• Analytical Science and Technology
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• v.11 no.5
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• pp.347-352
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• 1998

A study was carried out on the elelctrochemical characteristics of chemically modified electrodes (CMEs) by cyclic voltammetry. Fabrication of CMEs was made by coating with mixed valence (mv) inorganic-metal polymeric films on the glassy carbon electrode surface by potential cycling. Anodic oxidation behavior of methanol and L-ascorbic acid was studied by using CMEs working electrode. Deposition of films such as mv ruthenium oxo/ruthenium cyanide film (mv Ru-O/CN-Ru), mv ruthenium oxo/ferrocyanide film (mv Ru-O/$Fe(CN)_6$), and mv ruthenium oxo/ruthenium cyanide/Rhodium film (mv Ru-O/CN-Ru/Rh) was obtained to coat by scan rate of 50 mV/sec within the specified potential range (-0.5V ~ +1.2V). Film thickness was controlled by the repeat of the potential cycling. Anodic oxidation behavior of methanol was as follow. Calibration graph by using mv Ru-O/CN-Ru film showed linearly from 10 mM to 80 mM MeOH with slope factor of $-7.552{\mu}A/cm^2$. Although slope factor by using mv Ru-O/$Fe(CN)_6$ film was $-5.13{\mu}A/cm^2$, yet linear range of calibration graph could be extended from 10 mM to 100 mM MeOH. Anodic oxidation behavior of L-ascorbic acid was studied by mv Ru-O/CN-Ru film on the glassy carbon electrode and the glassy carbon electrode with Rh film, Glassy carbon electrode modified with Ru polymeric film was showed better sensitivity than the Rh-glassy carbon modified electrode (mv Ru-O/CN-Ru/Rh). Calibration graph was linear from 0.1 mM to 5 mM L-ascorbic acid by using glassy carbon electrode modified with Ru polymeric film. Solpe factor and relative coefficient are $-84.78{\mu}A/mM$ and 0.998, respectively.

• Bulletin of the Korean Chemical Society
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• v.28 no.2
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• pp.173-174
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• 2007

• Bulletin of the Korean Chemical Society
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• v.20 no.1
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• pp.119-121
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• 1999

• Bulletin of the Korean Chemical Society
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• v.15 no.8
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• pp.692-694
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• 1994

• Bulletin of the Korean Chemical Society
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• v.17 no.8
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• pp.765-766
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• 1996

• Bulletin of the Korean Chemical Society
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• v.22 no.9
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• pp.943-944
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• 2001

• Bulletin of the Korean Chemical Society
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• v.16 no.12
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• pp.1239-1241
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• 1995

• Korean Journal of Materials Research
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• v.9 no.4
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• pp.368-372
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• 1999

The suggested electrode structure of MOCVD-Pt/sputtered-Ru/polysilicon has an excellent adhesion with increasing annealing temperatures and shows a stable electrode structure up to $600^{\circ}C$. However, the ruthenium used for barrier layer increased the roughness of platinum bottom electrodes because ruthenium diffused through the Pt bottom electrode and reacted with oxygen during the annealing above $700^{\circ}C$. The surface roughness increased the resistivity of Pt bottom electrodes. The resistivity of samples annealed at $600^{\circ}C$ was about $13\mu$Ω.cm. The electrode structure was possible to apply for ferroelectric thin film integration of semiconductor memory devices.

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.206-207
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• 2000

A disposable, electro-chemiluminescent immunosensor utilizing a screen-printed carbon electrode and liposome coupled to antibody as tracer has been constructed. In proportion to the analyte (Legionella species as a model) concentration, the analyte-immunoliposome complexes were transferred by the capillary action through a membrane strip to the electrode, the liposomes were lysed in the presence of detergent, and ruthenium was released for signal generation. Such performance of the immunosensor was appropriate for a point-of-care testing.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.181.1-181.1
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• 2014

Supercapacitor is attracting growing attention for a promising energy conversion and storage device because of its desirable electrochemical properties such as rapid charge-discharge rate, high power density and long cycle life. Three-dimensional (3D) metal nanostructure has been widely studied since it can provide efficient charge transport along the 3D network in many device applications. In this work, we fabricated well-ordered 3D nickel (Ni) nanostructures using 3D-arrayed polystyrene nano-opal substrates. We also fabricated half-cell supercapacitors by electrodepositing $RuO_2$ onto these nanostructured Ni current collectors and investigated their morphological and electrochemical properties.