-Sun;Han, Chung-Hun
    • Textile Coloration and Finishing
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    • v.23 no.3
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    • pp.187-194
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    • 2011
  • This study used Jeju scoria to dye cotton fabric and measured its dyeability, colorfastness, antibacterial activity, deodorization efficiency, ultraviolet protection, and far-infrared emission. The cotton fabric was colored to yellowish red and optimal dyeing can be achieved at a temperature of $80^{\circ}C$ for a dyeing time of 120 minutes with a colorant concentration of 25%(o.w.b). The colorfastness to light, rubbing, perspiration, and washing was 8, 5, 5, and 4~5 ratings respectively, where the wash colorfastness remained after 15 wash cycles. The cotton fabric dyed with Jeju scoria demonstrated excellent antimicrobial activity to Staphylococcus aureus and high deodorization efficiency. Ultraviolet protection factor was as high as 50+. The Jeju scoria can be used as a new colorant for the natural dyeing of silk.

Removal of Copper ton by Na-P1 Synthesized from Jeju scoria (제주 스코리아로부터 합성된 Na-P1 제올라이트에 의한 Cu 이온 제거)

  • 감상규;홍정연;현성수;안병준;이민규
    • Journal of Environmental Science International
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    • v.11 no.1
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    • pp.75-83
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    • 2002
  • The removal performance of copper ion was studied using Na-P1 zeolites synthesized from Jeju scoria. The scoria which is found in large amounts in Jeju Island, was sampled at four regions, Jeju-shi Bonggae-dong(A). Pukcheju-gun Hanlim-eup Sangmyong-ri Mangoreum(B), Pukcheju-gun Hanlim-eup Keumag-ri(C) and Namcheju-gun Andeok-myun Dongkwang-ri(D). Synthetic Na-P1 zeolites used in this study were more effective than natural zeolite and scoria for the removal of copper ion. The removal performances of copper ion decreased in the order of Na-P1(D) > Na-P1(C) > Na-P1(B) > Na-P1(A) among Na-P1 synthesized from the scoria according to region. These results showed the same trend with cation exchange capacity(CEC) for each synthetic zeolite, i.e., the synthetic Na-P1 zeolite with a higher CEC showed a higher removal performance. The effective diffusion coefficients of copper ion by synthetic Na-P1 zeolites were one hundred and ten times higher than those by a pure zeolite 4A and the zeolite A synthesized from coal fly ash, respectively.

The photo-removal characteristic of VOCs by photocatalyst/scoria/loess concrete (광촉매가 첨가된 스코리아/황토/콘크리트의 VOCs 제거특성)

  • Ko, Seong-Hyun;Lee, Jae-Hoon;Hong, Chong-Hyun;Ryu, Seong-Phil;Kim, Moon-Hoon;Moon, Kyung-Jong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.585-588
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    • 2006
  • The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

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Effect of Solution Culture System on Growth and Mini-tuber Yield of Hydroponically Grown Potato(Solanum tuberosum L. cv. Dejima) (양액재배방식이 '대지' 감자(Solanum tuberosum L.)의 생육 형 소괴경 형성에 미치는 영향)

  • 김기택;박용봉
    • Journal of Bio-Environment Control
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    • v.6 no.3
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    • pp.198-204
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    • 1997
  • This study was conducted to investigate the effect of solution culture systems on growth and mini-tuber yields of hydroponlcally grown potato (Solanum tuberosun L. cv. Dejima). The growth of stem and foliage at 40 and 60 days after planting were better in aeroponics system than the other systems, and stem length and number of stems per plant at 90 days after planting were the greatest as of 65.4 cm, 7.3 in aeroponics and the lowest as of 49.5 cm, 3.2 in scoria media system. Stolon length was the longest as of 30.4 cm in aeroponics at 90 days after planting, and number of stolons was the greatest as of 10.5 in NFT. Number of mini-tubers per plant at 90 days after planting was 67.1, 62. 5, 20.1 and 18.0 in aeroponics, NFT, perlite and scoria media, respectively. The perlite media system made the fewest enlargement of lenticels of mini-tubers. The results indicate that aeroponic system can be used effectively for mini-tuber potato production.

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A Study on Iron Compounds of Scoria in The Western Seaside Area of Jeju (제주 서부 해안지역 스코리아의 철 화합물에 관한 연구)

  • Choi, Won-Jun;Ko, Jeong-Dae
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.227-232
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    • 2009
  • Fe compounds of scoria samples distributed in the western seaside area of Jeju island were investigated by means of X-ray fluorescence spectroscopy (XRD), X-ray diffractometry (XRF) and $^{57}Fe$ Mossbauer spectroscopy. The samples were prepared from five parasite volcanos. We found that the samples were a typical basalt from the contents ratio of $SiO_2,\;Al_2O_3$ and Fe, and that they were silicate minerals. Underwater volcanoes scoria samples are shown only doublets in Mossbauer spectra and others scoria samples are shown sextets due to hematite and magnetite. And the balence state of Fe in the underwater volcanoes scoria samples are chiefly 2+ charge state with a little of the 2+ charge state. But the balence state of Fe in the others scoria samples are chiefly 3+ charge state.