• 소성∙가공
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• 제8권3호
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• pp.295-295
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• 1999

In the present study, the corrosion behavior of AZ91D as-cast alloy was investigated form the viewpoint of the distribution aspect of precipitate ($Mg_{17}Al_{12}$) and the variation of Al concentration in the Mg-rich matrix. The dendrite arm spacing (DAS) of an as-cast specimen was measured as a function of degree which describes the distribution aspect of the precipitate, and the salt spray test was conducted for various grain-sired specimens fur 20 days. The dendrite arm spacing increased as the grain size increased to about 150㎛, but a constant value is indicated when the grain size exceeds that range. Although the relationship between the corrosion rate and grain size is of a nonlinear type, the linear trend between the corrosion rate and the dendrite arm spacing is maintained for the overall range of dendrite arm spacing. Since the precipitate in the as-cast alloy is discontinuously distributed, this linear relationship means that the variation of Al-solute concentration in the Mg-rich matrix has a more potent effect than the protective action of the precipitate on the corrosion behavior of an as-cast alloy.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.123-123
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• 2011

알루미늄은 경량 금속으로 부식 저항력이 높아 철을 부식으로부터 보호하기 위한 표면처리 소재로 사용되고 있다. 철의 부식을 방지하기 위해서 알루미늄을 코팅하는 경우, 코팅 방법은 용융도금법이 주로 사용되고 있으며, 알루미늄을 빛의 반사막으로 활용하는 경우 진공 중에서 물리기상증착(physical vapor deposition; PVD)법을 사용하기도 한다. 알루미늄 박막을 물리기상 증착으로 코팅하면 박막성장 초기에 핵(nucleus)을 형성하고, 형성된 핵을 중심으로 주상정(column)으로 박막이 성장하는 것이 일반적이다. 알루미늄 박막의 주상정과 주상정 사이에 공극(pore)이 존재하기 때문에 알루미늄 박막을 부식방지 막으로 이용하기 위해서는 두께를 증가시켜야 한다. 본 연구에서는 스퍼터링(unbalanced magnetron sputtering)을 이용하여 치밀한 조직을 갖는 알루미늄 박막을 코팅할 수 있는 공정변수를 도출하고, 치밀한 알루미늄 조직이 철의 부식에 미치는 영향을 평가하였다. 기판은 냉연강판(cold rolled steel sheet)이 사용되었으며, 알루미늄 타겟의 크기는 직경 4 inch이었다. 알루미늄 박막의 미세조직과 밀도에 영향을 주는 공정변수를 확인하기 위해서 스퍼터링 파워, 공정 압력, 외부 자기장 세기 등의 조건을 변화시켜 코팅을 실시하였다. 알루미늄 박막의 밀도 변화에 가장 큰 영향을 준 공정변수는 외부 자기장의 세기와 방향이었다. 알루미늄 박막이 약 3 ${\mu}m$의 두께로 코팅된 냉연강판을 염수분무시험(salt spray test, 5% NaCl)으로 부식특성을 평가한 결과, 시험을 시작한 후 120시간 후에도 적청이 발생하지 않았다. 이러한 결과는 기존의 동일한 두께를 갖는 알루미늄이 코팅된 강판의 내부식 특성의 2배의 성능을 보여준다.

• 한국표면공학회지
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• 제50권4호
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• pp.266-271
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• 2017

In this study, the corrosion resistance of Zn-3wt.%Mg coating was enhanced by controlling the density of coating. During the deposition the substrate temperature was controlled via an intermittent deposition process, resulting in the improvement of coating density. The maximum substrate temperature during this intermittent deposition process could be controlled from $200^{\circ}C$ to $80^{\circ}C$, depending upon the number of coating layer. The density of Zn-3 wt.%Mg coating increased from 76.1 % to 95.8 % as the substrate temperature was controlled. The salt spray test results revealed that the corrosion resistance of Zn-Mg coated steel could increase 3 times by increasing the density in coatings, while adhesion strength of coating was not changed significantly during 0-T bending test.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2015년도 추계학술대회 논문집
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• pp.256-257
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• 2015

마그네슘 합금은 낮은 비중, 높은 비강도, 주조성 및 절삭가공성, 치수안정성, 내흠집성이 우수한 특성을 지니고 있는 경량금속으로써 우수한 주조성과 상온강도, 연신율을 나타낸다. 최근에는 마그네슘 합금을 사용한 IT 기기의 케이스 및 자동차 내, 외장 부품 등의 제품이 다양하게 출시되어지며 금속 질감의 감성 기능까지 적용시킨 전자 기기 제품에 대한 수요가 급증하고 있는 추세이다. 하지만 마그네슘 합금의 낮은 부식 저항성은 마그네슘 합금을 적용시킨 제품에 큰 단점으로 작용되고 있으며 이를 해결하기 위한 연구가 활발히 진행 중이다. 본 연구에서는 플라즈마 전해산화법과 실리카 졸-겔 코팅법을 이용하여 마그네슘 합금의 내부식성을 향상시킴과 동시에 금속질감의 감성 기능을 구현하고자 하였다. 플라즈마 전해산화 공정으로 형성된 산화피막층과 $SiO_2$ 코팅으로 형성된 코팅층의 표면과 단면에 대해서는 FE-SEM(Field emission Scanning Electron Microscope)과 FE-TEM(Field emission Transmission Electron Microscope)으로써 확인하였고 전기화학적 특성 분석을 통한 동전위(Potentiodynamic polarization)와 EIS(Eletrochemical Impedance Spectroscopy) 그리고 Salt spray등을 분석하였다.

• 한국표면공학회지
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• 제51권3호
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• pp.172-178
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• 2018

In this paper, effects of potassium permanganate, pottasium dichromate, sodium molybdate on lean duplex stainless steel were studied by GDOES, OCP, potentiodynamic curves. The stainless steels were chemically passivated in each nitric acid solutions containing 4wt.% oxidants for 1 hour. As a result, when potassium dichromate or sodium molybdate was added, content of Fe was decreased and content of Cr was increased. Consequently, corrosion resistance of passive film was increased. But in case of potassium permanganate was added, contrastively, content of Fe was increased and content of Cr was decreased. So corrosion resistance was decreased. Adding sodium molybdate in nitric acid for chemical surface treatment process was the most effective among oxidants and also it showed the most stable anti-corrosion in SST.

• 한국표면공학회지
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• 제47권3호
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• pp.137-146
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• 2014

The important drawback of epoxy electrodeposition(ED) coatings is the lack of the weathering resistance caused by the structure of bisphenol A. To improve this yellowing phenomena, acryl ED coatings have been developed. Compared with the epoxy ED coatings, however, acryl ED coatings are relatively weak in the corrosion resistance and mechanical properties. The purpose of this study is complemented their drawbacks by mixing epoxy and acryl ED paints. The salt spray, accelerated weathering test(QUV) and cupping, bending, impact test were employed to investigate the corrosion resistance, weathering resistance, and mechanical properties of ED coatings. When the ratio of acryl to epoxy resin of ED coating is 0.33, the weathering resistances are appropriately improved in condition maintaining the corrosion resistance. It was shown that the weathering resistance for epoxy ED coating was adjusted by optimally mixing acryl ED paint.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.117-120
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• 1996

In this paper, It is tested by spraying the spoiled liquids on the materials to prove the process of tracking under the various environments. Our experiments ware examined by setting the materials in the spray chamber, and by spraying the distilled water(DW), the city water(CW), the underground water(UW), the artificial acid rain(AR) and the salt water(SW) in applied voltage 3-6[KV]. As the result, the time of tracking breakdown became shorter in the order of DW < CW < UW < AR < SW. XLPE was eroded and its anti-bracking property was very strong, but that of PVC sheath was week. Especially it was confirmed that spraying by AR and SW on the PVC sheath had a serious effect on the lifetime of cable by the tracking breakdown.

• Journal of Magnetics
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• 제16권3호
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• pp.304-307
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• 2011

High performance Nd-Fe-B magnets can be manufactured by both sintering and hot deformation. The corrosion behaviors of the magnets prepared by the two processes were compared. Effect of microstructure on the corrosion resistance of Nd-Fe-B magnets was also investigated. A neutral salt spray test (NSS) was performed for the different-processed magnets. The weight losses of the samples after the corrosion test were measured. The corrosion microstructures were observed using a scanning electron microscope. It shows that the corrosion resistance of hot deformed magnets is much better than that of the sintered ones because the grain size and the distribution of Nd-rich phases of the hot deformed magnets are much finer and more uniform than those of the sintered ones. The different microstructure between the sintered and the hot deformed magnets causes the different corrosion behavior.

• 한국표면공학회지
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• 제51권6호
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• pp.405-414
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• 2018

The present study investigated the adhesion and corrosion resistance of subsequent electrophoretic paint (E-paint) on "electroless" paint coated AZ31 Mg alloy, which was formed by immersion of AZ31 Mg alloy in E-painting solution. It was found that with increasing immersion time of AZ31 in E-painting solution, the amount of paint deposited by electroless process increased but it decreased the electrochemical equivalent of E-painting process and the adhesion of the subsequent E-paint layer. The E-paint on electroless paint coated AZ31 contained pores with the highest pore density and the largest pore size was obtained on the samples with electroless times of 2 and 5 minutes, respectively. Results of the salt-spray test showed an accelerated growth of blisters over the entire surface of the sample immersed for less than 5 minutes whereas blisters were observed only in the vicinity of the scratch in case of samples treated for 15 and 30 minutes. The E-paint on AZ31 with shorter electroless immersion time in E-painting solution was found to have good adhesion and better corrosion resistance.

• Corrosion Science and Technology
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• 제18권3호
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• pp.92-101
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• 2019

This study investigates how rivet head height affects the corrosion performance of carbon fiber reinforced plastic (CFRP) to aluminum alloy self-piercing riveted joints. Specimens with two different head heights were prepared. A rivet head protruding out of the top CFRP laminate forms the proud head height while a rivet head penetrating into the top CFRP generates the flush head height. The salt spray test evaluated corrosion performance. The flush head joints suffered from severe corrosion on the rivet head. Thus, the tensile shear load of flush head joints was substantially reduced. Electrochemical corrosion tests investigated the corrosion mechanisms. The deeper indentation of the flush head height damaged the CFRP around the rivet head. The exposure of damaged fibers from the matrix increased the cathodic potential of local CFRP. The increased potential of damaged CFRP accelerated the galvanic corrosion of the rivet head. After the rivet head coating material corroded, a strong galvanic couple was formed between the rivet head base metal (boron steel) and the damaged CFRP, further accelerating the flush rivet head corrosion. The results of this study suggest that rivet head flushness should be avoided to enhance the corrosion performance of CFRP to aluminum alloy self-piercing riveted joints.