• Title/Summary/Keyword: s-Al.p

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A Study on the Behaviour of High Temperature Corrosion of Fe-22Cr-5Al-X(X=Zr,Y) (Fe-22Cr-5Al-X(X=Zr,Y)합금의 고온 부식거동에 관한 연구)

  • Lee, Byeong-U;Park, Heung-Il;Kim, Jung-Seon;Lee, Gwang-Hak;Kim, Heung-Sik
    • Korean Journal of Materials Research
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    • v.7 no.10
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    • pp.898-907
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    • 1997
  • Fe-22Cr-5AI-X(X=Zr, Y)합금을 1143K, 고온 황화(P$s_{2}$=1.11x$10^{-7}$atm, P$O_{s}$ =3.11x$10^{-20atm}$) 및 황화/산화 (P$s_{2}$=8.31x$10^{-8}$atm, P$O_{s}$ =3.31x$10^{-18atm}$) 환경의 복합가스 분위기에서 1-30시간동안 노출하여 합금표면에 형성된 부식층을 관찰하여 SEM/EDS로 분석하였다. Fe-22Cr-5AI합금은 고온 부식환경에서 부식 생성물의 성장은 포물선법칙을 따르고 주요 성분은 결함이 많고 다공질인 철과 크롬의 황화물[(Fe, Cr)Sx]이므로 고온 내식성이 감소하였다. Zr을 1wt%첨가한 Fe-22Cr-5AI합금의 고온 부식거동은 Y을 1wt%첨가한 합금과 비슷한 거동을 나타내었다. 황화환경에서는 Cr의 선택 황화에 의한 크롬 황화물(CrS)이 생성되고 노출시간의 경과에 따라 (Fe, Cr)Sx나 (Cr, Fe)Sx 등의 황화물의 성장으로 고온 내식성이 감소하였다. 그러나 황화/산화환경에서는 초기에는 알루미늄산화물(A $I_{2}$ $O_{3}$)및 지르코늄산화물(Zr $O_{2}$)등이 생성되어 보호적이었으나 15시간이후 부터 (Fe, Cr)Sx나 (Cr, Fe)Sx 의 황화물의 성장으로 고온 내식성이 감소하였다.

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Purification and Characterization of Carboxymethyl Cellulase from Lampteromyces japonicus (Lampteromyces japonicus가 생산하는 Carboxymethyl Cellulase의 정제 및 특성)

  • Yoo, Kwan-Hee;Kim, Jun-Ho;Chang, Hyung-Soo
    • The Korean Journal of Mycology
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    • v.32 no.2
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    • pp.125-129
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    • 2004
  • A carboxymethyl cellulase (CMCase) bas been isolated and purified from Lampteromyces japonicus. The molecular weight of CMCase was estimated to be 42 kDa by sodium dodecyl sulfate (SDS) polyacrylamide gel electrophoresis. The maximum activity of the purified CMCase was observed at pH 6.0 and $30^{\circ}C$, and stable for pH 4 to 7 to maintain 40% activity. The CMCase activity was activated by $Al_{2}(SO_{4})_{3}$, and inhibited by SDS. Also, the enzyme activity was decreased by the addition of ethylene diamine tetraacetic acid (EDTA), suggesting that the purified CMCase is metalloenzyme.

Characteristics of Bacillus sphaericus PSB-13 as Phosphate Solublizing Bacterium Isolated from Citrus Orchard Soil (감귤원 토양에서 분리한 인산염 가용화 미생물 Bacillus sphaericus PSB-13의 특성)

  • Joa, Jae-Ho;Lim, Han-Cheol;Han, Seung-Gap;Chun, Seung-Joung;Suh, Jang-Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.5
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    • pp.405-411
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    • 2007
  • This study was carried out to measure insoluble phosphorus fractions content fixed in different soil type and isolate a superior phosphate solublizing bacteria(PSB) producing free phosphate in citrus orchard soil. Distribution of insoluble phosphate fraction ordered Al-P>Ca-P>Fe-P in the investigated citrus orchards. Insoluble phosphate fraction such as Al-P, Ca-P, Fe-P were higher in volcanic ash than in non-volcanic ash soil. A PSB with high holo zone in PDA-P medium isolated from citrus orchard soil. This strain identificated by MIDI system as Bacillus sphaericus. The optimum growth of pH and temperature were at 4~5, $30^{\circ}C$, respectively. When Bacillus sphaericus cultured at $25^{\circ}C$, 150 rpm condition in LB broth medium included different phosphate. Bacillus sphaericus produced free phosphate in the culture broth medium from tricalcium-phosphate(207.0 ppm), aluminium phosphate(324.5 ppm) and hydroxyapatite(334.8 ppm) and Phosphatase activity of Bacillus sphaericus was higher at $35^{\circ}C$ culture condition than that of $25^{\circ}C$. Two type preparation inoculated Bacillus sphaericus made with carrier materials such as Bentonite, $CaCO_3$, Sodium alginate. Density of PSB in this preparation conserved at $10^5c.f.u.\;g^{-1}$ level during storage in different temperature condition for 7 month. It also showed that free phosphate produced at PDA-P medium.

Growth Inhibition of Sclerotium Cepivorum Causing Allium White Rot by Serratia plymuthica Producing Chitinase (Serratia plymuthica AL-1이 생산하는 chitinase에 의한 대파 흑색썩음균핵병균의 생육억제)

  • 김진호;최용화;강상재;김영훈;주길재
    • Journal of Life Science
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    • v.13 no.1
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    • pp.90-98
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    • 2003
  • An allium rhizobacterium Serratia plymuthica AL-1 was previously selected as a biocontrol agent of allium white rot. The chitinase from S. plymuthica AL-1 produced in medium containing colloidal chitin was purified by ammonium sulfate precipitation (40~70%), affinity adsorption, column chromatography on DEAE-sephadex A-50 and sephadex C-200 gel filtration. The enzyme was purified 10.8-fold with a yield of 7.3% from the starting culture broth. The purified chtinase gave a single band on sodium dodecyl sulfate polyacrylamide gel electrophoresis, it's molecular weight was estimated to be 55 kDa. The optimum pH and temperature of the purified enzyme were pH 5.5 and $55^{\circ}C$, respectively and it is stable up to $50^{\circ}C$ and maintains around 90% of its activity for 60min. The enzyme were activated by $Ca^{2+}$, $Mn^{2+}$ and $Mg^{2+}$ and inhibited by $Cu^{2+}$, SDS, $\rho$-CMB, MIA, respectively. The purified chitinase showed broad spectrum of antifungal activities against plant pathogenic fungi Sclerotium cepivoruin, Alternana alternnta, Colletotrichum glceosporioidrs, Phoma sp., Sclerotinia sclerotiorum, Stemphylium solani, Fusarium oxysporium f. sp. niveum but rarely inhibited Phytophthora capsici and Pythium ultimum.. The purified chitinase from S. plymuthica AL-1 caused swelling, lysis, deceleration and degradation of the hyphal tips of S. sczerotiorum causing allium white rot. It suggest that S. prymuthica AL-1 chitinase play an important part in the bifunctional chitinase / lysozyme activity.

Aluminum Complexation and Precipitation with Seaweed Biosorbent

  • Lee, Hak-Sung;Kim, Young-Tae
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.1
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    • pp.1-8
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    • 1998
  • Biomass of non-living brown seaweed Sargassum fluitans pretreated by different methods is capable of taking up more than $10\%$ (11 meq/g) of its dry weight in aluminum at a pH of 4.5. It is indicated that the biomass sequestered the aluminum in the form of polynuclear aluminum species. The fraction of $Al(OH)_3$ Precipitated in the aluminum nitrate solution without biomass at pH 4.5 increased as the Al concentration increased. Aluminum-alginate complex precipitated in the solution as alginate was partially released from the biomass. External colloidal precipitate occurring in native and protonated S. fluitans biomass sorption systems caused a significant difference in Al sorption isotherms determined by standard and desorption methods, respectively, Sodium ions added for pH adjustment were not sorbed at all in the presence of aluminum ions.

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A Study on Health Promoting Lifestyle of Hospital Nurses (간호사의 건강증진 생활양식과 관련요인 연구)

  • Paik, Young Chu;Kim, In Sook
    • Korean Journal of Adult Nursing
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    • v.12 no.3
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    • pp.477-489
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    • 2000
  • The purpose of study was to assess how hospital nurses practice their health promoting lifestyle and to identify affecting factors. The subjects were 286 nurses working at three general hospitals in Kwang-ju. The data were collected by questionnaire from September 1st. to September 10th, 1999. The instruments for this study were the Health Promoting Lifestyle Profile developed by Walker et al., perceived health status scale developed by Ware et al., self-efficacy scale developed by Sherer et al., and social support scale developed by Cohen et al.. The data were analyzed with mean, standard deviation, t-test, ANOVA, Pearson's Correlation Coefficient and Stepwise Multiple Regression. The results of this study were as follows: 1. The mean score of health promoting lifestyle was 2.36. Interpersonal support showed the highest score(2.67) and health responsibility (1.92) showed the lowest score. The mean score of perceived health status was 3.07, self-efficacy was 2.62, and social support was 2.91. 2. The relationship between general characteristics of subjects and health promoting lifestyle showed significant differences according to duty cycle(t=4.15, p=.042), disease experience (t=5.18, p=.023), monthly income(F=3.13, p=.025), exercise frequency(F=9.12, p=.000), stress reliefe method(F=5.98, p=.000), job satisfaction(t=11.44, p=.000), and perceived fatigue(F=6.13, p=.002). 3. Health promoting lifestyle showed significant positive correlations with perceived health status (r=.2190, p=.0002), self-efficacy (r=.5137, p=.0001) and social support (r=.5181, p=.0001). 4. The combination of social support(27.1%), exercise frequency(10.4%), self-efficacy(8.8%), job satisfaction, perceived health status, perceived fatigue and explained 53.5% of the variance of health promoting lifestyle. Therefore, this study suggests that a replicate study is needed until more affecting factors other than health promoting lifestyle.

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Analysis of emission spectrum of strained AlGaN QW LD (Strain에 따른 AlGaN QW LD의 발광특성 해석)

  • Kim, Jong-Dae;Lee, Jong-Chang
    • Proceedings of the Optical Society of Korea Conference
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    • 2005.02a
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    • pp.290-291
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    • 2005
  • We have presented a comprehensive effective-mass Hamiltonian for strained Wurtzite semiconductors using k${\cdot}$p method and Kane's model. This theoretical groundwork provides a foundation for investigating the electrical and optical properties of wurtzite strained quantum-well lasers.

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The Effect of Fly Ash Composition and Reaction Conditions on Hydrothermal Synthesis of Zeolitic Materials (Fly ash 조성(組成)과 반응조건(反應條件)이 zeolite성(性) 물질(物質)의 열수합성(熱水合成)에 미치는 영향(影響))

  • Choi, Choong-Lyeal;Lee, Dong-Hoon;Park, Man;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.39-46
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    • 1999
  • This study was performed to examine the effect of initial composition ratio and various reaction conditions on CEC and crystallinity of the product in hydrothermal synthesis of zeolitic materials from fly ash. Na-P1 zeolite was formed from the mixture with $SiO_2/Al_2O_3$ ratio above 2.55, however from the mixture with $SiO_2/Al_2O_3$ ratio below 2.25 hydroxy sodalite was formed. The CEC of reaction product(Na-P1 zeolite) treated with 3N-NaOH, $Na_2O/Al_2O_3$ ratio 2.55 and $SiO_2/Al_2O_3$ ratio 2.0 for 12 hours at $103^{\circ}C$ was about $285cmol^+kg^{-1}$, which was higher than those of the products of other reaction condition. The crystallinity of Na-P1 zeolite as high as 45.1% was attained at the optimum reaction condition of 2N-NaOH, $SiO_2/Al_2O_3$ ratio 2.55, $Na_2O/Al_2O_3$ ratio 1.5 for 12 hours at $103^{\circ}C$. The XRD peak of the reaction product could be measured at 7.16, 5.04, 4.12, 3.18, $2.69{\AA}$ and tetragonal pillar shape observed by SEM image be characteristic for Na-P1 zeolite. Judging from the result, it should be considered the optimum synthesis condition for Na-P1 zeolite from fly ash was 2~3N NaOH, $SiO_2/Al_2O_3$ ratio 2.55 and $Na_2O/Al_2O_3$ ratio 1.5~2.0 for 12 hours at $80{\sim}103^{\circ}C$.

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