• Korean Journal of Materials Research
• /
• v.17 no.11
• /
• pp.601-605
• /
• 2007

The tribological properties of acrylonitrile-butadiene rubber (NBR) filled with two kinds of carbon black filler were examined. Different types of Semi-Reinforcing Furnace (SRF), and High Abrasion Furnace (HAF) blacks were used as filler material to test the influence of carbon black particle size on the friction and wear of NBR. Results from tribological tests using a ball on disk method showed that the smaller HAF particles were more effective for reducing the wear of NBR during frictional sliding. The hardness, elastic modulus at 100% elongation, and elongation at break were measured to examine the correlation between the effects of carbon black on the mechanical and tribological properties of the NBR specimens. The wear tracks of the NBR specimens were observed with scanning electron microscopy (SEM). The wear tracks for NBR with different ratios of SRF and HAF showed clearly different abrasion patterns. Mechanisms for the friction and wear behavior of NBR with different sizes of carbon black filler were proposed using evidence from wear track observation, as well as the mechanical and tribological test results.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.06a
• /
• pp.223-226
• /
• 2005

For $CO_2-free$ hydrogen production and better utilization of the produced carbon, catalytic decomposition of methane over rubber-grade carbon blacks manufactured from coal tar was carried out. The catalytic activities of several domestic carbon blacks were compared. A pelletized carbon black exhibited considerably lower activity and activation energy than the fluffy( loose) carbon black of the same grade. This difference is considered due to the binder that was added during pelletization. For pelletized carbon blacks, a tendency was observed that the activity per unit mass of catalyst increased with the specific surface area of the carbon black. Another tendency was also observed that the activation energy increased with the primary particle size or decrease of the specific surface area.

• Korea-Australia Rheology Journal
• /
• v.12 no.3_4
• /
• pp.157-163
• /
• 2000

We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

• Rubber Technology
• /
• v.12 no.1
• /
• pp.1-7
• /
• 2011

Nanotechnology is the fast becoming key technology of the $21^{st}$ century. Due to its fascinating size-dependent properties, it has gained significant important in various sectors. Myths are being formed on the proverbal nanotechnology market, but the reality is the nanotechnology is not a market but a value chain. The chain comprises of - nanomaterials (nanoparticles) and nanointermediates (coatings, compounds, smart fabrics). Elastomer based nanocomposites reinforced with low volume fraction of nanofillers is the first generation nanotechnology products and it has attracted great interest due to their fascinating properties. The incorporation of nanofillers such as nanolayered silicates, carbon nanotubes, nanofibers, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, barrier properties, flame retardency etc., Extremely small particle size, high aspect ratio and large interface area yield an excellent improvement of the properties in a wide variety of the materials. Uniform dispersion of the nanofillers is a general prerequisite for achieving desired properties. In this paper, current developments in the area of elastomer based nanocomposites reinforced with layered silicate and carbon nanotube fillers are highlighted.

• Elastomers and Composites
• /
• v.29 no.1
• /
• pp.9-17
• /
• 1994

Methylmetharylate grafted latex(MGL) was prepared by emulsion graft copolymerization of methyl methacrylate onto natural rubber latex(NRL) by using t-butyl hydroperoxide and tetraethylene pentamine in an aqueous medium. Blending of MGL and NRL with different mixing ratio carried out and viscosity and particle size distribution of blend latex were determined. It was found that the optimum condition of mature time, vulcanizing temperature and time for preparation of blend latex films were investigated. latex films prepared by dipping process were meaured. As the reuslt, blend latex(NR-d-MG) films obtained from two-dipping system were more excellent than NR and MG film obtained from one-dipping system.

• Proceedings of the KIEE Conference
• /
• 2005.07c
• /
• pp.1936-1938
• /
• 2005

$Al(OH)_3$ is added to the silicone rubber for improvement of its resistance against surface discharge. In this paper, four kinds of $Al(OH)_3$ were added to the SIR during compounding. SIR was deteriorated by a corona treatment. Hydrophobicity recovery rate after corona treatment and arc resistance of SIR were investigated. Hydrophobicity recovery rate of SIR was evaluated by the measurement of contact angle. Arc resistance was evaluated by measuring weight loss of SIR after arc resistance test.

• Elastomers and Composites
• /
• v.58 no.1
• /
• pp.17-25
• /
• 2023

Abrasion tests of model tire tread compounds (NR and NR/BR blend compounds) were performed at different slip angles (1° and 7°) using a laboratory abrasion tester. The abrasion behavior was investigated by analyzing the worn surface and wear particles. The abrasion spacing formed on the specimen worn at the large slip angle of 7° was significantly narrower than that at the small slip angle of 1°, while the abrasion depth for the specimen worn at 7° was lower than that at 1°. The abrasion spacing and depth tended to be narrower and lower, respectively, as the BR content increased. The abrasion patterns were clearly visible on the outside of the specimen for the slip angle of 1° but not for 7°. The wear particles had a rough surface and there were numerous micro-bumps. It was found that the crosslink density affected the abrasion patterns and morphologies of the wear particles.

• Tribology and Lubricants
• /
• v.28 no.6
• /
• pp.283-288
• /
• 2012

In this study, a new sliding contact problem involving an elastomeric seal, a spherical particle and a hard coated steel counterface was modeled to investigate the detailed wear mechanisms related to the sealing surface. The model was also used to design the optimum coating conditions. A three-dimensional finite element contact problem was modeled and analyzed using the nonlinear finite element code, MARC. The deformed steel surface and stress distributions are presented for different coating layers and thicknesses. When the coating thickness is relatively small, the entrapped particle produces surface plastic deformations such as groove and torus. In addition, the sealing surface can be damaged by abrasive wear as well as fatigue wear. For a relatively thick and multi-layered coating, on the other hand, surface plastic deformation does not occur, and the amount of abrasive and fatigue wear is reduced. Therefore, the proposed contact model and results can be used in the design of various sealing systems, further intensive studies are required.

• Elastomers and Composites
• /
• v.48 no.2
• /
• pp.167-171
• /
• 2013

Weatherability was examined according to aluminum particle size and its orientation used in PCM(Paint Coated Metal). Substrate delamination was checked by different UV transmission rate with QUV$^{(R)}$ (Q-LAB) equipment that can make accelerated UV irradiation. Film was prepared using three different types of conflake aluminum pastes under a PCM coating process and clearcoat was sprayed. UV transmission test results showed low transmission rate when EKART #790 having the smallest particle size and horizontal orientation was used. From the gloss retention results, gloss retention was highest in EKART #790 and followed by #770, #750.

• Journal of the Korean Magnetics Society
• /
• v.14 no.4
• /
• pp.131-137
• /
• 2004

For the aim of thin electromagnetic wave absorbers used in mobile telecommunication frequency band (0.8-2.0㎓), we investigate high-frequency magnetic, dielectric and microwave absorbing properties of iron particles dispersed in rubber matrix in this study. The major experimental variables are particle shape (sphere and flake) and initial particle size (in the range 5-70 $\mu\textrm{m}$) of iron powders. High value of magnetic permeability and dielectric permittivity can be obtained in the composites containing thin plate-shape (flake) iron particles (of which thickness is less than skin depth in ㎓frequency), which can be produced by mechanical forging of spherical iron powders using an attrition mill. This result is attributed to the reduction of eddy current loss (increase of permeability) and the increase of space charge polarization (increase of permeability). The optimum initial particle size is found to be about 10 $\mu\textrm{m}$ for the attainment of the material parameters (particularly, real part of complex permeability) satisfying the wave impedance matching. With the iron powders controlled in size and shape as absorbent fillers in rubber matrix, the thickness can be reduced to about 0.7mm with respect to -5㏈ reflection loss (70% power absorption) in mobile telecommunication frequency band.