• Textile Coloration and Finishing
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• v.4 no.3
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• pp.116-121
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• 1992

This paper is on for a material to replace the petroleum-based resins used as adhesives for the fiber in rubber composite materials. The study limited to the reaction properties of tannin with formaldehyde. Tannin-formaldehyde(TF) reactions were carried out in aqueous media. Rates of reaction were strongly dependent on concentration, temperature, pH, and the mole ratio of tannin to formaldehyde. Viscosities of reaction mixtures were followed up to gelation. The reactivity of tannin-formaldehyde resins was greater than that of resorcinol-formaldehyde resins. To formulate an adhesive, a styrene-butadiene-vinyl pyridine terpolymer latex(L) was added to the TF. This preliminary results suggest that the condensed tannins have considerable promise as substitutes for resorcinol used in resin formulation for bonding of fiber to rubber.

• Elastomers and Composites
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• v.28 no.4
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• pp.274-282
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• 1993

Resorcinol-tannin-formaldehyde-latex(RTFL) adhesive was prepared to bond SBR to nylon in reinforced rubber composites. A key factor of adhesive contributes to the adhesion strength between SBR and nylon was the toughness of adhesive itself. Although the stiffness and strength of adhesive film decreased slightly with increasing level of tannin substitution for resorcinol in a standard RFL adhesive, the maximum toughness of adhesive film, which showed yield behavior and high dissipative capacity, was obtain by 60% tannin substitution. However, a marked softening and reduction in toughness occurred at sufficiently high substitution. Also, the adhesive film, which was heat-treated to simulate cure, showed higher strength than the unheated film. Thus, the properties of tannin containing adhesives could be optimized by using 40/60 weight ratio of the resorcinol/tannin in RTFL adhesive composition as well as heat treatment of adhesive film.

• Elastomers and Composites
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• v.50 no.4
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• pp.304-313
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• 2015

In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

• Elastomers and Composites
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• v.37 no.1
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• pp.21-30
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• 2002

Core-shell polymers of methyl methacrylate/styrene pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) as an initiator. The characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, where as polymer blonds or copolymers show a combined properties from the physical properties or two homopolymers. This unique behavior of core-shell composite latex can be used in many industrial fields. However, in preparation of core-shell composite latex, several unexpected phenomina are observed, such as, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve the disadvantages, we studied the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the tore-shell structure or PMMA/PSt and PSt/PMMA. Particle size and particle size distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass transition temperature($T_g$) was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions were measured.

• Textile Coloration and Finishing
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• v.11 no.4
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• pp.50-56
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• 1999

The adhesive properties of polyester cord in rubber matrix were investigated according to the surface modification. The polyester cord was oxidized in sodium hypochlorite solution, and graft-polymerized with acrylic acid under the irradiation with ultraviolet light, and then coated with resorcinol-formaldehyde latex (RFL). The modified surface was checked with scanning electron microscope. The adhesive properties were measured by the full-Out method, and evaluated with regard to the energy of adhesion and the maximum load. The polyester was not oxidized in sodium hypochlorite solution, so the surface was not able to etch to produce the coarse topology. As the concentration of acrylic acid and the reaction time were increased, the graft yields were also increased. It was considered that the acrylic acid would swell the polyester and diffuse easily to the inner side of substrate. The adhesive properties of polyeser to rubber matrix were affected by the surface condition. Namely, the maximum load was almost same, but the energy of adhesion was rather higher In the polyester grafted with acrylic acid than in control one. We concluded that the flexible aliphatic chains of polyacrylic acid situated in the interface of cord and rubber matrix were distributed well the stress and strain all over the filler resulting the high energy of adhesion.

• Elastomers and Composites
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• v.54 no.2
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• pp.97-104
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• 2019

Emulsion styrene-butadiene rubber silica wet masterbatch (ESBR silica WMB) technology was studied to develop highly filled and highly dispersed silica compounds, involving the preparation of a composite by co-coagulating the modified silica and the rubber latex in a liquid phase. Previous studies have shown that when manufacturing ESBR silica WMB/Butadiene silica dry masterbatch (BR silica DMB) blend compounds, preparing BR silica dry masterbatch and mixing it with ESBR silica WMB gave excellent results. However, WMB still has the problem of lower crosslink density due to residual surfactants. Therefore, in this study, tetrabenzylthiuram disulfide (TBzTD) was added instead of diphenyl guanidine (DPG) in the ESBR silica WMB/BR silica DMB blend compounds and sulfur/CBS contents were increased to evaluate their cure characteristics, crosslink densities, mechanical properties, and dynamic viscoelastic properties. TBzTD was found to be more effective in increasing the crosslink density and to produce superior properties compared to DPG. In addition, with increasing sulfur/CBS contents, mechanical properties and rolling resistance were enhanced due to high crosslink density, but the abrasion resistance was not significantly changed because of the toughness.

• Magazine of the Korea Concrete Institute
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• v.8 no.5
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• pp.123-133
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• 1996

Recently, the construction of infrastructures has been booming and accelerating to keep up with rapid economic growth. Construction activities and operation of transportation facilities cause unfavorable effects such as civil petitions associated with vibration-induced damages or nuisances. Accordingly, the objective of this study is to develop vibration-controlled concrete using various vibration-controlled mixtures, and also to recycle obsolete materials in part. As the first step to achieve this research, preliminary mix designs have been carried out to obtain an appropriate mix proportion above 200kg/$\textrm{cm}^2$ in uniaxial compressive strength. Test specimen based on the mix proportion selected have been actuated by the impact hammer to investigate their dynamic characteristics. Vibration-controlled mixtures are foam, latex, rubber powder and plastic resin, which have been determined to reduce a vibration by and large. KS F2437 and travel time method have been used to figure out 1st natural frequency and dynamic elastic moduli. Damping ratios have been computed by adopting the polynomial curvefitting method and the geometric analysis method on the frequency response spectrum curve. of which results have been compared and analyzed hereon.

• Magazine of the Korea Concrete Institute
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• v.3 no.3
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• pp.101-110
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• 1991

Results of an experimental study on the manufacture, the mechanical properties and watertightness of pitch - based carbon fiber reinforced fly ash. cement composites are presented in this paper. The carbon fiber reinforced fly ash. cement composites using early strength cement silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and physical properties such as compressive , tensile and flexural strengths, watertightness and drying shrinkage of lightweight carbon fiber reinforced fly ash cement composites are Improved by using a samll amount of stylene butadiene rubber latex. Also, the manufacturing pnx:ess technology of carbon fiber reinforced fly ash . cement composItes is developed. The development and applications of precast products of lightweight carbon fiber remforced cement composites are expected in the near future.

• Journal of Fashion Business
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• v.12 no.5
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• pp.77-93
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• 2008

The purpose of the study was to examine make-up expression elements of horror characters as an evil spirit, a vampire, a zombie, a monster and a psycho murderer through make-up, focused on horror movies of the United States after1960s. First, an evil spirit was expressed that the pupil grew dim without a focus and the skin was torn by going bad and rot completely. Also, it was expressed that its teeth was changed to pointed canine teeth as a wild beast and its pale and bloodless face showed blood vessels clearly. To express its bloodless and pale skin, air brush was swept into the skin over several times. Its canine tooth was made acryl powder into its shape and was harden to make its shape smooth. Also, it was colored to show people like the real thing. Second, a vampire was expressed by make-up elements as long nails, a sharp canine tooth, a pale skin with a blood vessel and dead eyes. Its rough skin and long nails were manufactured with latex foam, which was colored like the skin. Third, a monster image as a werewolf was expressed by make-up elements as fur, sharp teeth, changed nails and toenails, a rough skin and a face changed to a wolf. Rubber mask and rubber body suit were manufactured as a make-up of special character and so all its body was changed. Fourth, a psycho murderer and body-deformed man were expressed by make-up elements as a distorted mask, swelled-up and deformed skull and face form, terribly deformed body, discolored and hang down skin and teeth with an indeterminate form. Its body and face were manufactured by the foam latex technology according to make-up design as a make-up of special character.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.25-32
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• 2013

This study has been conducted in order to propose Eco-friendly and High functional waterproofing technology available for structure by verifying application and performance of water proofing material(s) in purpose of making effective use of reclaimed rubber. As s result of 12 months evaluation, stable performance for water pressure and lateral pressure of $0.3N/mm^2$ were confirmed. Also, as the time elapsed, the amount of water absorption and adhesion performance showed only a slight difference(+0.05g, $-0.1Nmm^2$) as well, which in turn confirmed that waterproofing performance remains stable. Studies show that it is expected to expand recycling technology of natural rubber by applying reclaimed rubber on construction waterproofing field, and to hold a technical superiority by using eco-friendly material in construction waterproofing market throughout active application of these types of research.