• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.380-383
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• 2004

Heavy metal release from wastewater is a serious environmental problem, and therefore, various wastewater treatment techniques have been developed. Among the techniques, sorption technique is most attractive. Considerable researches have been recently focused on finding out inexpensive sorbents, especially from various natural materials. In order to evaluate the applicability of the scoria taken from the Jeju Island, Korea to remove heavy metals (Pb, Cu, Zn, Cd) from aqueous solutions, equilibrium sorption experiments were conducted in this study. In equilibrium tests, powdered activated carbon (PAC), one of the most commonly used sorbents, was also tested to compare the effectiveness of the Jeju scoria with that of PAC. The Jeju scoria had larger adsorption capacity and affinity for metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) than PAC. The sorption parameters of the two sorbents were evaluated by using both the Langmuir and Freundlich isotherms, and the sorption data were better fitted to the Freundlich isotherm. In addition, the sorption behavior of metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) onto the scoria displayed a typical characteristic of the cation sorption. The removal of metal ions decreased at a lower pH condition due to competition with hydrogen ions for the sorption sites of Jeju scoria, while the removal increased at a high pH condition due to hydroxide precipitation.

• 공업화학
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• 제32권1호
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• pp.97-101
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• 2021

스코리아와 활성탄의 혼합 충전탑에서 중금속과 유기물의 흡착 특성, 스코리아의 물리화학적 특성과 관능기를 조사하였다. 스코리아의 혼합비율이 증가할수록 카드뮴, 니켈, 크롬, 납 이온의 평균제거율은 증가하였으나, 벤젠과 톨루엔의 평균 제거율은 감소하였다. 스코리아와 활성탄의 혼합 충전탑은 중금속과 유기물의 동시 제거에 효과적으로 사용될 수 있었다. 스코리아는 Si-H와 Si-O 작용기를 갖고 있으며, 이중 Si-O 관능기가 중금속의 흡착에 크게 기여함을 확인할 수 있었다.

• 한국해양공학회지
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• 제19권4호
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• pp.28-34
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• 2005

In the study application of volcanic scoria concrete to artificial reefs is investigated. Volcanic scoria is a natural volcanic product that shows light weight, mil/i-porous, and far-infrared irradiation characteristics. The properties of volcanic scoria concrete using Jeju scoria aggregate are evaluated by conducting a comprehensive series of tests on strength and void ratio. It is concluded that the volcanic scoria concrete has the sufficient strength of 4MPa-13MPa and adequate void ratio of $12\%-35\%$ to be accepted as artificial reef concrete. The field experiments are performed through observation by scuba diver's at the Seogwipo coast. Porous specimen and plane concrete specimen are prepared for comparison purposes. Seasonal changes of soft coral on the two series of test specimens were have been observed from Apr. 9, 2004 to Mar. 18, 2005. The soft coral is well grown on the porous specimen however there are no significant changes on the conventional plain concrete specimen. Thus it is concluded that the volcanic scoria concrete is highly suitable as artificial reef concrete.

• 생물환경조절학회지
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• 제4권1호
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• pp.43-49
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• 1995

양액재배에서 제주송이가 다른 배지와 비교하여 방울토마토의 수량 및 품질에 미치는 영향과 양액성분 변화를 조사하여 제주송이를 양액재배용 고형배지로 실용화하기 위하여 시험한 결과는 다음과 같다. 1. 건엽비, 건과비, 당산비는 1익㉣ 1회 1시간 담액후에 완전 배액한 구에서 높았다. 2. 방울토마토 생과중은 상위 화방으로 갈수록 암면구와 담액수경구는 작아졌으나, 송이구와 일향토구, 펄라이트구 등 고형배지경에서 무거웠다. 3. 방울토마토의 생육이 왕성한 시기에 양액성분중 다량원소를 분석한 결과는 송이 재배구에서 인산과 칼륨 농도가 낮았다. 4. 방울토마토의 수량과 당도는 암면과 일향토구에서 높은 경향을 보였다. 5. 일반적으로 양액재배에서는 수분의 증발과 식물의 수분 흡수 증산작용으로 비료염의 농도가 높아가는데 송이구도 다른 고형배지경과 비슷한 결과를 보였다. 6. 제주 송이 양액재배용 고형배지로 손쉽게 이용할 수 있는 가벼운 자재로 가공개발 연구가 있어야 할 것으로 본다.

• 한국축산식품학회지
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• 제43권5호
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• pp.901-913
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• 2023

This study aimed to investigate changes in the quality of meat aged using Jeju scoria earthenware. Water-holding properties, pH, color, tenderization, fatty acid composition, and free amino acid characteristics of aged pork loin were evaluated to determine the effects of wet and dry (normal and Jeju Scoria) aging methods and aging time (0, 10, 20, 30, and 40 days) on meat quality. The aging methods altered pH and CIE L^* after 10 days of aging. However, the aging method did not alter the pH and CIE L^* of the aged pork loin after 10 days of aging. The shear force was significantly lower in the Scoria aging method than in the wet aging method after 10 and 20 days of aging. Both the normal and Scoria aging methods increased aging loss compared to the wet aging method, which could be attributed to longer air exposure times of the two non-packaged aging methods than in the packaged aging method. The scoria aging method had significantly higher contents and ratios of saturated (SFA) to mono-unsaturated fatty acids but lower ratios of poly-unsaturated fatty acids to SFA than the wet aging method. The content of most free amino acids significantly increased with aging time, especially those related to the sweet, and umami categories. In summary, this study suggests that the Scoria aging method provides positive aspects of eating quality, such as improvement of meat tenderness and taste, including umami, with minimum changes in the overall meat quality.

• 한국염색가공학회지
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• 제23권3호
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• pp.187-194
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• 2011

This study used Jeju scoria to dye cotton fabric and measured its dyeability, colorfastness, antibacterial activity, deodorization efficiency, ultraviolet protection, and far-infrared emission. The cotton fabric was colored to yellowish red and optimal dyeing can be achieved at a temperature of $80^{\circ}C$ for a dyeing time of 120 minutes with a colorant concentration of 25%(o.w.b). The colorfastness to light, rubbing, perspiration, and washing was 8, 5, 5, and 4~5 ratings respectively, where the wash colorfastness remained after 15 wash cycles. The cotton fabric dyed with Jeju scoria demonstrated excellent antimicrobial activity to Staphylococcus aureus and high deodorization efficiency. Ultraviolet protection factor was as high as 50+. The Jeju scoria can be used as a new colorant for the natural dyeing of silk.

• 한국환경과학회지
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• 제11권1호
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• pp.75-83
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• 2002

The removal performance of copper ion was studied using Na-P1 zeolites synthesized from Jeju scoria. The scoria which is found in large amounts in Jeju Island, was sampled at four regions, Jeju-shi Bonggae-dong(A). Pukcheju-gun Hanlim-eup Sangmyong-ri Mangoreum(B), Pukcheju-gun Hanlim-eup Keumag-ri(C) and Namcheju-gun Andeok-myun Dongkwang-ri(D). Synthetic Na-P1 zeolites used in this study were more effective than natural zeolite and scoria for the removal of copper ion. The removal performances of copper ion decreased in the order of Na-P1(D) > Na-P1(C) > Na-P1(B) > Na-P1(A) among Na-P1 synthesized from the scoria according to region. These results showed the same trend with cation exchange capacity(CEC) for each synthetic zeolite, i.e., the synthetic Na-P1 zeolite with a higher CEC showed a higher removal performance. The effective diffusion coefficients of copper ion by synthetic Na-P1 zeolites were one hundred and ten times higher than those by a pure zeolite 4A and the zeolite A synthesized from coal fly ash, respectively.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.585-588
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• 2006

The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

• 생물환경조절학회지
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• 제6권3호
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• pp.198-204
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• 1997

감자 소괴동 산을 위해 적합한 양담재배방식을 구명코자 분무경, NFT, perlite 및 scoria 배지비을 이용하여 '대지' 품종을 공시하고 생육과 소엽도의 연성 및 준양에 미치는 영향을 조사한 결과는 다음과 같다. 1. 분무병 방식이 NFT 방식이나 Perlite 및 scoria 배지경에 비해 정식 후 40일과 60일의 지상부 생조이 좋았고, 정식후 90일에는 동윤이 65.4cm, 주당자육가 7.3개로서 가장 많았으며, scoria 배지경은 기윤이 49.5cm, 도상기육 3.2개로서 가장 적었다. 2. 포지장은 분무비에서 30.4cm로 가장 길었고, 주당각지육는 NFT 방식에서 10.5개로 많았다. 3. 정식 후 90일에 주당 괴경수는 분무경에서 67.1개, NFT 62.5개, Perlite 배지경 20.1개, scoria 배지경 18.0개였다. 4. 3g 이상의 괴대 크기 분포는 분무경 72.7％, NFT 62.6％, perlite 배지비 84.1％, scoria 배지경 83.3％로 고협배지경이 높은 분포를 보였으나 주당 괴동수가 적기 때문에 총수양 은 적었다. 5. Perlite 배지경에서 황산된 소괴경은 피일발이이 적고 표피가 매끄러워서 보질의 괴대이 생산되었다.

• 한국자기학회지
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• 제19권6호
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• pp.227-232
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• 2009

제주도 서부 해안 일원에 형성된 오름에서 채취한 스코리아의 화학적 조성 및 산화철의 원자가상태와 자기적 성질을 조사하였다. X-선 형광분석으로부터 철 화합물의 총량은 11.00$\sim$13.87 wt%이었고, X-선 회절법을 이용하여 $SiO_2$와 같은 규산염 외에 소량의 철 산화물을 확인할 수 있었다. Mossbauer분광법을 통해 광물 내의 철 성분들이 어떤 형태를 이루는지 확인하였다. 측정한 시료들로부터 olivine인 규산염과 pyroxene, ilmenite와 같은 상자성 철산화물 및 상온에서 반강자성 및 강자성 물질인 hematite와 magnetite 산화철 광물을 확인하였다. 철 화합물의 원자가상태는 일부 $Fe^{2+}$인 olivine, pyroxene 그리고 ilmenite와 $Fe^{3+}$인 hematite, magnetite, clay mineral 등을 포함하고 있다. 분석 결과 제주 서부 해안의 시료 중 수중형성으로 추정되는 스코리아 성분에 대한 철 화합물의 주 원자가 상태는 $Fe^{2+}$로 분석되었고, 나머지 육상형성으로 추정되는 스코리아 성분 내에서 철의 주 원 자가 상태는 $Fe^{3+}$로 분석되었다.