• Title/Summary/Keyword: sample injection method

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Characteristic of Strength Increase in Clayey Soil by Electrokinetic Injection (동전기 주입에 의한 점성토의 강도증가 특성)

  • Kim, Ki-Nyun;Kim, Jong-Yun;Han, Sang-Jae;Kim, Soo-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.910-915
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    • 2005
  • In this study a series of tests(bench scale test) are carried out for increasing in strength of clayey soil by EK-Injection method. In addition, the effects of strength increase in the treated sample are measured by operating the vane shear test device during 25 days at 5 days intervals in order to estimate the effect of ground improvement caused by diffusion. The test results show that the strength increase was developed approximately double to 7 times in comparison to initial shear strength, and outstanding strength increase was created as much as 7 times while injecting the sodium silicate and phosphoric acid in anolyte and catholyte. In addition, the measured shear strength with the influence of diffusion and reduction of water-content had a tendency to converge in constant value in proportion to elapsed time. As a result of this study, strength increment developed by the influence of EK-Injection and diffusion rather than the reduction of water-content were high as 1000% on average

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Automatic Analysis of Volatile Basic Nitrogen of Pork with an On-line Flow Injection Analysis System (온-라인 FIA시스템에 의한 돈육의 휘발성염기질소의 자동분석 -연구노트-)

  • 이형춘
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.965-967
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    • 2000
  • An on-line FIA system in place of traditional Conway method was used for quicker and simpler analysis of volatile basic nitrogen of pork. The on-line system was developed by connecting an FIA apparatus with an ammonia electrode as a detector to a personal computer. The data from Conway method and from the on-line FIA system were in good agreement and the correlation coefficient was 0.981. One sample could be analyzed in about 4 min.

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Hyperthermia Properties of Fe3O4 Nanoparticle Synthesized by Hot-injection Polyol Process (Hot-injection Polyol 공정에 의해 제조된 Fe3O4 나노입자의 Hyperthermia 특성)

  • Lee, Seong Noh;Kouh, Taejoon;Shim, In-Bo;Shim, Hyun Ju
    • Journal of the Korean Magnetics Society
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    • v.24 no.2
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    • pp.51-55
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    • 2014
  • The $Fe_3O_4$ nanoparticle was synthesized by the hot-injection method while varying the injection time of the precursor solution. The crystal structure was determined to be cubic inverse spinel with space group of Fd-3m based on X-ray diffraction (XRD) measurements and the morphology of the prepared $Fe_3O_4$ nanoparticle was studied with a high-resolution transmission electron microscope (HR-TEM). When the precursor solution was injected for 0.5 min, the size of the $Fe_3O_4$ nanoparticle was 7.63 nm, while the size of the obtained particle was 21.27 nm with the injection time of 60 min. The magnetic properties of the prepared $Fe_3O_4$ nanoparticle were investigated by both vibrating sample magnetometer (VSM) and $^{57}Co$ M$\ddot{o}$ssbauer spectroscopy at various temperatures. From the hyperthermia measurement, we observed that the temperature of the $Fe_3O_4$ nanoparticle powder reached around $120^{\circ}C$ under 250 Oe at 50 kHz, when the injection time of the precursor solution was 60 min.

Effects of Soaansintang(SOAT) on the hemodynamics and electrocardiogram of isolated rat hearts induced by electrical stimulation (소아안신탕(小兒安神湯)이 STRESS를 유발한 흰쥐의 적출심장(摘出心臟)에 미치는 영향)

  • Lee Seung-Jun;Lee Jin-Yong;Kim Deok-Gon
    • The Journal of Pediatrics of Korean Medicine
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    • v.14 no.2
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    • pp.1-32
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    • 2000
  • It has long been known that SOAT is effective for sudden palpitation occurring unexpectedly in Oriental Medicine. However, effect of SOAT on the isolated heart has not been studied yet. The purpose of this study is to investigate the effect of SOAT on hemodynamics and ECG of isolated rat hearts induced by electrical stimulation using Langendorff perfusion apparatus for nonworking heart. SOAT extract was manufactured by water-alcohol precipitated method. Sprague-Dawley rats weighting $120{\sim}150g$ were used for the experiments, Subject animals were divided into four groups, which are consisted of 1) control(Group orally administered by normal saline 1ml for 14days), 2) sample A(Group orally administered by SOAT extract 1ml for 14days), 3) sample C(Group injected by SOAT extract 0.5ml after stimulation, 4) sample C(Group injected by SOAT extract 1ml after stimulation. To evluate the effects of SOAT on hemodynamics and ECG of isolated rat heart induced by stimulation, heart rate, left ventricular pressure, systolic power, diastolic power, coronary artery perfusion volume and ECG were measured using Langendorff apparatus in both stimulation mode(5 volts, 450 beats/min) and arrythmic mode(5 volts, 420 beats/min including 60 beats/min) The results obtained are as follows : 1. After receiving stressful electrical stimuli, isolated heart showed the heart rate, left ventricular pressure, systolic power, diastolic power, coronary artery perfusion volume were all decreased temporarily, but perfusion continued longer recovery to the control state appeared. However, the coronary artery perfusion volume diminished continuously. 2. The heart rates did not change significantly with both stimulation mode and arrhythmic mode, among experimental groups. 3. The left ventricular pressure showed with both stimulation mode and arrhythmic mode, the significant changes(p<0.05) especially in the injection sample group. In case of stimulation mode, low concentration injection group(0.5ml) was more significantly increased rather than high concentration group(1ml) and in case of arrhythmic mode, high density group(1ml) was so increased than the other(0.5ml). 4. For the systolic power and diastolic power, no significant changes were noticed in the stimulation mode, but in the arrhythmic mode of injection sample groups, significant change(p<0.05) was noticed in both systolic power and diastolic power. Specially the high concentration group(1ml) showed more significant increase than the low concentration group. 5. For the coronary artery perfusion volume, no significant change difference among sample groups was observed in both the stimulation mode and the arrhythmic mode. 6. For the ECG recordings, arrhythmia was induced by electrical stimulus of arrythmia mode and after the stimulus was removed, irregular wave appeared temporarily, but as perpusion continued, recovery to the control state was abtained like the stimulation mode. According to the above results, SOAT significantly changed the hemodynamic data from the electrically stressed, isolated hearts of connected Langendorff perfusion apparatus and we propose SOAT has the direct effects on the muscular function of heart.

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A Sensitive Procedure for the Rapid Determination of Mandelic Acid by Flow Injection Analysis and Chemiluminescence Detection

  • Alam, Seikh Mafiz;Jeon, Chi-Wan;Karim, Mohammad Mainul;Lee, Sang-Hak;Wabaidur, Saikh Mohammad;Suh, Yeoun-Suk;Chung, Hye-Young
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.102-106
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    • 2009
  • A rapid and sensitive chemiluminescence (CL) method using flow-injection (FI) has been developed for the determination of mandelic acid which is based on the enhancement of mandelic acid to the CL intensity of ${Ru(bipy)_{3}}^{2+}$-Ce(IV) system. The enhancement effect was dependent on the concentration of mandelic acid, based on which, CL system was established for the determination of mandelic acid. The concentrations of ${Ru(bipy)_{3}}^{2+}$+, Ce(IV), and $H_2SO_4$ were optimized. Under the optimum experimental conditions, the linear range and detection limit are 1.46-342.0 ${\mu}g/ml$ and 0.072 ${\mu}g/ml$, respectively. The correlation coefficient (R) was 0.99732. The utility of this method was demonstrated by determining mandelic acid in capsules and human urine sample.

A Study on the Process Optimization of Microcellular Foaming Injection Molded Ceiling Air-Conditioner 4-Way Panel (초미세발포 사출성형을 이용한 천정형 에어컨 4-way 판넬의 공정 최적화에 관한 연구)

  • Kim, Joo-Kwon;Lee, Jung-Hee;Kim, Jong-Sun;Lee, Jun-Han;Kwak, Jae-Seob
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.6
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    • pp.98-104
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    • 2018
  • Deflected 4-way panels of ceiling air conditioners produced by injection molding process have caused dew condensation at the edge of products. In order to prevent this drawback with reducing weight and deformation, this study proposed renovated process adopting microcellular foaming. According to results from 2-sample t-test and analysis of variance(ANOVA), the critical factors affecting weight were melt temperature and injection speed. In addition, the vital effects on deformation were structure at the edge, mold temperature and cooling time. Optimal conditions of these parameters were derived by regressive analysis with CAE and response surface method(RSM), and then applied to an actual design and process stage to analyze performance. As a results, it clearly showed that new process improved process capability as well as reduced both weight and deformation by 18.8% and 71.9% respectively compared to the conventional method.

A Metal Enhanced Flow-Injection Chemiluminescence Method for the Rapid Determination of Norfloxacin in Pharmaceutical Formulations and Serum Sample

  • Kamruzzaman, Mohammad;Ferdous, Taslima;Alam, Al-Mahmnur;Lee, Sang-Hak;Kim, So-Yeun;Kim, Young-Ho;Kim, Sung-Hong
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.639-644
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    • 2011
  • A simple and highly sensitive chemiluminescence method to determine norfloxacin (NFLX) has been proposed by measuring the chemiluminescence (CL) intensities using a flow injection (FI) system. The CL intensity of the luminol-$H_2O_2$ system is strongly enhanced by the addition of Cu (II) in alkaline condition. The CL intensity is substantially increased after the injection of NFLX into the luminol-$H_2O_2$-Cu (II) system. The enhancement effect is attributed to a catalytic effect of Cu (II) due to the interaction with NFLX which forms a complex with the catalyst. Under the optimal conditions, the sensitizing effect of the CL intensity is proportional to the concentration of NFLX in the range of $1.5{\times}10^{-9}-5.9{\times}10^{-7}molL^{-1}$ (r = 0.9994) with a detection limit ($3{\sigma}$) of $2.98{\times}10^{-10}molL^{-1}$. The proposed method had good reproducibility with the relative standard deviation (RSD, n = 5) of 1.6% for $1{\times}10^{-7}molL^{-1}$ of NFLX. The possible reaction mechanism of the CL reaction is also discussed. This method has been successfully applied for the determination of trace amount of NFLX in pharmaceutical preparations and serum samples.

A Comparative Analysis of Whole Blood Cadmium by Atomic Absorption Spectrophotometry with a Graphite Furnace (흑연로 원자흡수분광법에 의한 혈액중 카드뮴 정량분석)

  • Park, Jong An;Oh, Hye Jeong;Lee, Jong Hwa
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.301-312
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    • 1996
  • This study was performed to search a optimal analyzing method of cadmium in whole-blood. Cadmium was determined by graphite furnace atomic absorption spectrometry(GFAAS). We investigated the effect of ashing temperature on the absorbance of cadmium in a simple dilution(ten-fold) method with triton X-100 and matrix modifier methods treated with $NH_4H_2PO_4$(1 and 3%) and $Pd(NO_3)_2$(0.00l and 0.005%) as matrix modifier. We also compared the reported reference values of standard blood with values resulted from optimal analyzing conditions of this study. In case of a simple dilution method, when ashing temperature was set at $450^{\circ}C$, the absorbance of sample and background were $0.334{\pm}0.012$ and $1.382{\pm}0.245$, respectively. Background level was higher than the value(0.8) that can be corrected by $D_2$ background correction method. As ashing temperature was rised to $500^{\circ}C$, the absorbance of sample and background were $0.178{\pm}0.008$ and $0.711{\pm}0.223$ respectively. The higher ashing temperature($450^{\circ}C-650^{\circ}C$) was, the lower the absorbance of sample was. In case of a matrix modifier method with $NH_4H_2PO_4$(1 and 3%), when ashing temperature was rised from $500^{\circ}C$ to $650^{\circ}C$, the absorbance of sample slightly changed. The absorbances of sample at $600^{\circ}C$ were $0.230{\pm}0.017$ and $0.137{\pm}0.012$, respectively. These values were larger than that of simple dilution method. But the absorbance of background was higher than the level that can be corrected by $D_2$ method. In case of a matrix modifier method with $Pd(NO_3)_2$(0.001 and 0.005%), the absorbance of sample and background were higher than those of other methods and were stable and reproducible. When ashing temperature was over $550^{\circ}C$, the absorbance of sample was significantly decreased. In case of 0.005% $Pd(NO_3)_2$ carbon residue remained in graphite tube affected the absorbance of sample and background. From these results, We propose that in case of a simple dilution(ten-fold) method with triton X-100 ashing temperature must be maintained below $400^{\circ}C$. In order to diminish the absorbance of background, the alternative method is attenuation of injection volume or multiplication of dilution ratio. We recommend $Pd(NO_3)_2$ than $NH_4H_2PO_4$ as a matrix modifier. In case of a matrix modifier method with $Pd(NO_3)_2$ ashing temperature might be maintained below $550^{\circ}C$.

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Improvement of Modulation Index in 3-phase Inverters using Shunt Resistors (션트저항을 이용한 3상 인버터의 전압 변조지수 증대)

  • Kim, Jung-Dae;Choi, Jong-Woo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.3
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    • pp.374-382
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    • 2018
  • This paper has done a hardware-based approach to increase the modulation index in 3-phase inverters, unlike the conventional software algorithm-based approaches. The minimum required time to measure the currents in a three-phase inverters with shunt resistors has also been analyzed. By the analysis, the longest time in minimum required time is AD conversion time. To shorten the minimum required time, this paper proposed a sample-and-hold(S/H) circuit implemented at the inverter current signal output to retain the current signal. When the linear operation region of an inverter with S/H was compared with that without it, the modulation index was increased by 7.8 %. Inverters with S/H circuits can employ the traditional software algorithms, such as the voltage injection method or current restoration method, and it will yield further increase the modulation index.

A Numerical Study on Combustion-Stability Rating of Impinging-Jet Injector Using Air-Injection Technique (공기분사 기법을 이용한 충돌형 제트 분사기의 연소 안정성 평가에 관한 수치적 연구)

  • Sohn, Chae-Hoon;Park, I-Sun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.11 s.254
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    • pp.1093-1100
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    • 2006
  • Combustion stability rating of jet injector is conducted numerically using air-injection technique in a model chamber, where air is supplied to oxidizer and fuel manifolds of the model five-element injector head. A sample F(fuel)-O(oxidizer)-O-F impinging-jet injector is adopted. In this technique, we can simulate mixing process of streams flowing through oxidizer and fuel orifices under cold-flow condition without chemical reaction. The model chamber was designed based on the methodologies proposed in the previous work regarding geometrical dimensions and operating conditions. From numerical data, unstable regions can be identified and they are compared with those from air-injection acoustic and hot-fire tests. The present stability boundaries are in a good agreement with experimental results. The proposed numerical method can be applied cost-effectively to stability rating of jet injectors when mixing of fuel and oxidizer jets is the dominant process in instability triggering.