• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1871-1874
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• 2013

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2000년도 정기총회 및 봄 학술발표회
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• pp.63-64
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• 2000

공기중이나 UV 등의 광원에 비교적 안정적인 염료 Rhodamine B는 UV 조사아래 광촉매인 $TiO_2$의 첨가로 그 분해가 가능하였다. 유동층 반응기에 적합하도록 자체 제조된 광촉매 입자, Photomedia도 우수한 효율로 염료의 분해가 가능함을 보여주었다.

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2910-2916
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• 2012

Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.

• 대한화학회지
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• 제61권4호
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• pp.168-178
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• 2017

$La/TiO_2$ - graphene composites were synthesized in this study, and applied to the photocatalytic degradation of Rhodamine B (RhB) under UV-visible light irradiation. X-ray diffraction (XRD), surface analysis, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) analysis demonstrated that $La/TiO_2$ nanoparticles were well distributed on the surface of graphene, and formed the heterostructure of $La/TiO_2$-graphene. Compared to the pure $TiO_2$, $La/TiO_2$-graphene composites displayed much higher photocatalytic activities in RhB degradation under UV-visible light irradiation. The photocatalytic data of $La/TiO_2$-graphene composites exhibit extended light absorption in the visible light region, and possess better charge separation capability than that of pure $TiO_2$. The high photocatalytic activity was attributed to the composite's high adsorptivity, extended light absorption, and increased charge separation efficiency, due to the excellent electrical properties of graphene, and the large surface contact between graphene and $La/TiO_2$ nanoparticles.

• 분석과학
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• 제7권1호
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• pp.17-23
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• 1994

졸-겔법에 의해 dye host로 사용될 수 있는 무기/유기 복합체(ORMOSIL)를 제조하였으며, 이 복합체가 dye host로 적합한 조건을 갖췄음을 UV/VIS Spectrophotometer를 이용하여 90% 정도의 투광성을 얻음으로써 알 수 있었다. 이 투광성은 졸-겔 공정 중 촉매로 쓰이는 염산의 양이 적고 묵힘시간이 짧을수록 커짐을 알 수 있었다. 또한 이렇게 제조된 Host에 Rhodamine 6G Perchlorate를 도핑하여 유기염료의 형광 및 투광성을 측정한 결과 겔화온도가 증가될수록 형광 강도가 증가하며 투광성은 감소하는 것을 관찰할 수 있었다.

• Parasites, Hosts and Diseases
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• 제31권3호
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• pp.193-200
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• 1993

국내의 CUPtOSPOTidiUm 인체감염 실태를 조사하기 위하여 연세대학 세브란스 병원을 찾은 230명의 외래 환자 분변을 수거하였다. Acid-fast 염색, auramine-rhodamine 염색과 CWptosporidiwpowumoocyst에 특이적인 단클론 항체를 이용한 동정법을 이용하였다. 230명의 환자 중 48명(21%)이 AF 염색법에 의하여 50명(22%)이 AR 염색법에 의하여, 그리고 23명(10%)이 단클론 항체를 이용하는 형광현미경법으로 각각 Cryptosporidium에 감염된 것으로 조사되어 국내에서도 Cryptosporidium 인체 감염이 존재하고 있는 것으로 나타났다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.63-66
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• 2004

폐기물매립장에서의 침출수 유출을 확인하고 경로를 파악하기 위해 추적자시험이 실시되었다. 추적자는 요오드와 Rhodamine WT를 이용하였으며, 추적자는 T-2, 4, 5공에서 주입하였다. 관측지점으로는 매립장내 우수관 출구와 측면배수구에서 모니터링 하였으며, 또한 주입공 하부의 9개 지하수공에서 모니터링 하였다. T-4, T-2와 T-5 지하수공에서 요오드와 Rhodamine WT 용액을 주입한 추적자시험 결촤 매립장의 바닥 차수막이 파손되어 침출수가 우수관내로 유출되고 있음이 입증되었으며, 또한 매립장내의 투수성이 매우 높아 일반적인 자연상태에 비해 매립장에서 우수관내로의 침출수 유입이 매우 빠름을 알 수 있었다. T-4와 T-2 지하수공에서 실시된 추적자시험에서 매립장의 차수벽 하부에 위치한 B-5와 B-6공에서 다량의 추적자가 관측되어 하부차수벽을 통해 침출수가 유출되고 있음이 확인되었다. 본 현장에서 실시된 추적자시험을 통해 매립장에서의 침출수 유출은 매우 빠른 속도로 발생하고 있으며, 또한 주 유출경로로는 T-4와 T-5 지하수공 주변의 바닥차수막과 매립장의 하부차수벽을 통해 유출 되어지고 있음을 확인할 수 있었다.

• 한국환경과학회지
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• 제14권12호
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• pp.1203-1209
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• 2005

Basic dyes, Rhodamine 6G(R6G), Rhodamine B(RB), and Methylene Blue(MB), dissolved in water were used to investigate single-component adsorption affinity to the pearl layer fractionated according to the size. Unfractionated pearl layers were also used as adsorbents for the R6G and RB. The Langmuir and the Redlich-Peterson(RP) models were used to fit the adsorption data, and the goodness of fit was examined by using determination coefficient($R^2$) and standard deviation(SSE). The 3-parameter RP model was found to be better in describing the dye adsorption data than the 2 parameter Langmuir model, as can be expected from the number of parameters involved in the model. The adsorption affinity to the fractionated pearl layer was higher than that to the unfractionated layer The affinity order to the fractionated Conchiolin layer was found to be R6G > MB > RB. Furthermore, the dye adsorption capacity of the various types of pearl layer was found to be in the order, the fractionated pearl > powdered pearl > unfractionated pearl, exhibiting different adsorption isotherms according to the types of layer used in the study.

• 대한기계학회논문집B
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• 제24권10호
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• pp.1399-1408
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• 2000

A 2-dimensional temperature field measurement technique using PLIF (Planar Laser Induced Fluorescence) was developed and it was applied to an axisymmetric buoyant jet. Rhodamine B was used as a fluorescent dye. Laser light sheet illuminated a two-dimensional cross section of the jet. The intensity variations of LIF signal from Rhodamine B molecules scattered by the laser light were captured with an optical filter and a CCD camera. The spatial variations of temperature field of buoyant jet were derived using the calibration data between the LIF signal and real temperature. The measured results show that the turbulent jet is more efficient in mixing compared to the transition and laminar jet flows. As the initial flow condition varies from laminar to turbulent flow, the entrainment from ambient fluid increases and temperature decay along the jet center axis becomes larger. In addition to the mean temperature field, the spatial distributions of temperature fluctuations were measured by the PLIF technique and the result shows the shear layer development from the jet nozzle exit.

• 한국환경보건학회지
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• 제34권2호
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• pp.175-182
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• 2008

This study investigates the optimal conditions for electrogenerated hydrogen peroxide production and the application of the electro-Fenton process using DSA electrodes. The influences of parameters for the hydrogen peroxide generation such as electrode materials, electrolyte concentration, current, pH, air flow rate and electrode distance were investigated using a laboratory scale batch reactor. The relative performance for hydrogen peroxide generation of each of the six electrodes is : Ru-Sn-Ti > Ru-Sn-Sb > Ru > Ir > Pt > Sn-Sb. Optimum NaCl dosage, current and air flow rate were 2.0 g/l, 12.5 A and 2 l/min, respectively. When the pH is low, hydrogen peroxide concentration was high. Electrode distance dos not effect to a hydrogen peroxide generation. A complete color removal was obtained for RhB (200 mg/l) at the 8 min mark of the electro-Fenton process under optimum operation conditions of $Fe^{2+}$ 0.105 g/l and 5.0 A. The electro-Fenton process increased initial reaction and decreased final reaction time. However the effect was not high.