• 제목/요약/키워드: salt type and concentration

검색결과 146건 처리시간 0.028초

중성염 용액 내에서 우라늄으로 오염된 금속성 해체폐기물의 전해제염 (Electrolytic Decontamination of the Dismantled Metallic Wastes Contaminated with Uanium Compounds in Neutral Salt Solutions)

  • 최왕규;이성렬;김계남;원휘준;정종헌;오원진
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.72-80
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    • 2004
  • 국내의 가동 중지된 우라늄 변환시설의 해체 시 다량의 우라늄으로 오염되어 있는 금속성 폐기물의 재활용 또는 자체처분을 위한 제염기술로 중성염 전해액을 사용하는 전해제염 공정의 적용성을 평가하기 위하여 우라늄 변환시설 내부설비의 주 구성 재료인 SUS-304 및 Inconel-600에 대한 전기화학적 용해거동 연구를 수행하였다. 이를 위하여 중성염 전해질의 형태, 전해질의 농도, 전류밀도, 처리시간과 같은 전해제염 조건들이 금속 재료의 용해에 미치는 영향을 평가하였다. 모의 시편을 사용한 비방사성 전해용해 실험 결과를 근거로 실제 우라늄 변환시설로부터 인출한 $UO_2$, AUC (ammonium uranyl carbonate) 및 ADU (ammonium diuranate) 오염시편에 대해 $Na_2SO_4$$NaNO_3$ 중성염 용액에서 전해 제염실험을 수행하였으며, 오염물의 종류 및 오염 준위의 대소와는 관계없이 모든 시편에 대하여 10분 이내의 짧은 시간 내에 자체처분 기준치 이하로 $\beta$ 방사능 준위를 감소시킴으로써 본 중성염 전해제염이 매우 성공적임을 확인하였다.

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Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes

  • Garcia-Payo, M.C.;Essalhi, M.;Khayet, M.;Garcia-Fernandez, L.;Charfi, K.;Arafat, H.
    • Membrane and Water Treatment
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    • 제1권3호
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    • pp.215-230
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    • 2010
  • Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.

Overexpression of Cotton Glutathione S-Transferase (GST) cDNA and Increase of low Temperature and Salt Tolerance in Plants

  • Kang, Won-Hee;Jong Hwa kim;Lim, Jung-Dae;Yu, Chang-Yeon
    • Journal of Plant Biotechnology
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    • 제4권3호
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    • pp.117-122
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    • 2002
  • Cotton Glutathione S-Transferase(GST: EC 2.5.1.18) was cloned and Gh-5 cDNA was overexpressed in tobacco (Nicotiana tabacum) plants. The transformation of cotton GST in tobacco plant was confirmed by northern blot analysis. Type I and Type II transcript patterns were identified in Gh-5 transgenic tobacco plants. Type I transcripts was only discussed in this paper. Glutathione and 1-chloro-2,4-dinitrobenzene (CDNB) were used as the substrates, and the activity of GST in the type I transgenic plants was about 2.5-fold higher than the non-expressers and wild type tobacco plants. The expression of cotton GST in tobacco plants proved that Gh-5 could be translated into functional protein. Type I transgenic plants produced functional GST in the cells. Type I showed higher GST specific activity than Type II in the transgenic plants. Control and transgenic seedlings were grown in the growth chamber and under the light at 15$^{\circ}C$, and the effects of cotton GST in the seedlings was evaluated. The growth rate of Gh-5 overexpressors was better than the control and non-transgenic tobacco plants. Salinity tolerance was also analyzed on the seeds of transgenic plants. Seeds of Gh-5 overexpressors and the wild type tobacco seedlings were germinated and grown at 0, 50, 100, 150, and 200 mM NaCl solution. Gh-5 transgenic seedlings showed higher growth rate over control seedlings at both 50 and 100 mM NaCl solution. But at 0, 150, and 200 mM NaCl concentration, the difference in growth rate was not detected.

Mathematical Modeling on AC Pollution Flashover Performance of Glass and Composite Insulator

  • Prakash, N.B.;Parvathavarthini, M.;Madavan, R.
    • Journal of Electrical Engineering and Technology
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    • 제10권4호
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    • pp.1796-1803
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    • 2015
  • While considering the current scenario, in this world power demand goes on increases day by day. Frequent power outages occur in high voltage transmission line due to the deprived performance of polluted insulators; this affects overall operation of power system and may indirectly impinge on the growth of production sector. Many researchers are keenly taking efforts to provide highly reliable and stable power to neediest. In this paper, A.C pollution flashover performance of disc type glass insulator and composite long rod insulators investigation under various artificial pollutions by varying Equivalent Salt Density Deposition (ESDD) levels. Here, we use different types of pollution methods like binding method, dipping method and spraying methods with different types of pollutants concentration. Based on dimensional analysis, four different Mathematical models have been developed to predict the A.C pollution Flashover Voltage (FOV) of insulators. Both the experimental and mathematically modeled results are compared; it's observed that mathematical model 3 yields better results.

미꾸라지 렉틴 성분의 생화학적 특성 (Biochemical Studies on Lectins from Misgurnus spp.)

  • 정시련;김장환;소명숙;김무경;현태금;전경희
    • 약학회지
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    • 제35권5호
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    • pp.444-455
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    • 1991
  • Two kinds of new lectin fractions (LOA-I, LOA-II) were obtained from loach (Misgurnus spp.) meat by 0.15 M NaCl extraction, salt fractionation, ion exchange and hydroxyapatite column chromatographies. On polyacrylamide gel electrophoresis, LOA-I exhibited one major and a few minor bands, but LOA-II exhibited three minor bands. The partially purified loach lectins agglutinated not only erythrocytes of human B and AB type, rabbit, dog, but also murine splenic lymphocytes. Agglutinability was relatively labile at various pH and stable at increasing temperature, but was not affected by tested several metal ions. By the sugar specificity test, D-glucosamine and metyl-$\beta$-galactopyranose inhibited agglutinating activity at a final concentration of 3 mM. The lectins contained relatively high amounts of aspartic acid, valine and leucine, but sulfur containing amino acids, cystein, methionine and isoleucine were not determined. LOA-I, LOA-II lectins were nonmitogenic toward murine lymphocytes.

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Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.187-187
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    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

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한국재래식(韓國在來式) 간장의 발효미생물(醱酵微生物)에 관(關)한 연구(硏究)(제2보(第二報)) -한국재래식(韓國在來式) 간장의 담금중(中)에 있어서의 발효미생물군(醱酵微生物群)의 소장(消長)에 관(關)한 연구(硏究)- (Microbiological Studies of Korean Native Soy-sauce Fermentation -A Study on the Microflora Changes during Korean Native Soy-sauce Fermentation-)

  • 이우진;조덕현
    • Applied Biological Chemistry
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    • 제14권2호
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    • pp.137-148
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    • 1971
  • 한국재래식(韓國在來式) 메주를 전국(全國) 5개도(個道)에서 수집(收集)하여 메주 표면부분(表面部分), 내부부분(內部部分), 재래식(在來式) 메주 및 일본식(日本式) 방법(方法)을 도입(導入)한 개량식(改良式) 메주로 간장을 담그어 담금 중의 미생물(微生物) 소장(消長)에 관(關)하여 연구(硏究)하고 이들 미생물(微生物)의 flora에 영향(影響)을 주는 pH, 총산(總酸), 식염농도(食鹽濃度), 총질소(總窒素)를 조사(調査)하였다. 아울러 한국전성(韓國全城) 14개(個) 지방(地方)에서 현재(現在) 식용중(食用中)인 재래식(在來式) 간장을 수집(收集)하여 microflora 및 화학적성분(化學的成分)을 측정(測定)하여 다음과 같은 결과(結果)를 얻었다. 1. 한국재래식(韓國在來式) 간장의 주발효미생물군(主醱酵微生物群)을 구명(究明)한 결과 호기성(好氣性) 세균군(細菌群)은 Bacillus subtilis와 Bacillus pumilus 유산균군(乳酸菌群)은 Pediococcus halophilus 및 Leuconostoc mesenteroides, 그리고 효모군(酵母群)은 Rhodotorula flava, Torulopsis datila 및 Saccaromyces rouxii이었다. 2. 한국재래식(韓國在來式) 간장, 담금 중의 발효미생물(醱酵微生物)의 소장(消長)은 먼저 호기성(好氣性) 세균(細菌)이 담근후 2주(週)까지 증가(增加)하고 다음 호기성(好氣性)이 3주(週)쯤에 최고(最高)의 증식(增殖)을 보여 유균(乳菌) 등(等)의 유기산함량(有機酸含量)을 높이고 pH를 5,4부근(附近)으로 강하(降下)시킨 다음에 효모(酵母)가 증식(增殖)하기 시작(始作)하여 발효(醱酵)에 참여하고 있다. 유산균(乳酸菌)은 생산(生酸)에 의(依)해 자신(自身)과 호기성(好氣性) 細菌)과 생육(生育)을 조해(阻害)하고 있으며 담금 2개월(個月) 후(後)엔 모든 발효미생물(醱酵微生物)이 감퇴기(減退期) 내지(乃至) 사감기(死減期)에 접어들고 달인 뒤에는 대부분(大部分) 사감(死減)하고 소수(少數) Bacillus sp.만이 잔존(殘存)하나 담금액(液)의 조성(組成)에 따라 효모(酵母)와 유산균(乳酸菌)이 극소수(極少數) 잔존(殘存)하고 있는 경우도 있었다. 3. 담금중의 microflora에 영향(影響)을 주는 성분(成分)의 변화(變化)를 조사(調査)한바 간장의 전(全)담금 기간(其間)을 통(通)하여 총산(總酸), 식염농도(食鹽濃度) 및 총질소(總窒素)는 점차 증가(增加)하고 있으며 pH는 약(約) 4.5 정도(程度)까지 강하(降下)하고 있다. 4. Microflora는 주(主)로 식염농도(食鹽濃度)와 pH에 지배(支配)되는 것 같았다. 호기성세균(好氣性細菌)은 포자(胞子)의 형성(形成)으로 가장 생존력(生存力)이 강(强)한 것 같으며 유산균(乳酸菌)은 식염농도(食鹽濃度) $23{\sim}26%$, pH 4.8에서 생육(生育)이 조해(阻害)되었으며 효모(酵母)는 담금액(液)의 pH가 5.4 이하(以下)에서 비로소 발육(發育)을 시작(始作)하였고 pH $4.5{\sim}4.7$에서의 한계식염농도(限界食鹽濃度)는 26% 전후(前後)로 보였다. 5. 한국재래식(韓國在來式) 간장 재활과정중(製活過程中)의 지징(持徵)인 장시간(長時間)의 장달이기는 본(本) 실험결과(實驗結果)에서 보면 살균(殺菌) 단백질(蛋白質)의 응고(凝固) 식염(食鹽) 및 기지(基地) 성분(成分)의 농축(濃縮) 등(等)에 있어서 매우 효과적(效果的)인 방법(方法)이라는 것이 명백(明白)하다. 달인 후(後)의 간장의 숙성(熟成)은 미생물학적(微生物學的)이라기 보다는 오히려 화학적(化學的) 숙성(熟成)이 주(主)가 되는 것이라고 인정(認定)되었다. 6. 전국(全國)에서 수집(收集)한 한국재래식(韓國在來式) 간장의 발효미생물(醱酵微生物)의 평균생균수(平均生菌數)는 호기성세균(好氣性細菌) $53{\times}10^2$개/ml, 유산균(乳酸菌) 34개/ml, 효모(酵母) 14개/ml이었고 제화학성분(諸化學成分)의 평균치(平均値)는 식염농도(食鹽濃度) 28.9%, pH=4.79, 총산(總酸)(유산(乳酸)) 0.91g/100ml, 총질산(總窒酸) 1.09g/100ml이었다.

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죽염된장의 항산화 및 HT-29 암세포에서 in vitro 항암 효과 (Antioxidative and Anticancer Effects of Doenjang Prepared with Bamboo Salt in HT-29 Human Colon Cancer Cells)

  • 심정하;박의성;김인석;박건영
    • 한국식품영양과학회지
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    • 제44권4호
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    • pp.524-531
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    • 2015
  • 죽염된장의 발효기간(3년, 6년)과 죽염의 구운 횟수($3{\times}$, $9{\times}$)에 따른 항산화 및 HT-29 암세포에서 in vitro 항암 효과를 측정하였다. 죽염된장의 발효 기간에 따른 pH 및 아미노태 질소, 암모니아태 질소 함량은 3B-S($3{\times}$, 삶은 콩)를 제외하고는 큰 차이가 없는 것으로 나타났다. 총 폴리페놀 함량은 6Y9B-D(6년, $9{\times}$)가 유의적으로 가장 함량이 높았다(P<0.05). DPPH free radical 소거 효과에서는 6Y3B-D(6년, $3{\times}$)는 $34.1{\pm}0.4%$, 6Y9B-D는 $38.2{\pm}2.5%$, hydroxyl radical 소거 효과 역시 6Y3B-D는 $80.8{\pm}0.9%$, 6Y9B-D는 $86.2{\pm}2.0%$로 높은 소거 효과를 나타내었다. HT-29 인체 대장암세포를 이용한 암세포 성장 억제 효과 역시 6Y3B-D는 $65.9{\pm}2.4%$, 6Y9B-D는 $72.8{\pm}1.7%$로 가장 높은 성장 억제율을 나타내었다. TNF-${\alpha}$, IL-6과 iNOS, COX-2 염증 유발 인자에서 6Y9B-D군이 유의적인 차이를 보이며 mRNA의 발현을 가장 많이 억제하는 것으로 나타났다. 장기간 숙성된 6년 죽염된장이 3년 죽염된장보다 항산화, 항암 효과가 뛰어났고, 3회 죽염보다 9회 죽염을 첨가한 된장이 천일염과 정제염을 혼합해 제조한 시판된장보다 항산화, 항암 효과가 더 우수했다.

Simple and Direct Quantitative Analysis for Quinidine Drug in Fish Tissues

  • Chen, Yuan-Chin;Abdelhamid, Hani Nasser;Wu, Hui-Fen
    • Mass Spectrometry Letters
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    • 제8권1호
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    • pp.8-13
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    • 2017
  • Analysis of quinidine for fish tissues using single drop microextraction (SDME) coupled with atmospheric pressure matrix assisted laser desorption/ionization mass spectrometry (AP-MALDI-MS) are reported. Optimization conditions; such as extraction solvent, extraction time, pH of the aqueous solution, salt additions (NaCl), stirring rate, matrix type and concentration are investigated. Linear dynamic range (${\mu}M$), limit of detection, relative recovery%, and enrichment factor are 0.08-9.2, 0.05, $94.8{\pm}3.1-98.5{\pm}3.3%$, $4.34{\pm}0.28-4.40{\pm}0.30$, respectively. SDME-AP-MALDI-MS shows good intraday and interday reproducibility.

화학적 산소 요구량 측정을 위한 On-Line 측정 시스템에 관한 연구 (On-Line Measurement System for the Determination of Chemical Oxygen Demand)

  • 정형근;차기철
    • 한국환경과학회지
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    • 제7권2호
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    • pp.203-208
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    • 1998
  • A simple on-line measurement system consisting of a conventional peristaltic pump, a HPLC-type heater, and a flow-through spectrophotometer is introduced for the determination of chemical oxygen demand(CODI. The system was configured such that the reaction mixture in the highly concentrated surffuric acrid medium flowing through the PTFE reaction tubing was heated at 150℃ and the absorbance of dichromate was continuously moutored at 445 m. The same addation principle as in the standard procedure was employed akcept the use of CoSO4 as a new effective catalyst. To test the system, potassium hydrogen phthalate was selected as a COD standard material. With suitably optimized reaction condition, the applicable concentration range depends on the concentration of potassium dichromate in the oxidizing reagent. With 2.0×10-3 M and 5.0×10-4M dichromate, the linear dynamic range was observed up to 400 ppm and 100 ppm, respectively. The standards in the Unear ranges were shown to be completely oxidized, which was confirmed with sodium oxalate or Mohr's salt. In all cases, the typical reproduclbility for betweenruns was 2% or less. The proposed measurement system provides the valuable in- formation for the further development of automated analysis system based on the present standard procedure.

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