• Title/Summary/Keyword: rust

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Mechanical Characteristics and Corrosion Resistance of Concrete Using Tannin Acid-Corrosion Inhibitor (탄닌산 부식 억제제를 사용한 콘크리트의 역학적 특성 및 부식저항성)

  • Yang, Eun-Ik;Ryu, Jong-Hyun;Youm, Kwang-Soo;Hwang, In-Dong;Kim, Myung-Yu
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.741-746
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    • 2008
  • Many methods have been introduced to protect the corrosion of embedded steel in RC structure. One of the methods that restrain corrosion of steel is corrosion inhibitor. The technology that delayed the progress of corrosion is developed recently by converting active rust to passive rust. However, the performance for concrete structure is not fully examined because this corrosion inhibitor is developed for normal metal product. In this study, the application of corrosion inhibitor that use tannin acid is investigated by concrete specimen. According to the results, tannin acid corrosion inhibitor does not occur reduction of workability and strength in concrete. When corrosion inhibitor is added more than 4% per cement weight, the penetration depth of chloride decrease about 10%. Also, corrosion resistance of concrete is improved because tannin acid corrosion inhibitor has an effect on converting the rust of steel into stable state. It is showed in special that the addition more than 6% is effective in corrosion resistance.

Effect of Aluminum and Silicon on Atmospheric Corrosion of Low-alloying Steel under Containing NaHSO3 Wet/dry Environment

  • Chen Xinhua;Dong Junhua;Han Enhou;Ke Wei
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.315-318
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    • 2008
  • The atmospheric corrosion performance of Al-alloying, Si-alloying and Al-Si-alloying steel were studied by wet/dry cyclic corrosion tests (CCT) at $30^{\circ}C$ and 60% relative humidity (RH). The corrosion electrolyte used for CCT was 0.052 wt% $NaHSO_{3}$ (pH~4) solution. The result of gravimetry demonstrated that Al-Si-bearing steels showed lower corrosion resistance than other rusted steels. But the rusted 0.7%Si-alloying steel showed a better corrosion resistance than rusted mild steel. Polarization curves demonstrated that Al-/Si-alloying and Al-Si-alloying improved the rest potential of steel at the initial stage; and accelerated the cathodic reduction and anodic dissolution after a rust layer formed on the surfaces of steels. XRD results showed that Al-Si-alloying decreased the volume fraction of $Fe_{3}O_{4}$ and $\alpha-FeOOH$. The recycle of acid accelerated the corrosion of steel at the initial stage. After the rust layer formed on the steel, the leak of rust destabilized the rust layer due to the dissolution of compound containing Al (such as $FeAl_{2}O_{4}$, $(Fe,\;Si)_{2}(Fe,\;Al)O_{4}$). Al-Si-alloying is hence not suitable for improving the anti-corrosion resistance of steel in industrial atmosphere.

Identification of Puccinia iridis on Iris domestica in Korea (범부채에서 녹병균 Puccinia iridis의 동정)

  • Choi, In-Young;Choi, Young-Joon;Kim, Jin-Young;Shin, Hyeon-Dong
    • The Korean Journal of Mycology
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    • v.47 no.1
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    • pp.89-94
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    • 2019
  • A rust fungus on Iris domestica (syn. Belamcanda chinensis) from China was previously identified as Puccinia iridis. Accordingly, the identity of the rust fungus on the same host species in Korea needs to be reexamned. Morphological characteristics of the Korean materials matched with P. iridis. Molecular phylogenetic analyses based on internal transcribed spacer and large subunit rDNA sequences of two representative materials confirmed the identification by high sequence similarities of 100% and 99% with the reference sequences available in NCBI GenBank database. Phylogenetic tree inferred from neighbor-joining method proved them to be clustered in P. iridis group. Thus, the rust fungus on I. domestica in Korea was determined as P. iridis. On the other hand, a previous record that Puccinia belamcandae is another rust agent on I. domestica in Korea should be reconfirmed in future.

Identification of Active Agents for Reductive Dechlorination in Cement/Fe(II) Systems (시멘트와 Fe(II)을 이용한 환원성 탈염소화반응의 유효반응성분 규명)

  • Kim, Hong-Seok;Lee, Yu-Jung;Kim, Ha-Yan;Hwang, In-Seong
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.35-42
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    • 2006
  • Experimental study was conducted to identify the active agent for reductive dechlorination of TCE in cement/Fe(II) systems. Several potential materials-hematite (${\alpha}-Fe_2O_3$), lepidocrocite (${\gamma}$-FeOOH), akaganeite (${\beta}$-FeOOH), ettringite ($Ca_6Al_2(SO_4)_3(OH)_{12}$)-that are cement components or parts of cement hydrates were tested if they could act as reducing agents by conducting TCE degradation experiments. From the initial degradation experiments, hematite was selected as a potential active agent. The pseudo-first-order degradation rate constant ($k\;=\;0.637\;day^{-1}$) for the system containing 200 mM Fe(II), hematite and CaO was close to that ($k\;=\;0.645\;day^{-1}$) obtained from the system containing cement and 200 mM Fe(II). CaO, which was originally added to simulate pH of the cement/Fe(II) system, was found to play an important role in degradation reactions. The reactivity of the hematite/CaO/Fe(II) system initially increased with increase of CaO dosage. However, the tendency declined in the higher CaO dosage region, implying a saturation type of behavior. The SEM analysis revealed that the hexagonal plane-shaped crystals were formed during the reaction with increasing degradation efficiency, which was brought about by increasing the CaO dosage. It was suspected that the crystals could be portlandite or green rust ($SO_4$) or Friedel's salt. The XRD analysis of the same sample identified the peaks of hematite, magnetite/maghemite, green rust ($SO_4$). Either instrumental analysis predicted the presence of the green rust ($SO_4$). Therefore, the green rust ($SO_4$) would potentially be a reactive agent for reductive dechlorination in cement/Fe(II) systems.

The Effect of Chloride on the Corrosion of Reinforced Concrete (염화물이 철근콘크리트의 부식에 미치는 영향)

  • Kim, Jeong-Sup;Shin, Yong-Seok;Lee, Sul;Kim, Kwang-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.147-154
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    • 2005
  • It is found that as contents of chloride ion and age increase, area of corrosion also increases. Inare increased to 1035 days from 730 days, slope of increase of corrosion area is greatest. Non-rust inhibitor specimens show corrosion area of 8~35 times more than rust inhibitor specimens and anticorrosive effects by application of rust inhibitor can be confirmed. When chloride ion is not contained, corrosion control effects of steel reinforcing according to increase of thickness are found, but specimens having chloride ion show no regular tend of thickness and corrosion due to complex problems such as reverse diffusion of chloride and test errors.

High Efficient Metal-oxide Removing Characteristics as Pulse Repetition Rates in the Atmospheric Arc Discharge (펄스반복율의 가변에 의한 대기압 아크방전중의 고효율 금속산화물 제거 특성)

  • 이윤수;송우정;김수원;정종한;김용철;김희제
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.4
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    • pp.179-184
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    • 2003
  • The pulsed power system is widely used for many industries and environments. Generally, we call the "RUST", the reddish brown surface, that was made on iron surface or some other metals, when they are contacted by water and air the main substance of rust is oxide-ionization. In other words, the chemical symbol of rust on iron surface is iron oxide(III) hydrate Fe203.nH2O. In this study, we have designed and fabricated our system which has a compact pulse generator with switching MOSFET. Also we have studied the metal-oxide removing characteristics using in the atmospheric arc discharge. It has been investigated their removing characteristics by the change of charging voltage and pulse repetition rates. From this result, we can find out that the removal area Is increased from 3.80 to 8.04[$\textrm{cm}^2$], when pulse duration is increased from 100[pps] to 400[pps]. 400[pps].

Verification of aecial host ranges of four Gymnosporangium species based on artificial inoculation.

  • Yun, Hye-Young;Lee, Seung-Kyu;Lee, Kyung-Joon
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2003.10a
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    • pp.134.1-134
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    • 2003
  • Aecial host ranges of four Gymnosporangium species causing cedar-apple rust diseases, G. asiaticum, G. cornutum, 5. japonicum and G. yamadae, were investigated through artificial inoculation. Thirteen species of nine genera among Rosaceous plants, which have been reported as social hosts in Korea, were inoculated with fresh teliospores spores in early days of May of 2000 and of 2001, respectively. In the results, we re-confirmed that there was highly specific relationship between the rust species and aecial hosts and report new aecial hosts of four Gymnosporangium species. Teliospores of G. cornutum collected from Juniperus rigida successively produced spermogonia and aecia only on Sorbus alntifolia, the first report on host alteration of G. cornutum in Korea. Positive responses by teliospores of G. japonicum from J. chinenis of Suwon and from J. chinenis var. horizontalis of Jeju island were obtained only on P. villosa. Crataegus pinnatifida was confirmed as a new aecial host of G. viatium. Until this time, G. ymadae was believed to have Malus as the aecial host. However, teliospores of G. yamadae collected from J. chinensis var. kaizuka successively formed spermogonia and aecia on the leaves of Chaenomeles lagenaria, C. sinensis, Pyrus pyrtifolia var, culta, P. ussuriensis, Malus pumila and M. sileboldii. The date for maturation of spermogonia and aecia, and symptom development varied according to the rust fungi and aecial host plants, respectively.

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An Antifungal Property of Burkholderia ambifaria Against Phytopathogenic Fungi

  • Lee Chul-Hoon;Kim Min-Woo;Kim Hye-Sook;Ahn Joong-Hoon;Yi Yong-Sub;Kang Kyung-Rae;Yoon Young-Dae;Choi Gyung-Ja;Cho Kwang-Yun;Lim Yoong-Ho
    • Journal of Microbiology and Biotechnology
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    • v.16 no.3
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    • pp.465-468
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    • 2006
  • Even though many pesticides are known for barley powdery mildew and wheat leaf rust, alternative controls are necessary, because of consumer rejection of chemical pesticides and the appearance of fungi resistant to fungicides. To discover biopesticides, many broths of microorganisms were screened. Of those, a culture broth of Burkholderia ambifaria showed an excellent antifungal activity against both Erysiphe graminis and Puccinia recondita, which cause barley powdery mildew and wheat leaf rust, respectively.

Evaluation of Cleaning Method for Remanufacturing Using Start Motor of Vehicle (차량용 스타트모터를 활용한 재제조 세척방법 평가)

  • Park, Sang Jin;Son, Woo Hyun;Jeon, Chang Su;Mok, Hak Soo
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.3
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    • pp.381-392
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    • 2020
  • The necessity and the importance of the remanufacturing are increasing day by day along with environmental problems. Many studies are being conducted on remanufacturing, but the research for cleaning is much lacking. This study aims to evaluate the effective cleaning method for remanufacturing of start motors, one of the automobile parts. The cleaning process consists of oil stain removal, drying and rust removal processes. In this study, the two processes were conducted except for the drying process which has little influence on cleaning. The methodology for cleaning agent selection, degreasing and rust removal process was presented. For each methodology, five analysis factors were calculated by two-way comparison according to the process, and the values were evaluated quantitatively by substituting them into the evaluation table. In the selection of cleaning agent, neutral system, ultrasonic cleaning in degreasing, and grinding in rust removal were selected as the best cleaning methods.

Corrosion Behaviour of DH36 Steel Used for Oil Platform in Splash Zones

  • Liu, J.G.;Li, Y.T.;Hou, B.R.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.190-194
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    • 2015
  • The splash zone is the most corrosive area of the marine environment, and the corrosion of steel structures exposed in this area is a serious concern. DH36 steel is one of most commonly used steels for offshore oil platforms in China, and its corrosion behaviour in splash zones was studied in this paper. Polarization curves were obtained from the corroded steel exposed in this area while the morphologies and rusts of the rust steel were characterized using scanning electron microscopy and X-ray diffraction. Double rust layers were formed in the splash zone. The inner layer contained magnetite and fine flaky lepidocrocite, and the outer layer was composed of accumulated flaky lepidocrocite and a small amount of goethite. In the wet period, the iron dissolved and reacted with lepidocrocite, and magnetite appeared, while the magnetite was oxidized to lepidocrocite again during the dry period. Electrochemical reduction and chemical oxidization cycled in intermittent wetting and drying periods, and magnetite and lepidocrocite were involved in the reduction reaction, leading to serious corrosion.