• 공업화학
• /
• 제18권6호
• /
• pp.630-635
• /
• 2007

구조중에 1개의 tert-부틸기를 가진 새로운 형태의 키랄살렌 착체를 합성하여 비대칭반응 촉매로서 활용하였다. 알루미늄족의 금속염을 소유한 이량체형의 키랄 살렌 촉매는 에폭사이드의 산소고리를 페놀류로 여는 비대칭반응에서 매우 높은 활성과 선택성을 나타내었다. 또한 무기담체에 고정화된 살렌 착체도 이 반응에 대하여 효과적인 촉매로 사용할 수 있었다. 새로운 키랄 살렌촉매 중에 존재하는 금속염의 종류는 광학선택적 반응에서 중요한 영향을 나타내었다.

• 오토저널
• /
• 제10권6호
• /
• pp.48-53
• /
• 1988

In a previous report, the properties of vegetable oils as diesel fuel substitutes were investigated and the basic load performance of a diesel engine was examined using vegetable oil. The results show that despite of the long term chain hydrocarbon structure and large droplet size due to high viscosity, vegetable oils have good basic performance and exhaust emissions, however they cause serious problems as carbon deposit buildup, they have poor durability, and also poor thermal efficiency. In this paper, the startability and engine durability with long term operation was tested by physical methods for reducing viscosity when vegetable oil was used as compared against diesel fuel. The results obtained in this investigation may be stated as follows; (1) There is no problem in startability when vegetable oil was used as diesel fuel substitutes as far as fuel temperature is higher than 30.deg. C (2) The carbon deposits were most extensive at lower loads and lower engine speeds, and deposit buildup more heavily on the cooler parts of the combustion chamber wall. (3) Blends with 25% diesel fuel and 20v-% ethanol are effective in reducing the carbon deposit buildups. (4) Significant improvement in carbon deposit and piston ring stick can be obtained by heating fuel(200.deg.).

• 한국가구학회지
• /
• 제26권2호
• /
• pp.179-185
• /
• 2015

A study was carried out to observe the 1% aqueous safranine solution flow speed in longitudinal and radial directions of softwood G. biloba, ring-porous wood A. altissima, and diffuse- porouswood D. kaki. In radial direction, ray cells and in longitudinal direction tracheids, vessel and wood fiber were considered for the measurement of liquid penetration speed at less than 12% moisture contents (MC). The length, lumen diameter, pit diameter, end wall pit diameter and the numbers of end wall pits determined for the flow rate. The liquid flow in the those cells was captured via video and the capillary flow rate in the ones were measured. Vessel in hardwood species and tracheids in softwood was found to facilitate prime role in longitudinal penetration. Radial flow speed was found highest in ray parenchyma of G. biloba. Anatomical features like the length and diameter, end-wall pit numbers of ray parenchyma were found also responsible fluid flow differences. On the other hand, vessel and fiber structure affected the longitudinal flow of liquids. Therefore, the average liquid penetration depth in longitudinal tracheids of G. biloba was found the highest among all cells considered in D. kaki and A. altissima.

• 한국전자파학회논문지
• /
• 제10권6호
• /
• pp.866-878
• /
• 1999

본 논문에서는 원형 디스크와 두 개의 환 디스크로 구성된 페라이트 공진기를 갖는 스트럽라인 서률레이 터를 설계하고 제작한다. 순환 그런함수 가법을 이용하여 각 단자의 전자계를 구하고 입력 임피던스와 산란 행렬을 유도한다. 페라이트 공진기의 각 디스크에 대한 매질 배치에 따른 서율레이션 특성, 바이어스 필드의 세기에 따른 서률레이션 특성과 포트 단자의 폭에 따른 서률레이션 특성을 비교. 분석한다. 설계된 제원을 사용하여 제작한 서률레이터의 통과대역 주파수는 1.55 GHz에서 2.95 G Hz까지이고 입력 단의 반사계수 $S_{11}$ 은 공진접 2.38 GHz에서 30 dB, 아이솔레이션 단에서 입력 단으로의 전송계수 $S_{21}$은 - 28 dB로 나타났다

• 한국철도학회:학술대회논문집
• /
• 한국철도학회 2008년도 춘계학술대회 논문집
• /
• pp.1032-1038
• /
• 2008

KTX train system is composed of TORNAD* network for transmitting information of train's internal equipments and OBCS which proceed information within train. OBCS of one trainset consisted of 28 equipments takes intelligent and dynamic composition according to equipment handling, train command and control flow. Each OBCS which is installed within trainset handle and supervise mutually action information about equipments, transmit it to driver to transmit information about train operation and preventive management. This mutual supervision and information transmission use KTX TORNAD* network system. TORNAD* network system is the one which is uniquely developped by GEC ALSTHOM, the KTX trainset manafacturing provider and this field is excluded from technical know-how transfer item. Through the research on analysis method of KTX TORNAD* system data structure which is operating on Seoul-Pusan Line, I hope that this thesis can contribute to train network system's standardization after applying it to improvement of train network system maintenance, enhancing quality of train service and applying it to future Korean rolling stock network system development.

• Bulletin of the Korean Chemical Society
• /
• 제33권1호
• /
• pp.270-274
• /
• 2012

The nucleophilic substitution reactions of 1,2-phenylene phosphorochloridate (1c) with X-pyridines are investigated kinetically in acetonitrile at $-25.0^{\circ}C$. The free energy correlations for substituent X variations in the nucleophiles exhibit biphasic concave upwards with a break point at X = 3-Ph. The pyridinolysis rate of 1c with a cyclic five-membered ring is $2.70{\times}10^5$ times faster than its acyclic counterpart (1a: phenyl ethyl chlorophosphate) because of great positive value of the entropy of activation of 1c (${\Delta}S^{\neq}$ = +26 eu) compared to negative value of 1a (${\Delta}S^{\neq}$= -24 eu) over considerably unfavorable enthalpy of activation of 1c (${\Delta}H^{\neq}=20.5kcal\;mol^{-1}$) compared to 1a (${\Delta}H^{\neq}=12.7kcal\;mol^{-1}$). Great enthalpy and positive entropy of activation are ascribed to sterically congested transition state (TS) and solvent structure breaking in the TS. A concerted mechanism involving a change of nucleophilic attacking direction from a frontside attack with the strongly basic pyridines to a backside attack with the weakly basic pyridines is proposed on the basis of greater selectivity parameters (${\rho}_X$ = -1.99 and ${\beta}_X$ = 0.41) with the strongly basic pyridines compared to those (${\rho}_X$ = -0.42 and ${\beta}_X$ = 0.07) with the weakly basic pyridines.

• Bulletin of the Korean Chemical Society
• /
• 제31권11호
• /
• pp.3297-3300
• /
• 2010

In this study, the 3D-QSARs (three-dimensional quantitative structure-activity relationships: CoMFA and CoMSIA) between structural changes of N-phenyl-O-phenylthionocarbamate analogues (1-30) and their fungicidal activities against the capsicum phytophthora (Phyophthora capsici) fungi were analyzed, then considered quantitatively in terms of minimum structural requirements for fungicidal evaluation. The statistical qualities ($r^2_{cv.}$ = 0.510 and $r^2_{ncv.}$ = 0.948) of the optimal CoMFA 1 model are improved over the other models in the conditions of field combinations, and the two alignments. In the optimal CoMFA 1 model, relative contribution percentages of the CoMFA field were: steric field, 52.3%; electrostatic field, 37.8%; hydrophobic field, 9.9%. Results were similar for the CoMFA 2 model. Therefore, the steric field of the analogues had the highest contribution ratio for fungicidal activity. Specifically, with the contour map of steric fields, the fungicidal activity increased when bulky steric Y-substituents were introduced to the meta-position on the N-phenyl ring and small steric Y-subsituents were introduced to its para-position.

• Bulletin of the Korean Chemical Society
• /
• 제28권8호
• /
• pp.1299-1304
• /
• 2007

New sulfur functionalized cyclopentadiene ligands, 1-[2-(thioanisole)]-2,5-dimethylcyclopentadiene (3), 1-[2- (thioanisole)]-2,3,5-trimethylcyclopentadiene (4), and 1-[2-(thioanisole)]-2,3,4,5-tetramethylcyclopentadiene (5), were prepared. In these ligands, the S-donor atom is connected to a cyclopentadiene ring by a rigid phenylene spacer. CpCo(III)-diiodo half-sandwich complexes (6-8) were obtained from reaction the ligands (3- 5) with Co2(CO)8, followed by treatment of I2. Substitution reaction of CpCo(III)-diiodo complexes with MeLi yielded the corresponding CpCo(III)-dimethyl complexes (9-11). Further transformation to the corresponding cationic cobalt complexes (12-14) were achieved by reaction of the CpCo(III)-dimethyl complexes with HB(ArF)4·2Et2O and trapping with CD3CN. The new sulfur functionalized cyclopentadiene ligands having a rigid phenylene spacer and the corresponding cobalt complexes were characterized by 1H, 13C and 19F NMR spectroscopy. The diiodo Complex 6 was also characterized by a single crystal X-ray diffraction method.

• 한국물환경학회지
• /
• 제31권4호
• /
• pp.418-427
• /
• 2015

This study was carried out to evaluate the performance of a lab-scale novel septic tank system for improving the conventional septic tank in the developing countries of water shortages. The lab-scale novel septic tank system consists of sepetic tank, aeration tank with HBC-ring, and sand filter. Optimum HRT was reguired about 1.5days to get a total COD removal efficiency of 90%, COD, BOD and SS removal efficiency was about 70%, 60%, and 85% in sepetic tank only. The structure of sepetic tank with two stages results in the high removal efficiency of organic matter. When sepetic tank, aeration tank, and sand filter were more than HRT 1.5days, 18hrs, and 12hrs, respectively, final effluent was less than 20 mg/L of BOD, 14 mg/L of SS, so that there is a high potential of its use for reusing water in flush toilet. There is no significant effect of HRT change on nutrient removal. Total nitrogen removal efficiency was about 40%, final effluent was 30~40 mg/L of TN, total phosphorus removal efficiency was about 11~25%, final effluent was 9~12 mg/L of TP. Because there is very small amounts of organic nitrogen and phosphorus in effluent, it was possible to reuse water for agricultural use.

• ETRI Journal
• /
• 제19권4호
• /
• pp.402-413
• /
• 1997

A CMOS device which has an extended heavily-doped amorphous silicon source/drain layer on the field oxide and an amorphous silicon local interconnection (ASLI) layer in the self-aligned source/drain region has been studied. The ASLI layer has some important roles of the local interconnections from the extended source/drain to the bulk source/drain and the path of the dopant diffusion sources to the bulk. The junction depth and the area of the source/drain can be controlled easily by the ASLI layer thickness. The device in this paper not only has very small area of source/drain junctions, but has very shallow junction depths than those of the conventional CMOS device. An operating speed, however, is enhanced significantly compared with the conventional ones, because the junction capacitance of the source/drain is reduced remarkably due to the very small area of source/drain junctions. For a 71-stage unloaded CMOS ring oscillator, 128 ps/gate has been obtained at power supply voltage of 3.3V. Utilizing this proposed structure, a buried channel PMOS device for the deep submicron regime, known to be difficult to implement, can be fabricated easily.