• Title/Summary/Keyword: sc-$CO_2$

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Heavy Metal Pollution in Soil and Vegetation near the Closed Daeseong Coal Mine in Keumsan, Chungnam (충남 금산 폐탄광지역의 토양 및 식물체내 중금속 오염)

  • 민일식;송석환;김명희
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.41-51
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    • 1998
  • The research was conducted to measure the heavy metal pollution of soils and vegetations adjacent to the closed Daeseong coal mine in Keumsan, Chungnam. The studied area was divided into two sites ; the coal-bearing polluted and the non-polluted without coal. The samples of the weathered soils and vegetations(Miscnthus sinenis(MS) and Pinus rigida(PR)) were collected from both area. Cr, Mo, Ni, and Fe concentrations were high in the polluted soils, whereas Co, Sc, and Zn concentrations were high in the non-polluted soils. In the vegetations, Co, Cr, Sc, and Fe concentrations in the roots of MS and PR growing on the polluted sites were higher than the above-ground. However, on the non-polluted sites, Mo and Ni concentrations had an opposite trend. In the above-ground parts, high heavy metal concentrations (except Cr) were shown in MS of the non-polluted sites, whereas in the roots, heavy metal concentrations (except Zn) were high in the polluted sites. In the average heavy metal concentrations of two plants, most elements (except Zn) were lower in the plants than the soils. Comparing with vegetations and adjacent forest soils, heavy metal concentrations of the MS were similar to those of soil concentrations relative to the PR, suggesting that absorptions of the elements were higher in the MS than the PR.

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Basic Characteristics of Slag Cement using CO2 Fixed Desulfurized Gypsum (CO2 고정 탈황석고를 사용한 슬래그 시멘트의 기초적 특성)

  • Chun-Jin Park;Jong-Ho Park;Sung-Kwan Seo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.25-31
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    • 2023
  • In this study, the basic properties of CO2 immobilized desulfurized gypsum (CFBG) and the possibility of being used as a stimulus for slag cement were reviewed, and performance evaluation was conducted through a concrete mixing test. The main components of CFBG were CaO and SO3, and CaO and SO3 increased as the drying temperature increased. The moisture content of undried CFBG was 15.7 %, the drying temperature was 1.7 % and the drying temperature was 0.03 % at 105 ℃. Mortar using CFBG tended to have a lower flow value as the drying temperature increased, and the compressive strength was equivalent to that of the FGB use mixture. As a result of the concrete experiment using CFBG SC, both slump and air volume satisfied the target range after 60 minutes, and the compressive strength tended to increase overall compared to the ternary binder mixture.

Effective Extraction of Sea Mustard with Supercritical Carbon Dioxide (초임계 이산화탄소에 의한 미역의 효과적 추출)

  • Lee Seok-Hee;Cheon Jae-Kee;Ju Chang-Sik
    • Journal of the Korean Institute of Gas
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    • v.3 no.1
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    • pp.33-40
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    • 1999
  • The extraction characteristics of lipids from powdered sea mustard have been investigated by the use of supercritical carbon dioxide($SC-CO_2$) and cosolvents. The extraction rate was increased as the particle size of the sea mustard is smaller, the pressure is higher, the temperature is lower, and the quantities of the fluid is more. However, the extraction yield of lipids from sea mustard was almost constant at a given condition. The optimum extraction condition was determined with the extraction yield of $1.45wt\%$ at 300um of particle size, 313K of $SC-CO_2$ temperature, 13.8MPa of pressure, and 30L/min of flow rate. Ethanol was the most efficient cosolvent among ethanol, methanol, and hexane. The extraction yield was increased at about 2.21times by the addition of ethanol as a cosolvent to $SC-CO_2$. As the residence time and the average concentration of lipids were decreased, the mass transfer parameter($k_fa$) was increased. But the opposite result was obtained when the ethanol was used as cosolvent.

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New Cosmetic Agents for Anti-aging from Zostera marina L. (잘피(Zostera marina L.)의 신규 항노화 화장품 소재 응용)

  • Jin-Hui, Kim;Kyung-Eun, Lee;Jin-Hwa, Kim;Young-Ho, Cho;Sung-Min, Park;Jeong-Jae, Lee;Bum-Chun, Lee;Hyeong-Bae, Pyo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.235-240
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    • 2004
  • In order to develop new anti-photoaging agents from marine natural products, Zostera marina L. was selected for its antioxidative activity and inhibition of matrix metalloproteinase-1 (MMP-1) expression. Three compounds (compounds 1, 2, and 3) were isolated from the extract, and they were identified as apigenin-7-O-${\beta}$-D-glucoside (1), chrysoeriol (2), and luteolin (3). These compounds have SC$\_$50/ values of 0.18 mM, 0.68 mM, and 0.01 mM against l,l-dipheny1-2-picrylhydrazyl radical and 0.04mM, 0.03mM, and 0.01mM against the superoxide radical in the xanthine/xanthine oxidase system, respectively. Compound 3 suppressed the expression of MMP-1 by up to 44% at 35.0${\mu}$M and inhibited the production of interleukin 6, which is known as a cytokine that induces MMP-1 expression. In addition, the wrinkle improvement effect of the formulation with Z. marina extract was measured. As a result, remarkable reduction was found in the fine wrinkle and skin roughness after application of the cream with 3.0% this extract for 8 weeks. In conclusion, the isolated compounds from Z. marina extract were good antioxidant and suppressor of MMP-1 expression and the formulation with the extract diminished the skin wrinkle. Therefore, the extract can be used as a new anti-aging agent for application in cosmetic.

Enhanced Formation of Scrapie Prion Protein in Cultured Cells by Treatment with Mycosporine-like Amino Acids (MAAs) (Mycosporine-like amino acids (MAAs) 처리에 따른 배양세포 내 스크래피 프리온 단백질의 형성증가)

  • Lee, Jihyun;Moh, Sang-Hyun;Ryou, Chongsuk;Kim, Dae-Hwan
    • Microbiology and Biotechnology Letters
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    • v.43 no.2
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    • pp.91-96
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    • 2015
  • Prions are proteinaceous infectious particles that cause neurodegenerative diseases, such as scrapie in sheep, bovine spongiform encephalopathy in cattle and Creutzfeldt-Jakob disease (CJD) in humans. Although the detailed process, regarding the abnormal conversion of prion proteins (PrP), remains to be fully elucidated, a number of environmental factors appear to affect the formation of misfolded PrP, termed PrPSc. Because oceanic algae contain mycosporine-like amino acids (MAAs), which exhibit cellular defensive activities under a variety of stress conditions, we investigated the level of PrPSc in prion-infected neuroblastoma cells using mycosporine-glycine, porphyra-334 and shinorine. When judged by the level of protease-resistant PrPSc in western blots, porphyra-334 and shinorine increased the level of PrPSc in cells, but mycosporine-glycine did not. The current results indicate that the MAAs tested in this study enhance the formation of PrPSc.

Evaluation on the Selective Combining for the Detection of M-ary DPSK Signals over Nakagami Fading Channels

  • Na, Seung-Gwan;Kim, Chang-Hwan;Jin, Yong-Ok
    • Journal of electromagnetic engineering and science
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    • v.7 no.2
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    • pp.74-82
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    • 2007
  • The performances of M-ary DPSK(MDPSK) for diversity reception theoretically are derived, using an L-branch selection combining(SC) in frequency-nonselective slow Nakagami fading channels. For integer values of the Nakagami fading parameter m, An exact closed-form symbol error rate(SER) multichannel performance that can be easily evaluated via numerical integration is presented. Finally, we compare these analyses with numerical analyses with integral-form expressions for the performance of MDPSK signals under the effect of two-branch SC diversity over slow and nonselective Rician fading channels with additive white Gaussian noise(AWGN).

Temporal and Spatial Variability of the Middle and Lower Tropospheric Temperatures from MSU and ECMWF (MSU와 ECMWF에서 유도된 중간 및 하부 대류권 온도의 시 ${\cdot}$ 공간 변동)

  • Yoo, Jung-Moon;Lee, Eun-Joo
    • Journal of the Korean earth science society
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    • v.21 no.5
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    • pp.503-524
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    • 2000
  • Intercomparisons between four kinds of data have been done to estimate the accuracy of satellite observations and model reanalysis for middle and lower tropospheric thermal state over regional oceans. The data include the Microwave Sounding Units (MSU) Channel 2 (Ch2) brightness temperatures of NOAA satellites and the vertically weighted corresponding temperature of ECMWF GCM (1980-93). The satellite data for midtropospheric temperatures are MSU2 (1980-98) in nadir direction and SC2 (1980-97) in multiple scans, and for lower tropospheric temperature SC2R (1980-97). MSU2 was derived in this study while SC2 and SC2R were described in Spencer and Christy (1992a, 1992b). Temporal correlations between the above data were high (r${\ge}$0.90) in the middle and high latitudes, but low(r${\sim}$0.65) over the low latitude and more convective regions. Their values with SC2R which included the noises due to hydrometeors and surface emission were conspicuously low. The reanalysis shows higher correlation with SC2 than with MSU2 partially because of the hydrometeors screening. SC2R in monthly climatological anomalies was more sensitive to surface thermal condition in northern hemisphere than MSU2 or SC2. The first EOF mode for the monthly mean data of MSU and ECMWF shows annual cycle over most regions except the tropics. The mode in MSU2 over the Pacific suggests the east-west dipole due to the Walker circulation, but this tendency is not clear in other data. In the first and second modes for the Ch2 anomalies over most regions, the MSU and ECMWF data commonly indicate interannual variability due to El Ni${\tilde{n}$o and La Ni${\tilde{n}$a. The substantial disagreement between observations and model reanalysis occurs over the equatorial upwelling region of the western Pacific, suggesting uncertainties in the model parameterization of atmosphere-ocean interaction.

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Coal pyrolysis behaviors at supercritical CO2 conditions

  • Hakduck Kim;Jeongmin Choi;Heechang Lim;Juhun Song
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.265-273
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    • 2022
  • In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO2 condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO2 condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO2 atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO2 pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO2 condition.

The Methodology for Extraction of Geochemical Anomalies, Using Regression Formula: an Example from a Granitic Body in Gyeonggi Province (회귀 수식을 이용한 지구화학적 이상분포지역 도출기법: 경기도화강암의 예)

  • 황상기;신성천;염승준;문상원
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.137-147
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    • 2002
  • Natural geological and environmental processes reflect to element abundances in geological materials on the surface. This study aims to elucidate a possibility of geostatistical application to differentiate geochemical anomalies affected by anthropogenic and geogenic factors. A regional geochemical map was produced using 'inverse distance weight interpolation' method for analytical results of stream sediments «150 11m) which were collected from 2,290 first- to second-order streams over the whole Gyeonggi Province. The Jurassic granitic batholith in the southeastern province was selected as a target for the geostatistical examination. Factor analysis was conducted using 22 elements for stream sediments from 445 drainage basins over the granitic body. Co, Cr, Sc, MgO, Fe$_{2}$O$_{3}$, V, and Ni were grouped with high correlation coefficients and the depletion of the components may reflect the whole-rock chemistry of the granite. Regression analysis was done using Co, Cr, and Sc as dependent variables and other six components as independent variables, and the results were drawn as maps. The maps acquired generally show quite similar distribution patterns with those of concentrations of each variable. The similarity in the spatial patterns between the two maps indicates that the application of regression statistics can be valid for the interpretation of regional geochemical data. However, some components show local discrepancies which may be influenced by secondary factors regardless of the basement lithology. The regression analysis may be effective in extracting local geochemical anomalies which may reflect rather anthropogenic pollutions than geogenic influences.

Fabrication of $(La, Sr)MO_3$ (M=Mn or Co)/YSZ Nanocomposite Thin Film Electrodes for the Exhaust Gas Purification by a Chemically-Modified Sol-Gel Process

  • Hwang, H.J.;Moon, J.W.;Awano, M.;Maeda, K.
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.201-206
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    • 2001
  • $>LaMnO_3$$(La, Sr)MO_3$, and $(La, Sr)MO_3/YSZ$ gel films were deposited by spin-coating technique on scandium-doped zirconia (YSZ) substrate using the precursor solution prepared from $La(O-i-C_3H_7)_3$, $Co(CH_3COO)_2$or $Mn(O-i-C_3H_7)_2$,2-methoxyethanol, and polyethylene glycol. By heat-treating the gel films, the electrochemical cells, $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ were fabricated. The effect of polyethylene glycol on the microstructure evolution of $$LaCoO_3and $LaMnO_3$thin films was investigated, and NOx decomposition characteristics of the electrochemical cells were investigated at $500^{\circ}C$ to $600^{\circ}C$. By applying a direct current to the $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ electrochemical cell, good NOx conversion rate could be obtained relatively at low current value even if excess oxygen is included in the reaction gas mixture.

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