• Title/Summary/Keyword: rosin

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A Study on the Physical Properties according to Varnish Cooking Conditions of Phenolic Modified Rosin Ester (로진변성 페놀수지의 Varnish 제조조건에 따른 물성 변화에 관한 연구)

  • Jung, Soon-Kie;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.24 no.2
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    • pp.11-24
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    • 2006
  • The Lithographic ink is composed of pigment, vehicle and additives. In especially, the vehicle is the most important element and consist of vegetable oils, mineral oils and resins. Varnishes have to resist certain forms of chemical and physical attack during ink manufacturing process and printing process So this varnish cooking is very important. In this paper, effects of cooking conditions of varnish using phenolic modified rosin ester on physical properties of the vehicle were studied. The varnish cooked according to temperature and time were compared in order of average molecular weight by the GPC method. and the rheological properties were found by rotational rheometer. And the emulsion behavior were compared by high speed emulsification tester which were set on 1200 rpm and $40^{\circ}C$ temperature (Novomatics Lithotronic). We displayed viscosity against tack(Inkometer Thwing-Albert M-106) by diagram.

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Analysis of Production Process of Fine Size Fraction of Korean Kaolin by Ball Mill Grinding I (Ball Mill 분쇄에 의한 고령토의 미분성분 생성과정의 해석 I)

  • 심철호;김상필;서태수
    • Journal of the Korean Ceramic Society
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    • v.23 no.4
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    • pp.35-40
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    • 1986
  • The production process of a fine size fraction of Korean kaolin by ball milling is studied in this paper by analyzing the size distribution the size distribution of products with the Rosin-rammle formular and the rate process of cumulative size fractions with Alyavdin-Chujyo's formular. The size distribution is found to be divided in three regions a coarser part influenced by feed size an intermediate part where the size distribution shows a clear straight line relationship on Rosin-Rammler chart and the finest part with the ultimate limit of fineness by ball milling. Alyavdin-Chujyo's relationship is found to be valid over a very wide range of milling conditions. For different feed sizes the Alyavdin-Chujyo's relationship gives a group of straight lines with a common intersection point which can be defined as the limiting point of the persistent component region.

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Analysis of Production Process of Fine Size Fraction of Korean Kaolin by Ball Mill Grinding II (Ball Mill 분쇄에 의한 고령토의 미분성분 생성과정의 해석(II))

  • 서태수;심철호;김상필
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.1-8
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    • 1987
  • The validity of Alyavdin-Chujyo's Equation was re-examined over the broader milling conditions that those previously examined. Ordinary ball mill grinding with a laboratory scale batch mill (133mmø×144mm length) were selected as the grinding methods. The results show that in ball milling the Alyavdin-Chunjyo's Equation can be applicable over wide grinding time and size range with few exceptions. The validity of which are examined and discussed. The theoretical consideration of the relation between Alyavdin-Chujyo's Equation and size distributiion equation, such as Rosin-Rammler's law, was tried, and it is found that, under the condition of alyardin-Chujyo's relation, the Rosin-Rammler size distribution law can hold.

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Applicability of Color Bituminous Mixtures for Highway Pavement (차도용 칼라 역청 혼합물의 적용성 연구)

  • Doh, Y.S.;Oh, S.K.;Choi, Y.K.;Kim, K.W.
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.91-100
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    • 2004
  • This study was Performed to evaluate applicability of color flexible pavement concrete (CFPC) for motorway pavement. Color flexible pavement has been applied to non-motorway pavements, such as pedestrian and bicycle road. Two polymers were used to modify the binder and to strengthen the stiffness of pavement mixture. Waste paper was used to prevent the asphalt of gap-grade mixture from draining. Marshall properties, indirect tensile strength(ITS), tensile strength ratio(TSR) before and after freezing-and-thawing treatment and artificial aging, permanent deformation and fatigue life were measured. Color bituminous concrete mixtures used this study had nearly the same quality in mechanical properties when compared with conventional asphalt concrete mixtures manufactured with AP-3 and all mixtures satisfied with domestic specification for motorway pavement. Therefore, it is proved that the color bituminous concrete used this study can be applied for motorway pavement.

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Adhesion Performances of Natural Adhesives Made by Rosin (로진을 이용한 천연접착제의 접착물성)

  • Choi, Jae-Hoon;Hwang, Hyeon-Deuk;Moon, Je-Ik;Kim, Hyun-Joong;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.4
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    • pp.38-44
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    • 2007
  • As environmental issues is important thing, our study aims to develop natural adhesives made by rosin instead of synthesis adhesive with the formaldehyde emission. Natural adhesives were formulated to enhance curing speed and adhesion performances with various drying agent contents. Adhesion performances were evaluated with tack values measured by texture analyzer and shear strengths determined by single lap shear test. The adhesion performances of nature adhesives developed in this study and compared with those of overseas natural adhesives made by AURO, BioFa, Livos. Optimum drying agent formulation was Co 0.7 part, Zr 1.0 part, Ca 0.5 part, and Activ8 0.1 part. Shear strength of the adhesives manufactured by the optimum drying agent formulation was $93.2{\pm}19.1N/cm^2$.

Development of fluoride varnish with sustained fluoride release and biocompatibility (불소 지속방출 및 생체적합성을 가진 불소 바니쉬의 개발)

  • Shin, Kyung-Su;Kim, Ah-Jin;Oh, Seunghan;Bae, Ji-Myung
    • Korean Journal of Dental Materials
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    • v.44 no.1
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    • pp.21-31
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    • 2017
  • The purpose of this study was to fabricate a biocompatible fluoride varnish with sustained fluoride release, and to compare it with commercial fluoride varnishes. For the experimental fluoride varnish, bis-GMA (BG) or two types of rosin (KR-610: K0, KR-612: K2) were used as bases. Either ethyl acetate or ethanol was added as solvent and 5 wt% NaF was used. 5 mg of experimental F- varnishes and 2 commercial products, Cavity shield (CS) and Flor-opal (FO), were applied on a labial surface of bovine teeth ($10mm{\times}7mm$). The amount of fluoride release was measured at 1 hr, 2 hrs, 3 hrs, 4 hrs, 8 hrs, 12 hrs, 1 day, 3 days, 5 days, 10 days, 15 days, 20 days and 30 days. MTT test was done with diluted F- varnishes using ethanol. Statistical analysis was done with one-way ANOVA and Duncan multiple range test (${\alpha}=0.05$). BG showed the highest fluoride release at 1 hr (P<0.05), while that of K0 was highest at 2 hrs (P<0.05). From 1 day to 5 days, experimental fluoride varnishes showed higher fluoride release than the commercial products (P<0.05), and there were no significant differences after 5 days (P>0.05). For MTT test, K0 and FO showed higher cell viability than other experimental groups (P<0.05), with no significant differences with K2 (P>0.05). Considering the sustained fluoride release and cell viability of the experimental rosin-based fluoride varnishes compared with commercial products, it will be appropriate for clinical application.

A Study on the Manufacturing and Applicability of Rosin-based Epoxy Adhesives and Filling Material for Conservation of Wood Crafts (목공예품 보존용 송진 기반 에폭시 접착제 및 메움제의 제조와 적용성에 관한 연구)

  • Wi, Koang-Chul;Han, Won-Sik;Oh, Seung-Jun
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.475-482
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    • 2020
  • In this study, we synthesized rosin-based epoxy resin and manufactured two components adhesives and epoxy putty using this epoxy resin. This study manufactured main element of adhesives for enabling it to form epoxide group by letting epichlorohydrin react to maleic anhydride modified rosin, and used room temperature curing type triethylenetetramine for hardener. The ratio between main element and hardener of of manufactured adhesives was 100 : 20, and main element and hardener of filling material were manufactured as clay type by mixing them with filler. Manufactured undiluted adhesives and filling material showed very stable result in the adhesive strength (3.06 MPa) and ultraviolet irradiation, showing outstanding result comparing to existing restoration adhesives. And it is considered a material having reversibility as it was dissolved in organic solvents such as acetone and toluene after being hardened, which showed a result that solved part of possible problems caused by restoration. As a result of use and application of manufactured adhesives and filling material for actual wood crafts, they showed excellent results in workability, stability, removability etc., and this study confirmed that the material can be used for and applied to various fields.

Compatibility and Properties of SIS Pressure Sensitive Adhesives (SIS계 점착제의 상용성과 점착물성)

  • Yoon, J.;Shim, M.J.;Kim, S.W.
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.851-856
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    • 1994
  • Compatibility and viscoelasticity in non-solvent type pressure sensitive adhesive of styrene-isoprene-styreno(SIS) block copolymer with tackifier resin were investigated. In the isoprene phase of SIS block copolymer, it was found that it's compatibility with $C^5$ petroleum resin was good, but that with Coumarone-indents resin was not so good. The magnitudes of peel strength, tack, and holding power were as follows : $C^5$ petroleum resin>rosin ester resin>coumarone-indene resin. The tackifier resin with good compatibility in rubber phase was also effective. However, with plateau modulus value of $1{\times}10^6-3{\times}10^6dyn/cm^2$, the effect of pressure sensitive adhesives was excellent.

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Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephthalate and its Sizing Efficiency (Part 2) - Sizing efficiency of modified PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제2보) - 개질 PET의 내수특성 평가 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.95-101
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    • 2010
  • For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

Drying Rate of Natural Paint Made by Rosin Using HORUS (HORUS를 이용한 천연페인트의 건조속도)

  • Choi, Jae-Hoon;Hwang, Hyeon-Deuk;Moon, Je-Ik;Kim, Hyun-Joong;Lee, Sun-Sang;Lee, Gwan-Hyung
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.4
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    • pp.45-51
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    • 2007
  • To investigate the drying behaviors of the water-based natural coating made by rosin during drying, the mass transfer and optical change from speckle image and speckle rate were measured and the relationship between two analysis methods were investigated. At a linear scale, the speckle rate measured by HORUS related with the mass transfer of coating during drying, and the speckle rate at a log scale was included not only drying time, but also drying mechanism of coating during drying. Therefore, the HORUS was an available method to investigate the drying time and drying mechanism of coating during drying.