• 폴리머
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• 제26권5호
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• pp.568-574
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• 2002

호스트 분자로서 환형 폴리옥시에틸렌을 사용한 inclusion 화합물을 이용하여 수용액상에서 피롤의 화학적 중합을 수행하였다. 이와 같은 합성 전략은 수용액상에서 화학적 산화방법에 의해 견고한 방향족 고분자의 사슬을 성장시킬 수 있는 가능성을 나타내며, 수용성 올리고 또는 폴리피롤을 손쉽게 얻을 수 있는 방법을 제시하고 있다. 본 연구에서는 부분적으로 고분자 주사슬에 환형 폴리옥시에틸렌을 함유한 수용성 폴리피롤을 얻었으며, NMR, IR, UV 및 MALDI-TOF MS 분석 등을 통하여 그 구조를 확인하였다.

• Geomechanics and Engineering
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• 제30권1호
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• pp.51-66
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• 2022

The article presents the results of finite element analyses carried out on skirted footings. The bearing capacity increases with the provision of the flexible and rigid skirt, but the effectiveness varies with various other factors. The skirts are more efficient in the case of cohesionless soils than cohesive and c-ϕ soils. Efficiency reduces with an increase in the soil strength and footing depth. The rigid skirt is relatively more efficient compared to the flexible skirt. In contrast, to the flexible skirt, the efficiency of the rigid skirt increases continuously with skirt length. The difference in the effectiveness of both skirts becomes more noticeable with an increase in the strength parameters, skirt length, and footing depth. The failure mechanism also changes significantly with the inclusion of a rigid skirt. The rigid skirt behaves as a solid embedded footing, and the failure mechanism becomes confined with an increase in the skirt length. Few small-scale laboratory tests were carried out to study the flexible and rigid skirt and verify the numerical study results. The numerical analysis results are further used to develop nonlinear equations to predict the enhancement in bearing capacity with the provision of the rigid and flexible skirts.

• Computers and Concrete
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• 제33권4호
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• pp.445-469
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• 2024

The Federal Highway Administration (FHWA) has recommended the use of AASHTOWare Pavement Mechanistic-Empirical Design (PMED) software for Roller-Compacted Concrete (RCC) pavement design, but specific calibration for RCC is missing. This study investigates the software's capacity to predict the long-term performance of RCC roadways within the framework of conventional concrete pavement calibration. By reanalyzing existing RCC projects in several U.S. states: Colorado, Arkansas, South Carolina, Texas, and Illinois, the study highlights the need for specific calibration tailored to the unique characteristics of RCC. Field observations have emphasized occurrence of early distresses in RCC pavements, particularly transverse-cracking and joint-related issues. Despite data challenges, the AASHTOWare PMED software exhibits notable correlation between its long-term predictions and actual field performance in RCC roadways. This study stresses that RCC applications with insufficient joint spacing and thickness are prone to premature cracking. To enhance the accuracy of RCC pavement design, it is essential to discuss the inclusion of RCC as a dedicated rigid pavement option in AASHTOWare PMED. This becomes particularly crucial when the rising popularity of RCC roadways in the U.S. and Canada is considered. Such an inclusion would solidify RCC as a viable third option alongside Jointed Plain Concrete Pavements (JPCP) and Continuously Reinforced Concrete Pavements (CRCP) for design and deployment of rigid pavements. The research presents a roadmap for future calibration endeavors and advocates for the integration of RCC pavement as a distinct pavement type within the software. This approach holds promise for achieving more precise RCC pavement design and performance predictions.

• 대한기계학회논문집
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• 제16권7호
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• pp.1255-1265
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• 1992

본 연구에서는 단열 및 온도가 영으로 고정된 경계조건을 갖는 대칭 입술형과 대칭 익형 강체함유 물상의 접합경계면 균열에 대한 Hilbert 문제로부터 복소 포텐셜 함수와 커스프 균열선단 그리고 접합경계면 균열선단에서 TSIF를 구하고자 한다.

• 접착 및 계면
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• 제13권4호
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• pp.163-170
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• 2012

${\beta}$-cyclodextrin은 다른 분자를 포접하여 inclusion complex (포접착물)를 만드는 특성을 가지고 있기 때문에 의약품, 농약, 식품, 화장품, 산화방지제, 휘발방지제, 흡습방지제, 퇴색방지제, 유화제 등의 다양한 용도로 사용되고 있다. 이러한 장점에도 불구하고 ${\beta}$-cyclodextrin은 물이나 유기용매에 대한 용해도가 낮아 사용에 제약을 받아왔다. 본 연구에서는 이러한 문제를 해결하기 위해서 Bisphenol-A나 폴리우레탄(PU) 발포제인 cyclopropane에 대한 포접특성을 갖고 물이나 유기용매에 대한 용해도가 향상된 polyol type의 ${\beta}$-cyclodextrin 유도체를 합성한 후 그 특성을 고찰하였다. 연구결과 합성된 polyol을 사용해서 제조한 경질 PU foam은 기존의 polyol과 비교해서 더 우수한 열전도 특성과 압축강도를 나타내었다.

• Geomechanics and Engineering
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• 제29권2호
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• pp.155-170
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• 2022

An accurate analysis of structures supported on soft soils and subjected to seismic loading requires the consideration of the soil-foundation-structure interaction. An important aspect of this interaction lies with the energy dissipation due to soil material damping. Unlike advanced constitutive models that can induce energy loss, the use of simple elastoplastic constitutive models requires additional damping. The frequency dependent Rayleigh damping is a formulation that is frequently used in dynamic analysis. The main concern of this formulation is the correct selection of the target damping ratio and the frequency range where the response is frequency independent. The objective of this study is to investigate the effects of the Rayleigh damping parameters in soil-pile-structure and soil-inclusion-platform-structure systems in the presence of soft soil under seismic loading. Three-dimensional analyses of both systems are carried out using the finite difference software Flac3D. Different values of target damping ratios and minimum frequencies are utilized. Several earthquakes are used to study the influence of different excitation frequencies in the systems. The soil response in terms of accelerations, displacements and strains is obtained. For the rigid elements, the results are presented in terms of bending moments and normal forces. The results show that when the frequency of the input motion is close to the minimum (central) frequency in the Rayleigh damping formulation, the overdamping amount is reduced, and the surface spectral acceleration of the analyzed pile and inclusion systems increases. Thus, the bending moments and normal forces throughout the piles and inclusions also increase.

• Journal of Advanced Marine Engineering and Technology
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• 제33권6호
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• pp.852-859
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• 2009

For the analysis of solids containing a number of microinclusions or microvoids, in which the mechanical effect of each inclusion or void, a numerical approach is need to be developed to understand the mechanical behavior of damaged solids containing these defects. In this study, the simulation method using the natural element method is proposed for the analysis of effective elastic moduli. The mechanical effect of each inclusion or void is considered by controlling the material constants for Gaussian points. The relationship between area fraction of microinclusions or microvoids and effective elastic moduli is studied to verify the validity of the proposed method. The obtained results are in good agreement with the theoretical results such as differential method, self-consistent method, Mori-Tanaka method, as well as the numerical results by rigid body spring model.

• 소성∙가공
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• 제9권5호
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• pp.533-538
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• 2000

This study has been carried out to develop a CRT die using hot forging. The conventional CRT die made by casting has defects such as void and inclusion. These defects of the cast die make micro-spots on the surface of the CRT which affect the quality of the final product. So, a hot forging process is developed to avoid these defects of CRT die by the model material test and the rigid-plastic FEM. Firstly, model material tests are carried out with plasticine billets in order to investigate the material flow pattern in the die cavity and to get the reasonable initial values for designing the preform in the FE simulation. And then a finite element analysis has been performed to Predict the preform and the forging load of a CRT die. We also suggest an integrated die-set which combines two die-sets into one die-set to save manufacturing time and cost in case of similar die-size.

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.769-775
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• 2005

An efficiency of Monte Carlo (MC) docking simulations was examined for the prediction of chiral discrimination by cyclodextrins. Docking simulations were performed with various computational parameters for the chiral discrimination of a series of 17 enantiomers by $\beta$-cyclodextrin ($\beta$-CD) or by 6-amino-6-deoxy-$\beta$-cyclodextrin (am-$\beta$-CD). A total of 30 sets of enantiomeric complexes were tested to find the optimal simulation parameters for accurate predictions. Rigid-body MC docking simulations gave more accurate predictions than flexible docking simulations. The accuracy was also affected by both the simulation temperature and the kind of force field. The prediction rate of chiral preference was improved by as much as 76.7% when rigid-body MC docking simulations were performed at low-temperatures (100 K) with a sugar22 parameter set in the CHARMM force field. Our approach for MC docking simulations suggested that the conformational rigidity of both the host and guest molecule, due to either the low-temperature or rigid-body docking condition, contributed greatly to the prediction of chiral discrimination.

• 한국지진공학회논문집
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• 제2권2호
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• pp.1-12
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• 1998

여섯 성분의 지진에 의한 지반속도를 받는 회전기계-기초시스템의 거동을 해석하기 위해 회전기계-기초시스템을 회전원판, 회전축, 윤활유막 베어링, 주각, 그리고 뼈대기초로 구성된 것으로 이상화한다. 이때 회전기계-기초의 동적거동을 나타내는 지배운동방정식은 Gyroscope 효과와 Coriolis 효과, 윤활유막의 동적특성 그리고 지반의 병진과 회전거동을 고려하여 얻는다. 지반의 회전거동, Gyroscope 효과, 그리고 Coriolis 효과들이 회전기계-기초시스템의 전체거동에 미치는 영향을 해석예젤르 통해 고찰한다. 해석결과 회전기계-기초시스템의 지진해석에 있어서 지반의 회전거동 성분과 Gyroscope 효과의 영향을 포함하여야함을 알 수 있다.