• Title/Summary/Keyword: salt removal

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Preparation of Highly Tough Ethylene Vinyl Acetate (EVA) Heterogeneous Cation Exchange Membranes and Their Properties of Desalination

  • Kim, In Sik;Ko, Dae Young;Canlier, Ali;Hwang, Taek Sung
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.361-369
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    • 2018
  • A manufacturing method has been devised to prepare novel heterogeneous cation exchange membranes by mixing ethylene vinyl acetate (EVA) copolymers with a commercial cation exchange resin. Optimum material characteristics, mixture ratios and manufacturing conditions have been worked out for achieving favorable membrane performance. Ion exchange capacity, electrical resistance, water uptake, swelling ratio and tensile strength properties were measured. SEM analysis was used to monitor morphology. Effects of vinyl acetate (VA) content, melt index (MI) and ion exchange resin content on properties of heterogeneous cation exchange membranes have been discussed. An application test was carried out by mounting a selected membrane in a membrane capacitive deionization (MCDI) system to investigate its desalination capability. 0.92 meq/g of ion exchange capacity, $8.7{\Omega}.cm^2$ of electrical resistance, $40kgf/cm^2$ of tensile strength, 19% of swelling ratio, 42% of water uptake, and 56.4% salt removal rate were achieved at best. VA content plays a leading role on the extent of physical properties and performance; however, MI is important for having uniform distribution of resin grains and achieving better ionic conductivity. Overall, manufacturing cost has been suppressed to 5-10% of that of homogeneous ion exchange membranes.

Glycerol Separation from Biodiesel Byproduct (바이오디젤 부산물로부터 글리세롤의 분리)

  • Yang, Young-Mi;Kim, Kwang-Je;Lee, Yongtaek
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.690-692
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    • 2008
  • Pure glycerol could be obtained from a biodiesel byproduct by separation processes including neutralization, precipitation, and distillation. The contents of distilled glycerol through the above separation processes were measured and the results were compared according to experimental conditions such as acid concentration and precipitation temperature. Neutralization processes were carried out in the concentration range of 5~37 wt% hydrochloric acid, 5~95 wt% sulfuric acid, and 5~85 wt% phosphoric acid, respectively. Precipitation temperatures in neutralization were controlled in the range of 293~333 K. Higher values of the distilled glycerol content were obtained due to the salt removal in the pretreatment case of neutralization with 10 wt% sulfuric acid and precipitation of 313 K with 85 wt% phosphoric acid, respectively. The variations of acid concentration and precipitation temperature in pretreatment steps affected to some extent glycerol recovery from the biodiesel byproduct.

Quality Characteristics of Salicornia herbacea L. Extract Added Brown Sauce (함초 추출액을 첨가한 브라운 소스의 품질 특성)

  • Kim, Ja-Kyoung;Hahm, Moon-Hoon
    • The Korean Journal of Food And Nutrition
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    • v.26 no.2
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    • pp.184-191
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    • 2013
  • This study performed physicochemical characteristics and sensory tests on brown sauce with different Salicornia herbacea L. (saltwort) content to find the best brown sauce recipe with saltwort. Moisture content increased with greater saltwort extract content. There was significant (p<0.001) pH difference with saltwort content. There was also significant (p<0.001) sweetness difference in the samples and sweetness increased with greater saltwort content. Viscosity measured at $20^{\circ}C$ and $60^{\circ}C$ was significantly (p<0.001) lower with greater saltwort content. The brightness of brown sauce containing saltwort extracts significantly (p<0.001) increased with greater saltwort content and its redness and yellowness usually decreased. SPS4 with the greatest saltwort content showed the highest value of 4.25% and DPPH radical removal increased significantly (p<0.001) with greater saltwort content. In the sensory test, the color value was lowest at 4.82 with BSL1 and the flavor value was lowest at 5.00 with BSL0, the control group. The taste and the flavor values were highest with BSL2 with 2% saltwort content. Overall acceptance was highest with BSL3, the brown sauce with 3% saltwort content, at 6.09. As a result, it was concluded that the brown sauce with 3% saltwort content was most suitable. Therefore, this study concluded that saltwort with various functions could be used for food and may be used to replace salt and have other functions in brown sauce, a popular sauce consumed in Korea.

Determining the Proportions of Bone and Cartilage Growth in the Crucian Carp (carassius auratus) Using the Modified Simultaneous Differential Staining Technique

  • Lee, Jin-Heon
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.337-341
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    • 2010
  • The modified simultaneous differential staining technique, which enables double staining of cartilage and bones, needs to be improved to prevent soft tissues from being damaged during the staining process. Key factors influencing the extent to which soft tissues are damaged include the fixative used, macerating time, potassium hydroxide concentration, incubation temperature and the removal of skin from specimens. Here we describe a protocol that enables the hardening of tissues during bleaching and maceration. We also describe a method for objectively measuring rates of cartilage and bone growth. The use of formalin as a fixative rendered soft tissues more rigid due to the resulting chemical bonds formed between proteins. Blotted specimens were immersed in 1% potassium hydroxide (KOH) and incubated at $37^{\circ}C$ for 1 day (smaller specimens) or 2-3 days (larger specimens). The 1% KOH solution was also used as the diluent solution for the subsequent immersion in a graded series of 30%, 50%, 70%, 90%, 100% glycerol solutions, a procedure that made soft tissues even more transparent and hardened. It was not necessary to remove the skin of specimens shorter than 2 cm, since the macerating solution could easily penetrate their thin skin layer and continuously remove those pigments hindering visibility. Since excessive osmosis is another factor that can damage soft tissues in the macerating process by causing the rupture of those cells not able to withstand the osmotic pressure, here it was minimized by balancing the salt concentration between the interior and exterior of cells with the addition of 0.9% sodium chloride (NaCl) in the macerating solution. Finally, to determine the proportions of cartilage and bone growth, photographs of the stained specimens were taken with a dissecting microscope and sections corresponding to the cartilage and bones were cut out from the printed pictures and weighed. Our results show that this method is suitable for the objective evaluation of bone and cartilage growth.

A Study on Nonlinear Filter for Removal of Complex Noise (복합잡음 제거를 위한 비선형필터에 관한 연구)

  • Lee, Kyung-Hyo;Ryu, Ji-Goo;Kim, Nam-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.455-458
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    • 2008
  • Former times Information Technology generally has only depended on text or sound, while nowadays information is being moved through a variety of image media. Cell phone, TV and computer have been major elements of modem society as mediators using image signal. Therefore, image signal processing also has been treated importantly and done actively. The processing has been developed in many fields of digital image processing technologies as image data compression, recognition, restoration, etc. Noises are inevitably generated by using the signals during the processing, and typical types of the noise are Impulse(salt & pepper) and AWGN(Addiction White Gaussian Noise). To reduce the noise, various kinds of filters have been developed, and according to each noise, it is being used different filter each. However, the noise is not generated by one signal but by a complex. In this paper, I suggested an image filter to remove the complex noise, and compared with existing filters' methods for verification.

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Prevalence of surgical affections with their clinical management in crocodiles (Crocodylus porosus) in Bangladesh

  • Arif, Abu S.M.;Hashim, M.A.;Runa, R.A.;Chowdhury, E.H.;Rahman, Md Siddiqur;Song, Hee-Jong
    • Korean Journal of Veterinary Service
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    • v.33 no.3
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    • pp.313-317
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    • 2010
  • This study was conducted in the saltwater crocodile (Crocodylus porosus) for the occurrence of various surgical affections with their clinical management. During the period of January 2006 to June 2008, a total of 68 adult crocodiles were considered as reference population from the Reptiles Farm Ltd. at Bhaluka, Mymensingh. The occurrence of surgical affections of adult female (88.9%) was significantly (P<0.01) higher than male (11.1%). Prevalence of common surgical affections were wound: 72.2%, fibroma: 11.1% abscess: 5.6%, fracture: 5.6%, tail necrosis: 2.8%, myiasis: 2.8%. Wound was the highest among the affections. Among the identified wounds, biting wound was higher. In summer (57.7%) the occurrence of wound was higher compared to other seasons. In winter season (7.7%) the occurrence of abscess, myiasis, fibroma were higher compared to other seasons. Wounds and fibroma are the major surgical affections in salt water crocodile. The most common site of surgical affection was recorded in crocodile's tail (30.6%). It was suggested that minimal stress, allowing constant and easy access to water, removal of roots of the tree in the basking land of crocodiles pen, basking land of the pen is better filling up by sand, clinical surgical managements are essential for better health and production.

Removal of pentachlorophenol by pentachlorophenol resistant strains isolated from activated sludge (활성오니에서 분리한 pentachlorophenol 내성균주의 pentachlorophenol 제거에 관한 연구)

  • Park, Yun-Hee;Cho, Sung-Eun;Lee, Woo-Sang;Jo, Do-Hyun
    • Applied Biological Chemistry
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    • v.35 no.4
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    • pp.242-247
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    • 1992
  • Twenty strains of pentachlorophnol (PCP) resistant bacteria were isolated from activated sludge of the sewage treatment plant of Jung Lang Chun, Seoul. The predominant strains were Bacillus spp. including B. sphaericus and E. schlegelii. The other strains were identified as Corynebacterium spp., Staphylococcus aureus, Arthrobacter spp. and Aeromonas spp. The resistant strains could be grouped into two categories; PCP-degrading and PCP-adsorbing/absorbing ones. PCP-degrading strains degraded $75{\sim}90%$ of PCP in the medium containing 100 ppm PCP during the first 24 hours of growth. At the initial period the PCP-adsorbing/absorbing strains removed PCP from the medium but started to release PCP after 24 or 72 hours of growth. PCP degradation products from the culture broth of PCP-degrading strains were identified by comparing their $R_f$ values with those of the reference compounds. 2-chlorophenol and 2.4-dichlorophenol were presumed to be the intermediate products of PCP degradation.

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Antimicrobial Activity and Stability of Tetrasodium Pyrophosphate Peroxidate (과산화피로인산나트륨의 항균성 및 안정성)

  • Lee, Jong-Hoon;Kim, Il-Hwan
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1040-1044
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    • 1998
  • Tetrasodium pyrophosphate peroxidate can be crystallized as a hydrogen-peroxide-bound salt from the solution of tetrasodium pyrophosphate and hydrogen peroxide. The antimicrobial activity and stability of the compound were tested for the use as a food preservative. It showed antimicrobial activities against several food spoilage microorganisms at the concentration of 0.1% (w/v), and was stable for 80 days in room temperature as a form of 70% hydrogen-peroxide-bound tetrasodium pyrophosphate peroxidate. It was also stable at the boiling temperature but decomposed significantly in the presence of metal ions. The compound can be an effective food preservative at the 0.2% (w/v) concentration, which contains 0.03% (v/v) hydrogen peroxide. The compound could be commercialized if the application area and usage direction as well as the removal method of hydrogen peroxide were developed.

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THE EFFECT OF FILLERS ON THE DEINKING OF PHOTOCOPIED PAPER

  • Chen, Qing-min;Chang, Hou-min;Ethan K. Andrews;Heinz G. Olf
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.159-163
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    • 1999
  • Model experiments were conducted to investigate the effect of different fillers on the removal of toner ink. Combinations of different papers (commercial photocopy paper and filler-free paper), fillers (calcium carbonate, kaolin clay, and talc), and chemicals(1-octadecanol, stearic acid, oleic acid, and TOFA) and stearic acid were found to be effective in detachment and agglomeration of toner ink. Furthermore, pH had little effect on toner detachment and agglomeration, indicating both protonated fatty acids and their anions are equally effective. In the presence of either kaolin clay or talc, all these agglomerating agents are equally effective, although a slightly higher dosage(1% for clay and 2% for talc as compared with control) is required, presumably due to the adsorption of chemical by the filler. Calcium carbonate filler, on the other hand, has a significant and adverse effect on the fatty acids used but has little effect on 1-octadecanol with the exception of possible adsorption. While stearic acid is not effective, a much higher level of oleic acid or TOFA is needed when calcium carbonate fillers are present as compared to the filler-free case. Fatty acids react with calcium carbonate to form calcium salts. The availability of fatty acid anion for toner detachment and agglomeration is determined by the solubility of calcium salt of a given fatty acid. Calcium oleate is 10 times more soluble in water than calcium stearate.

Pilot Scale Anaerobic Digestion of Korean Food Waste (파일로트 규모 음식쓰레기 2상 혐기소화 처리공정에 관한 연구)

  • Lee, J.P.;Lee, J.S.;Park, S.C.
    • Solar Energy
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    • v.18 no.3
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    • pp.197-203
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    • 1998
  • A 5 ton/day pilot scale two-phase anaerobic digester was constructed and tasted to treat Korean food wastes in Anyang city. The process was developed based on 3 years of lab-scale experimental results on am optimim treatment method for the recovery of biogas and humus. Problems related to food waste are ever Increasing quantity among municipal solid wastes(MSW) and high moisture and salt contents. Thus our food waste produces large amounts of leachate and bed odor in landfill sites which are being exhausted. The easily degradable presorted food waste was efficiently treated in the two-phase anaerobic digestion process. The waste contained in plastic bags was shredded and then screened for the removal of inert material such as fabrics and plastics, and subsequently put into the two-stage reactors. Heavy and light inerts such as bones, shells, spoons and plastic pieces were again removed by gravity differences. The residual organic component was effectively hydrolyzed and acidified in the first reactor with 5 days space time at pH of about 6.5. The second, methanization reactor part of which is filled with anaerobic fillters, converted the acids into methane with pH between 7.4 to 7.8. The space time for the second reactor was 15 days. The effluent from the second reactor was recycled to the first reactor to provide alkalinities. The process showed stable steady state operation with the maximum organic rate of 7.9 $kgVS/m^3day$ and the volatile solid reduction efficiency of about 70%. The total of 3.6 tons presorted MSW containing 2.9 tons of food organic was treated to produce about $230m^3$ of biogas with 70% of methane and 80kg humus. This process is extended to full scale treating 15 tons of food waste a day in Euiwang city and the produced biogas is utilized for the heating/cooling of adjacent buildings.

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