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Full Parametric Impedance Analysis of Photoelectrochemical Cells: Case of a TiO2 Photoanode

  • Nguyen, Hung Tai;Tran, Thi Lan;Nguyen, Dang Thanh;Shin, Eui-Chol;Kang, Soon-Hyung;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.244-260
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    • 2018
  • Issues in the electrical characterization of semiconducting photoanodes in a photoelectrochemical (PEC) cell, such as the cell geometry dependence, scan rate dependence in DC measurements, and the frequency dependence in AC measurements, are addressed, using the example of a $TiO_2$ photoanode. Contrary to conventional constant phase element (CPE) modeling, the capacitive behavior associated with Mott-Schottky (MS) response was successfully modeled by a Havriliak-Negami (HN) capacitance function-which allowed the determination of frequency-independent Schottky capacitance parameters to be explained by a trapping mechanism. Additional polarization can be successfully described by the parallel connection of a Bisquert transmission line (TL) model for the diffusion-recombination process in the nanostructured $TiO_2$ electrode. Instead of shunt CPEs generally employed for the non-ideal TL feature, TL models with ideal shunt capacitors can describe the experimental data in the presence of an infinite-length Warburg element as internal interfacial impedance - a characteristic suggested to be a generic feature of many electrochemical cells. Fully parametrized impedance spectra finally allow in-depth physicochemical interpretations.

Edge-based Surface Segmentation Algorithm of 3-D Image using Curvature (곡률을 이용한 3차원 영상의 에지 기반 표면 분할 알고리즘)

  • Seol, Seong-Uk;Lee, Jae-Chul;Nam, Gi-Gon;Jeon, Gye-Rok;Ju, Jae-Heum
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.38 no.2
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    • pp.199-207
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    • 2001
  • In this paper, we suggest an edge-based surface segmentation algorithm of 3D image using curvature. For the first, in this proposed method, we approximate 3D depth data to second order curves by each scan line and decide splitting points of 3D edges by curvature of the approximated curves. And finally make a group as 3D surface with the region of input image by the 3D edges. In the conventional algorithms, there are some difficulties in detecting 3D edge with the separated processes for the jump edge and the crease edge and especially, in deciding the ambiguous discontinuity of surface directions about the crease edge. The proposed algorithm decides curvature discontinuity using curvature which is simply calculated by a geometrical approximation. Furthermore, the algorithm has a cooperated process to calculate the jump and crease edges. The results of computer simulations with several 3D images show that the proposed method yields better performance as comparing with the conventional methods.

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A Case of Zollinger-Ellison Syndrome with Gastrinoma Localized by $^{111}In$-Pentetreotide Scan ($^{111}In$-Pentetreotide 스캔으로 진단 가능했던 가스트린종을 가진 Zollinger-Ellison 증후군 1예)

  • Jeong, Hyeon-Jo;Ryu, Jin-Sook;Kim, Jae-Seung;Moon, Dae-Hyuk;Jung, Hwoon-Yong;Ha, Hyun-Kwon;Lee, Hee-Kyung
    • The Korean Journal of Nuclear Medicine
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    • v.33 no.6
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    • pp.537-542
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    • 1999
  • In patient with Zollinger-Ellison syndrome, it is difficult to localize gastrinoma because the tumor is frequently small and multiple. However, accurate localization of the tumor is important for the treatment Among various imaging modalities, somatostatin receptor scintigraphy (SRS) has been recognized to be the most sensitive tool for the detection of neuroendocrine tumors such as gastrinomas based on the presence of high-affinity binding sites for somatostatin. Recently, we experienced a case of Zollinger-Ellison syndrome caused by gastrinomas which was localized by SRS. This is the first case report of gastrinoma detected by SRS in Korea. SRS can facilitate tumor detection in patient with Zollinger-Ellison syndrome and should be considered as the first-line diagnostic method in the early course of the disease.

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An Improved Method of Digital Watermarking Applied to Binary Printed Images (이진 프린트 영상에 적용하는 디지털 워터마킹의 성능 개선)

  • 김현주;곽내정;권혁봉;안재형
    • Journal of Korea Multimedia Society
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    • v.4 no.3
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    • pp.247-256
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    • 2001
  • Digital watermarking is a copyright protection technique for digital images which embed a code into the digital data so the data is marked. Watermarking techniques previously deal with on-line digital data and have been developed to withstand digital attacks such image processing, compression and geometric transformation. In this paper we propose a novel method of embedding watermarks in printed images. In the proposed algorithm, watermark is embedded in a dithered binary image by comparing the $2\times{2}$ blocks of the counting array is the number of 1 (WHITE) in the $16\times{16}$ blocks of the dithered binary image with predefined reference block pattern, which is generated by watermark values. The proposed algorithm is able to provide more information at a watermark because the proposed algorithm use both '1'and '0' as watermark values. The watermark information is detected by comparing the watermark which is reconstructed from the image which is embedded watermark with the original watermark which is embedded in a binary image. The performance of the proposed algorithm is compared with that of the conventional watermark embedding algorithm for printed images by detecting watermark for scan images.

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The Measurement of Flight Data of Golfball with High-Speed Multi-Exposure Image (고속 다중 노출 영상을 이용한 골프공의 비행 요소 측정)

  • Kim, Ki-Hyun;Park, Hyun-Woo;Ju, Woo-Suk;Lee, Dong-Hoon;Yun, Tae-Soo
    • Journal of Korea Multimedia Society
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    • v.12 no.5
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    • pp.699-707
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    • 2009
  • Recently, while 3D sports game increases, the research that it recognizes the operation of the real user actively progresses. Most of all, the research about the golf is active. In this paper, the camera acquiring in a high-speed multi-exposure image measures the flight data of the golf ball through the image processing. While photographing, the high-speed camera, using this system, exposes an image at regular intervals. And line scan camera checks whether the golf ball passed or not. After the location information of the calculated golf ball calculates a speed and a direction by using the physical formula, it applies the golf simulation. After, this system is possible the measurement of the physical element of the spherical object.

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A Study on Stereo Visualization of the X-ray Scanned Image Based on Volume Reconstruction (볼륨기반 X-선 스캔영상의 3차원 형상화 연구)

  • Lee, Nam-Ho;Park, Soon-Yong;Hwang, Young-Gwan;Park, Jong-Won;Lim, Yong-Gon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.7
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    • pp.1583-1590
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    • 2011
  • As the existing radiation scanning systems use 2-dimensional radiation scanned images, the low accuracy has been pointed out as a problem of it. This research analyzes the applicability of the stereo image processing technique to X-ray scanned images. Two 2-dimensional radiation images which have different disparity values are acquired from a newly designed stereo image acquisition system which has one additional line sensor to the conventional system. Using a matching algorithm the 3D reconstruction process which find the correspondence between the images is progressed. As the radiation image is just a density information of the scanned object, the direct application of the general stereo image processing techniques to it is inefficient. To overcome this limitation of a stereo image processing in radiation area, we reconstruct 3-D shapes of the edges of the objects. Also, we proposed a new volume based 3D reconstruction algorithm. Experimental results show the proposed new volume based reconstruction technique can provide more efficient visualization for cargo inspection. The proposed technique can be used for such objects which CT or MRI cannot inspect due to restricted scan environment.

The Effects of Bee Venom on PLA2 and Calcium Concentration in Raw 264.7 Cells (봉약침액(蜂藥針液)이 RAW 264.7 세포의 PLA2 및 Calcium Concentration에 미치는 영향(影響))

  • Yun, Jong-Il;Jo, Hyun-Chul;Sim, Sung-Yong;Kim, Kee-Hyun
    • Journal of Pharmacopuncture
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    • v.6 no.2
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    • pp.149-158
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    • 2003
  • Objective : The purpose of this study was to investigate the effect of Bee Venom on the lipopolysaccharide, sodium nitroprusside and hydrogen peroxide induced expression phospholipase $A_2$ and calcium concentration in RAW 264.7 cells, a murine macrophage cell line. Method : The expression of phospholipase $A_2$ was determined by western blotting with corresponding antibodies, and the generation of intracellular calcium concentration was investigated by delta scan system in RAW 264.7 cells. Results : 1. Compared with control, expressions of lipopolysaccharide-induced phospholipase $A_2$ were decreased significantly by $1\;{\mu}g/{\mu}l$ of bee venom and decreased by 0.5, $5\;{\mu}g/{\mu}l$ of bee venom. 2. Compared with control, expressions of sodium nitroprusside-induced phospholipase $A_2$ were decreased significantly by $5\;{\mu}g/{\mu}l$ of bee venom but increased by 0.5, $5\;{\mu}g/{\mu}l$ of bee venom. 3. Compared with control, expressions of hydrogen peroxide-induced phospholipase $A_2$ were decreased significaltly by $1{\mu}g/{\mu}l$ of bee venom and decreased by $0.5\;{\mu}g/{\mu}l$ of bee venom but increased by $5\;{\mu}g/{\mu}l$ of bee venom. 4. Compared with control, lipopolysaccharide, sodium nitroprusside and hydrogen peroxide- induced intracellular calcium concentrations were decreased by 0.5, 1, $5\;{\mu}g/{\mu}l$ of bee venom and by indomethacin

Development of Inspection System for Surface of a Shock Absorber Rod using Machine vision (머신비전을 이용한 업쇼버 로드의 표면검사 시스템 개발)

  • Kim, Seong-Jin;Lee, Seong-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3416-3422
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    • 2014
  • A shock absorber rod is located in the center of the absorber piston and is responsible for the reciprocating movement portion. If it has surface defects, the damping performance of product will be adversely affected. A rod surface has gloss by heat treatment. Therefore, it is difficult to find a defect, such as dust, imprints, and blowholes. Because a total inspection is achieved by visual inspection by workers, it causes eyestrain and the quality of the product is not constant. In this paper, a machine vision system was developed to find a defect using a line-scan camera. The machine can detect surface defects than 0.3mm. To minimize the occurrence probability of defects on the inspection process, the developed auto inspection system had an automatic feeding system and incorporated a protection system. Through the development of this system, which relies on the operator's visual inspection of the surface of the shock absorber, the Rod inspection system constructed quality inspection standards and standardized tests to ensure improved reliability.

Real-time Object Tracking using Adaptive Background Image in Video (동영상에서 적응적 배경영상을 이용한 실시간 객체 추적)

  • 최내원;지정규
    • Journal of Korea Multimedia Society
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    • v.6 no.3
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    • pp.409-418
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    • 2003
  • Object tracking in video is one of subject that computer vision and several practical application field have interest in several years. This paper proposes real time object tracking and face region extraction method that can be applied to security and supervisory system field. For this, in limited environment that camera is fixed and there is seldom change of background image, proposed method detects position of object and traces motion using difference between input image and background image. The system creates adaptive background image and extracts pixels in object using line scan method for more stable object extraction. The real time object tracking is possible through establishment of MBR(Minimum Bounding Rectangle) using extracted pixels. Also, effectiveness for security and supervisory system is improved due to extract face region in established MBR. And through an experiment, the system shows fast real time object tracking under limited environment.

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Volume Reconstruction by Cellboundary Representation for Medical Volume Visualization (의료영상 가시화를 위한 셀 경계 방식 체적 재구성 방법)

  • Choi, Young-Kyu;Lee, Ee-Taek
    • Journal of KIISE:Computer Systems and Theory
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    • v.27 no.3
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    • pp.235-244
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    • 2000
  • This paper addresses a new method for constructing surface representation of 3D structures from a sequence of tomographic cross-sectional images, Firstly, we propose cell-boundary representation by transforming the cuberille space into cell space. A cell-boundary representation consists of a set of boundary cells with their 1-voxel configurations, and can compactly describe binary volumetric data. Secondly, to produce external surface from the cell-boundary representation, we define 19 modeling primitives (MP) including volumetric, planar and linear groups. Surface polygons are created from those modeling primitives using a simple table look-up operation. Comparing with previous method such as Marching Cube or PVP algorithm, our method is robust and does not make any crack in resulting surface model. Hardware implementation is expected to be easy because our algorithm is simple(scan-line), efficient and guarantees data locality in computation time.

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