• Title/Summary/Keyword: sand compounds

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On-line GC Analysis of Odorous VOC and S Gas Pollutant Levels in Ambient Air of a Residential Area at Ansan City, Korea (안산시 주거지역을 중심으로 한 환경대기 중 휘발성 유기화합물과 황계열 성분의 온라인 연속측정 연구)

  • Kim K.-H;Ju DW;Choi YJ;Hong YJ;Sa JH;Park JH;Jeon EC;Choi CR;Koo YS
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.107-118
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    • 2005
  • In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.

TCE제거를 위한 반응층과 고정화층의 결합 실험

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.67-70
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    • 2002
  • Remediation of groundwater contaminated with chlorinated organics, nitro aromatics, and heavy metals using zero valent iron (ZVI) filings has paid considerable attention in recent years. When the contaminants of high concentration leaked abundantly in subsurface environment, permeable reactive barrier technology using iron filing is taken a long time for the remediation of contaminated groundwater, The problem of contaminant shock is able to be solved using surfactant (hexadecyltrimethylammonium, HDTMA) modified bentonite (SMB) as immobilizing material. Therefore, the purpose of this research was to develop the combined remediation technology using conventional permeable reactive and immobilizing barrier for the enhanced decontamination of chlorinated compounds. Four column experiments were conducted to assess the performance of the mixed reactive materials with Ottawa sand, iron filing, and HDTMA-bentonite for trichloroethylene (TCE) removal under controlled groundwater flow conditions. TCE reduction rates with sand/iron filing/HDTMA-bentonite were highest among four column due to dechlorination of TCE by iron filing and sorption of TCE by SMB.

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Distribution and Changes of Amino Acids and Related Compounds in the Muscle Extract of the Right-eye Flounder during Heat Treatment (가자미류 육엑스분중의 아미노산 및 그 관련화합물의 분포와 가열조건에 따른 변화)

  • Moon, Soo-Kyung;An, Mi-Jeung;Han, Young-Sil;Pyeun, Jae-Hyung
    • Korean journal of food and cookery science
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    • v.6 no.3 s.12
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    • pp.43-50
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    • 1990
  • Distribution of amino acids and related compounds in the muscle extract of seven species of right-eye flounder (spotted halibut, slime flounder, marbled sole, sand flounder, stone flounder, frog fleunder and bastard halibut) were studied. The effect of heat treatment on quantitative change in the composition of amino acids and related compounds in the extract of sand fleunder muscle was also investigated since the sand flounder has much Ex-nitrogen in the extract of the muscle. The content of crude protein and that of pure protein were in the range of $17.54{\sim}19.99%$ and $15.63{\sim}17.95%$, respectively. Among the extracts of the seven fish muscle, stone flounder showed the highest content of Ex-nitrogen(2.12%). In the muscle extracts of the seven fish taurine was abundantly contained $(29.4{\sim}56.9%)$, and followed alanine $(6.6{\sim}10.4%)$ and glycine $(1.6{\sim}16.7%)$. The compositions of amino acids and related compounds were characterized by the existence of phosphoethanolamine, ${\alpha}-aminoadipic\;acid$, DL-allocystathionine, ethanolamine and ornithine. The experiments on amino acids and related compounds of the muscle extract of sand flounder with reference to heating time and temperature were resulted in that the amount of taurine, tyrosine, leucine and alanine were increased with the heating time at $100^{\circ}C$, whereas that of lysine, histidine, ${\alpha}-aminoadipic\;acid$ and proline were decreased with prolonged heating time. When heating temperature was changed from $90^{\circ}C$ to $130^{\circ}C$ for 60 min, the contents of taurine, alanine and leucine were increased, while that of histidine, lysine and aspartic acid were decreased.

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Effect of Dissolved Organic Matter and Cationic Surfactant on the Distribution of HOC in soil/water system (토양/수체 내 양이온 계면활성제와 용존유기물이 소수성유기화합물의 분포에 미치는 영향 연구)

  • 문정원;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.281-285
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    • 2000
  • The effect of the presence of dissolved organic matters(DOM) on the binding of phenanthrene to cetylpyridinium chloride(CPC) coated sand was investigated. The distribution coefficient of phenanthrene increased with increase of sufactant coverage, and decreased with the presence of dissolved organic matters except for the 1.600mg/g coverage case. Both Aldrich humic acid and extracted dissolved organic matter showed the similar tendency. For the quantification of the overall distribution coefficient, this study presented mass distribution model and estimated the sorption equilibrium coefficients of hydrophobic organic compounds(HOCs) in multi system. The suggested model combined a series of sorption equilibrium relationships including the adsorption of DOMs on sorbents, the binding between HOCs and DOMs, and the sorption of HOCs on sorbents with or without DOMs.

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Analysis of Efficiency of Artificial Wetland for Waste Water Treatment Past Six Year Operation (6년 동안 운영한 인공습지의 처리효율 분석)

  • Hur, Jai-Kyou;Nam, Jong-Hyun;Kim, Yong-Jeon;Kim, In-Seon;Choi, Kyoung-Suk;Choi, Seung-Ik;Ahn, Tae-Seok
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.10 no.3
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    • pp.1-7
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    • 2007
  • For waste water treatment, artificial wetland was constructed in 1998. The size of artificial wetland is 20m${\times}$200m, with sand and gravel as media and Phragmites japonica was implanted. The removal rate of BOD, TN, and TP were 86%, 33% and 25% from June 2004 to November 2005 respectively, while those were 88%, 38% and 55% in 1999. Organic materials and nitrogen compounds are still effectively removed, after 6 years of construction, but the removal efficiency of phosphorus compounds is reduced. So for sustaining of artificial wetland as waste water treatment system, the removal efficiency of phosphorus compounds must be elevated.

A Study on the Lime of Government Constructions Based on the Analysis of Construction Reports in the Late of Joseon Dynasty(17~19c) - Emphasized on the production, provision, and application of lime - (산릉(山陵).영건의궤(營建儀軌) 분석을 통한 조선후기 관영 건축공사의 석회에 관한 연구 - 석회의 생산.조달.적용을 중심으로 -)

  • Lee, Kweon-Yeong
    • Journal of architectural history
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    • v.18 no.6
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    • pp.23-46
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    • 2009
  • The history to have used lime in building construction was much long without distinction of the East or the West. The ancient nations of korean peninsula had used lime as construction material. The witness was discovered in the kings' tombs of fifth century. In the Joseon dynasty(15~19c), what applied several developed lime compounds to the kings' tombs have been recorded in 'Sanleong-Uigwe(山陵儀軌)' & 'Yeonggeon-Uigwe(營建儀軌)' of those days documents. Therefore, this paper is to examine the whole procedures from the product and provision of lime to its application through those days documents. Following conclusions have been reached through the study. Three lime compounds to be developed for the kings' tombs was extendedly applied to residential government buildings step by step within the current of time. These compounds to be used in the kings' tombs of the Joseon dynasty had been correlated to those of the ancient nations, which were nations of korean peninsula in narrow range, chinese and orient nations in broad range. These compounds have possibilities of development as the environmental-friendly building material. And these compounds should provide a standard specification for conservation & restoration of the traditional and cultural properties. I could confirm that the whole procedures had not been developed within limited space-time of the specified nation & period, but within interactions of the nations & periods. In the periods which disturb its interaction, the expansion of productivity in building construction was interfered.

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Volatile Flavor Components of Chestnut Honey Produced in Korea (한국산 밤꿀의 휘발성 향기성분)

  • Kang, Kui-Hwan
    • Applied Biological Chemistry
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    • v.41 no.1
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    • pp.84-88
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    • 1998
  • Composition of volatile flavor components of chestnut flower sand honey were investigated by GC and GC-MS. A total of 64 components including 14 aromatic compounds, 13 hydrocarbons, 7 fatty acids, 4 terpenes, 12 oxygenated hydrocarbons, and 7 misellaneous compounds and a total 41 components including 7 aromatic compounds, 16 hydrocarbons, 12 fatty acids, 1 terpene, 2 oxygenated hydrocarbons, and 3 misellaneous compounds were identified from total volatile concentrates of chestnut flower and honey respectively. The main components of flower volatile were 2-phenyl ethyl alcohol, 1-phenyl ethyl alcohol and benzyl alcohol which comprise 49.02% of this volatiles The main components of flower volatile were 2-phenyl ethyl alcohol, 1-phenyl ethyl alcohol and benzyl alcohol which comprise 49.02% of this volatiles. Aromatic compounds such as 2-phenyl ethyl alcohol, benzyl alcohol, 1-phenyl ethyl alcohol, 1-(2-aminophenyl) ethanone act as major contributor to the characteristic honey-like flavor of chestnut honey.

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Removal of Odorous Compounds Using Ozone and Hydrogen Peroxide (오존과 과산화수소를 이용한 이취미 물질 산화 제거)

  • Lee, Hwa-Ja;Son, Hee-Jong;Roh, Jae-Soon;Lee, Sang-Won;Ji, Ki-Won;Yu, Pyung-Jong;Kang, Lim-Seog
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.12
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    • pp.1323-1330
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    • 2006
  • In this study, five different odor causing compounds in the Nakdong river and rapid sand filtered waters were treated by oxidation from $O_3/H_2O_2$ process. In addition, the change in BDOC formation by the $O_3/H_2O_2$ process was also investigated for considering this advanced oxidation Process as a pre-treatment to the BAC treatment process. The experimental result showed that the removal efficiency of geosmin was higher with the use of 5 mg/L of $O_3$ and 0.2 mg/L of $H_2O_2$ than with the use of 20 mg/L of $O_3$ alone for the sand filtered water. And in general, the removal efficiency of geosmin in raw water was $12{\sim}27%$ lower than the one in sand filtered water. In sand filtered water. the removal efficiencies of geosmin and IPMP decreased when $H_2O_2/O_3$ ratio increases above the optimum ratio. The optimum ratio of $H_2O_2/O_3$ dose was $0.5{\sim}1.0$ for geosmin and $0.2{\sim}1.0$ for IPMP. However, the optimum ratio of $H_2O_2/O_3$ in raw water remove geosmin appealed to $1.0{\sim}3.0$. According to the experimental results for the removal of 5 different odor causing compounds under varied $O_3$ doses, the removal efficiency of IPMP was the highest with 60% and, in overall, $O_3/H_2O_2$ process showed higher removal efficiency than $O_3$ alone process. The BDOC formation by the $O_3/H_2O_2$ process increased from $0.1{\sim}0.25$ to $0.19{\sim}0.34$ comparing to $O_3$ process alone. Therefore, it is concluded that the advanced oxidation process with $O_3/H_2O_2$ can be used as a pretreatment to the BAC treatment process.

Laboratory Tests for Trichloroethylene (TCE) and Toluene Remediation in Soil Using Soil Vapor Extraction (토양증기추출(Soil Vapor Extraction)을 이용한 토양 내 Trichloroethylene (TCE)과 Toluene정화 실험)

  • 이민희;강현민
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.221-227
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    • 2002
  • Column experiments were performed to evaluate the removal efficiency of soil vapor extraction (SVE) iota TCE (trichloroethylene) and toluene in soil. Homogeneous Ottawa sands and real soils collected from contaminated area were used to investigate the effect of soil properties and SVE operation conditions on the removal efficiency. In column teats with two different sizes of Ottawa sand, the maximum effluent TCE concentration in a coarse sand column was 442 mg/L and 337 mg/L in a fine sand column. However, after 20 liter gas flushing, the effluent concentrations were very similar and more than 90% of initial TCE mass were removed from the column. For two real contaminated soil columns, the maximum effluent concentration decreased 50% compared with that in the homogeneous Ottawa coarse sand column, but 99% of initial TCE mass were extracted from the column within 40 liter air flushing, suggesting that SVE is very available to remove volatile NAPLs in the contaminated soil. To investigate the effect of contaminant existing time on the removal efficiency, an Ottawa sand column was left stable for one week after TCE was injected and the gas extraction was applied into the column. Its effluent concentration trend was very similar to those for other Ottawa sand columns except that the residual TCE after the air flushing showed relatively high. Column tests with different water contents were performed and results showed high removal efficiency even in a high water content sand column. Toluene as one of BTEX compounds was used in an Ottawa sand column and a real soil column. Removal trends were similar to those in TCE contaminated columns and more than 98% of initial toluene mass were removed with SVE in both column.

Content of Benzo(a)pvrene and Heavy Metals and Physico-chemical Properties of Turfgrass Playground Soil in Elementary School of Jeollabuk-do (천연잔디시공 학교운동장 토양중 벤조피렌 및 중금속 오염물질의 함량 - 전라북도 초등학교를 중심으로 -)

  • Park, Bong-Ju;Kim, Sei-Cheon;Cho, Jae-Young
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.3
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    • pp.39-49
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    • 2008
  • A study was carried out on the physico-chemical properties of soil and content of heavy metals and benzo(a)pyrene that might have been introduced through by-product fertilizers or air pollution to growing turfgrass at natural turfgrass playgrounds in elementary schools located at the western coast and eastern mountain areas in Jeollabuk-do, Korea. The soil of turfgrass playgrounds is composed of loamy sand, and the CEC and organic matters were very low. Compared to agricultural land in Korea, the concentrations of nitrogen, phosphorus and potassium were very low, requiring control in terms of nutrients. The contents of total and fraction heavy metals in soil were found to be background level. The reason may lie in the fact that unpolluted sand soil or sand was used to construct the foundation for the natural grass playground in the first place. However, any change in oxidation-reduction conditions or acceleration of decomposition of organic compounds may release some heavy metals from the soil and be transformed into forms that may be easily absorbed by plants or grass. It is believed that sustained monitoring and environment impact assessments should be carried out. The contents of benzo(a)pyrene in soil showed an average 0.60ng/g with a range between 0.06 to 1.47ng/g. The detected contents were found as background level.