• Journal of the Korean Applied Science and Technology
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• v.23 no.1
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• pp.77-84
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• 2006

Modified polyesters (TTBA-10C, -20C, -30C) that contain phosphorus and chlorine were synthesized by the condensation polymerization of tetramethylene bis(orthophosphate), neohexanediol trichlorobenzoate, 1,4-butanediol and adipic acid, in which tetramethylene bis(orthophosphate) and neohexanediol trichlorobenzoate were prepared previously in our laboratory. In this study, two-component flame-retardant polyurethane coatings (TTBA-10C/HDI-trimer=TTHD-10C, TTBA-20C/ HDI-trimer= TTHD-20C, TTBA-30C/HDI-trimer= TTHD-30C) were obtained by curing at room temperature with the synthesized TTBAs and hexamethylene diisocyanate (HDI)-trimer as a curing agent. The obtained TTHDs were made into coating samples and used as test samples for various physical properties. The physical properties of the flame-retardant coatings containing chlorine and phosphorus groups were generally inferior to those containing only phosphorus group. Flame retardancy was tested by vertical and horizontal combustion method, and $45_{\circ}$ Meckel burner method. Since the retardancy of flame-retardant coatings containing chlorine and phosphorus groups was better than that containing only phosphorus group, it could be concluded that the retardancy by the synergism effect of chlorine and phosphorus groups exhibited.

• Journal of the Korean Applied Science and Technology
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• v.25 no.3
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• pp.322-331
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• 2008

In order to synthesize high-solid coatings, acrylic resins (HSAs) containing 90% solid content were first synthesized, then the synthesized HSAs were cured with a curing agent, isocyanate, at room temperature to obtain high-solid coatings. In the HSAs synthesis, conversion was in a range of $82{\sim}87%$, and viscosities and number-averaged molecular weight ($M_n$) of the HSAs were in a range of $4380{\sim}8010$ cP and $1540{\sim}1660$, respectively. From the correlation between $T_g$ value, viscosity and $M_n$, it was found that, with increasing $T_g$ value, viscosity increases rapidly and molecular weight increases slowly. From the visco-elasity measured by the pendulum method, it was found that the curing time decreased with increasing $T_g$ values. From the tests of physical properties of the coatings' film, $60^{\circ}$ specular gloss, impact resistance and heat resistance were proved to be good and pencil hardness, drying time and pot-life were proved to be poor.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.15-21
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• 2015

In this study, rheological properties and flow dynamics in roll coating process of basecoat paints have been investigated for automotive precoated metal (PCM) sheet applications. Various rheological properties for basecoats with three colors (black, blue, and silver), such as shear viscosity data at room temperature and elastic/viscous moduli under thermal curing condition, have been measured using a rotational rheometer. It is found that the relative portion of function groups inside basecoats and their viscosity level have greatly affected the formation of crosslinked networks by thermal curing. Also, operability coating windows for basecoats have been established in three-roll coating process system by observing their flow instabilities such as ribbing and cascade. It is confirmed that rheological approaches applied in this study have been usefully applied to develop environmentally-friendly PCM coating technology and optimally control the coating operations for non-Newtonian PCM paints.

• Journal of the Microelectronics and Packaging Society
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• v.20 no.1
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• pp.21-26
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• 2013

This study presents new analysis method to predict bending behavior of packaging substrate structure by comparing finite element method simulation and measured curvature using 3D scanner. Packaging substrate is easily bent and deflected while undergoing various processes such as curing of prepreg and copper pattern plating. We prepare specimens with various conditions and measure contours of each specimen and compute the residual stresses on deposited films using analytical solution to find the principle of bending. Core and prepreg in packaging substrate are made up of resin and bundles of fiber which exist orthogonally each other. Anisotropic material properties cause peculiar bending behavior of packaging substrate. We simulate the bending deflection with finite element method and verify the simulated deflection with measured data. The plating stress of electrodeposited copper is about 58 MPa. The curing stresses of solder resist and prepreg are about 13 MPa and 6.4 MPa respectively in room temperature.

• The Journal of Korean Academy of Prosthodontics
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• v.37 no.2
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• pp.167-184
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• 1999

The purpose of this study was to evaluate and compare the at of denture bases processed by injection pressing technic using laser scanner of reverse engineering technic. The auther duplicated 20 maxillary edentulous models and 20 mandibular edentulous models, which were scanned on HYSCAN 45C 3D BCANNER(Hymarc Co., Canada). The scanned data were stored in the personal computer using SURFACER (Imageware Co. U.S.A.) software program. After 40 dentures were cured by PERform Inkovac system, SR-Ivocap system, Palajet system, and Sulfon system, they were stored in water at room temperature fir 24 hours. The dentures were scanned on HYSCAN 45C 3D SCANNER(Hymarc Co., Canada). The scanned data were stored in the personal computer using SURFACER (Imageware Co., U.S.A.) software program. By overlapping two images using the same program, the fit between two surfaces was scaled by positive and negative errors. The obtained results were as follows 1. In the upper denture, most of the positive errors occurred on the lingual side of anterior alveolar ridge and the negative errors were on the flange of denture bases. 2. In the lower denture, most of the positive errors occurred on the inner side of lingual flange and the negative errors were on the border of anterior labial flange areas, 3. There were no statistical differences among the positive errors of the four types of injection denture curing methods and also no statistical differences between negative errors except only in negative maximum errors. 4. In PERform system and SR-Ivocap system, they have the tendency of inaccurate at of lower denture bases comparing to that of upper denture bases. 5. The negative error scales were greater than the positive error scales in all types of injection denture curing methods.

• Composites Research
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• v.34 no.5
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• pp.269-276
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• 2021

PCM (Prepreg Compression Molding) process is a high-speed molding technology that can manufacture high-quality CFRP (Carbon Fiber Reinforced Plastic) parts. Compared to the autoclave process, it generates less waste and can significantly reduce cycle time, so various studies are being conducted in the aerospace and automobile industries. In this study, in order to improve the quality of the PCM process, a molding method was developed to increase the compression pressure of the press step by step according to the curing behavior of the prepreg. It was confirmed that this multi-stage compression molding technology is a good means to produce high-quality CFRP products and shorten cycle times. And, the laminated prepreg at room temperature was immediately put into the mold and preheated and molded at the same time, so that it could be molded without a separate preheating process. In addition, as a result of applying the same process conditions optimized for flat plate molding to three-dimensional shapes, a product similar to a flat plate in appearance could be made without the process of establishing process conditions.

• Journal of the Korean Wood Science and Technology
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• v.32 no.5
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• pp.59-65
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• 2004

The present study aims to optimise the process parameters of fish glue and adhesion property through room temperature in terms of curing time and opened assembly time for attaining best adhesion strength to wood (Yellow birch, B. alleghaniensis). The uncured and cured fish glue have been characterised by TGA, DSC, FT-JR. It is observed that with increasing curing time up to 48 H, tensile lap shear strength of adhesive joint of fish glue to wood increases and decreases after 48 H. At 15 min. opened assembly time, lap shear strength increases up to 4833 kgf/cm² and decreases after 15 min.

• International Journal of Highway Engineering
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• v.15 no.2
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• pp.113-119
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• 2013

PURPOSES : The objectives of this study are to develop the eco-friendly pavement material using polyurethane binder and evaluate mechanical properties of the developed binder and concrete. METHODS : The bending beam test was conducted to select the sample candidates of polyurethane binder based on the bending strength. The characteristics of viscosity, curing time, and temperature change of sample binder was examined on different temperature conditions. The mechanical properties of polyurethane binder was estimated using the dynamic modulus testing. The indirect tensile strength test was conducted on polyurethane binder concrete with different gradation and binder content for evaluating the mechanical properties of concretes. RESULTS : Based on the beading beam test, four different binder samples were prepared for estimate the mechanical properties. The viscosity of polyurethane binder tends to increase with increase of liquid temperature and the hardening phenomenon begins 10 to 15 minutes at room temperature after mixing the resin and hardener. It is observed that the dynamic modulus of binder increases as loading frequency increases and change of modulus is found to be the highest in the PU-2I binder type. The PU-2I binder concretes shows the largest value of indirect tensile strength and indirect tensile energy. CONCLUSIONS : The use of polyurethane binder as pavement materials is capable of increasing the pavement performance and reducing the detrimental environmental effect during the highway construction.

• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.3
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• pp.83-91
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• 2011

This study aimed to investigate the engineering and environmental characteristics of phosphogypsum-cement-soil mixtures composed of phosphogypsum, soil, and a small amount of cement was analysed on the basis of the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test, SEM and EDS analysis, XRD analysis and Leaching test. The specimens were manufactured with soil, cement and phosphogypsum. The cement contents was 10 %, and the phosphogypsum contents was 10, 20, 30, and 40 % by the weight of total dry soil. Each specimen was manufactured after curing at constant temperature and humidity room for 3, 7 and 28 days, after which the engineering characteristics of phosphogypsum-cement-soil mixtures were investigated using the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test. The basic data were presented for the application of phosphogypsum-cement-soil mixtures as construction materials. To investigate the environmental characteristics, leaching test was performed and the leaching test results were far below than of regulatory requirement of Waste Management Act in Korea. Therefore the results show that phosphogypsum is environmentally safe and can be used as construction materials in environmental aspect.

• Journal of the Korean Applied Science and Technology
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• v.17 no.1
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• pp.7-13
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• 2000

Quater polymer(MBHA) containing two types of acrylic functional group, acetoacetoxyethyl methacrylate(AAM) and 2-hydroxyethyl acrylate was prepared. Then, the MBHA was blended with polyisocyanate type Desmodur IL as a curing agent. Thereafter the mixture was cured at room temperature to get high solid acrylic/polyisocyanate. The MBHA was synthesized at $150^{\circ}C$ for 6 hours typically, and the final conversion reached 87-88%. Lowering Tg and increasing AAM amount in the MBHA resulted in high value of conversion. There was no difference in conversion with the variations of OH values. From the results of physical property tests, MIHS coating was proved to be a good automotive top-coating material.