• 제목/요약/키워드: rheometry

검색결과 40건 처리시간 0.031초

밥의 텍스쳐와 쌀 아밀로오스의 분자량 분포에 관한 연구 (Texture of Cooked Rice and Molecular Weight Distribution of Rice Amylose)

  • 노은숙;안승요
    • 한국식품과학회지
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    • 제21권4호
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    • pp.486-491
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    • 1989
  • 단립종인 천마벼, 중립종인 용문벼, 장립종인 Mahatma등 3품종 설에 대한 취반미의 텍스쳐 특성과 아밀로오스의 분자량 분포를 rheometer와 겔 크로마토그래피 방법을 통하여 연구하였다. Mahana 품종 쌀로 만든 밥은 천마벼나 용문벼로 만든 밥보다 경도가 컸고 부착성이 낮았다. 가용성 아밀로오스는 경도와 정의 상관관계가 있었으나 총 아밀로오스 함량이나 불용성 아밀로오스 함량과는 뚜렷한 상관관계를 보이지 않았다. 분리한 아밀로오스의 ${\beta}-amylolysis$ limit는 $77.2{\sim}78.5%$였으며 iodine binding capacity는 $16.5{\sim}18.2%$였다. 겔 크로마토그래피에 의하여 분리한 아밀로오스의 분자량 분포는 천마벼, 용문벼, Mahatma의 순으로 컸다.

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광 투사법을 이용한 슬릿 점도계에서의 적혈구 응집성 및 점도 측정에 관한 연구 (Simultaneous measurements of red blood cell aggregation and blood viscosity in a slit rheometry with light transmission analysis)

  • 박명수;구윤희;신세현;서장수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1678-1681
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    • 2004
  • The light-transmission technique has been applied to a slit rheometer for measuring red blood cell aggregation as well as blood viscosity over a range of shear rates. For measurement of blood viscosity and aggregation, instantaneous pressure and transmit-light intensity are measured with time. Using a precision pressure measurement, one can determine the shear stress and shear rate. In addition, a transmitted light through a blood sample indicates degree of RBC aggregation. With abruptly flowing with high shear rate, RBCs rapidly disaggregate and the intensity of the transmitted light becomes low. When continuously flowing with decreasing shear rate, RBCs tend to re-aggregate and the corresponding transmit-intensity gradually increases with time. The light intensity as a degree of RBC aggregation is plotted against shear rate and compared with blood viscosity. The advantages of this design are dual measurement at a time, simplicity, i.e., ease of operation and no moving parts, low cost, short operating time, and the disposable kit which is contacted with blood sample.

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NaIO4를 사용한 도파민-수식 폴리아스팔트아미드의 산화적 젤화 (Oxidative Gelation of Dopamine-modified Polyaspartamides by NaIO4)

  • 전영실;;안중현;정동준;김지흥
    • 폴리머
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    • 제38권1호
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    • pp.108-112
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    • 2014
  • 도파민 및 에틸렌디아민의 폴리숙신이미드(polysuccinimide)와의 연속적인 개환 아미놀리시스 반응을 통해 카테콜 및 1차 아민기를 곁가지에 함유한 접착성 폴리아스팔트아미드를 합성하고, 산화제로서 $NaIO_4$를 사용한 상기 고분자 수용액의 산화적 젤화 반응을 관찰하였다. FTIR, UV-vis과 oscillatory rheometry를 이용하여 산화성 가교반응을 통한 젤 형성을 규명하고, 제조된 젤의 수팽윤도, 열중량분석(TGA) 및 SEM 모폴로지를 조사하였다.

Rheological properties of some thermotropic liquid crystalline polymers

  • Fan, Yurun;Dai, Shaocong;Tanner, Roger I.
    • Korea-Australia Rheology Journal
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    • 제15권3호
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    • pp.109-115
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    • 2003
  • Rheometry testing and the DSC measurement of five thermotropic liquid crystalline polymers (TLCP) have been carried out. The dynamic viscosities of the five TLCPs show a typical shear-thinning behaviour obeying the power-law with the power indices from 0.2 to 0.3. When these TLCPs are heated above the melting temperatures determined by the DSC measurements, the dynamic viscosities first rapidly decrease by 2~3 orders of magnitude then level off, finally increase gradually with the further increasing of temperature. The steady shearing exhibited the same behaviour as the dynamic shearing, but serious edge fracture of material slippage out of the plates occurred. The abnormal temperature dependence of the viscosities can be explained by the nematic-isotropic transition. By using the concept of activation energy, we propose a simple model which can fit the shear-thinning behaviour quite well and predict qualitatively correct temperature effects.

Effect of Cellulose Concentration of Cellulose/[AMIM]Cl Solution on the Liquid Crystalline Spinning

  • Kim, Su-Jin;Jang, Jin-Ho
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2012년도 제46차 학술발표회
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    • pp.51-51
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    • 2012
  • Cellulose is extremely difficult to dissolve cellulose in water and most common organic solvents due to their stiff molecular structure, close chain packing and intermolecular hydrogen bonds. Recently, cellulose solutions using ionic liquids (ILs) as a green solvent have been known to form cholesteric liquid crystalline phase at high cellulose concentration. In this study, the phase transition and rheological behaviors of concentrated cellulose/[AMIM]Cl solution were investigated using polarized optical microscopy and rheometry. Studies were conducted to characterize the influence of cellulose concentration on the phase transition of the cellulose solution and the mechanical properties of the regenerated fibers spun from the anisotropic cellulose/[AMIM]Cl solutions.

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Migration of Nanoclay in Immiscible Polymer Blends

  • Kim, Yong-Kyoung;Ahn, Kyung-Hyun;Lee, Seung-Jong;Hong, Joung-Sook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.366-366
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    • 2006
  • Five sandwiched multilayers consisting of PBT(Polybutyleneterephthalate), PS(Polystyrene) and clay were prepared to investigate the migration mechanism of clay in the polymer blend system. Rheometry (RMS800) was used to apply well-defined shear on the above multilayer samples in order to well understand dominant factors controlling the migration. Applied shear force was enough to move clay tactoids to the interface, if either long time or high shear was available, but it was not sufficient to separate into individual platelets of clay. The morphology evolution was subsequently studied in term of scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HR-TEM), respectively.

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Effect of added ionomer on morphology and properties of PP/clay nanocomposites

  • Liu, Hongzhi;Lim, Hyoung-Taek;Kim, Yong-Kyoung;Han, Nam-Kun;Ahn, Kyung-Hyun;Lee, Seoung-Jong
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.367-367
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    • 2006
  • With poly (ethylene-co-methacrylic acid) ionomer (i.e. Surlyn) as a compatibilizer, PP/organoclay (Cloisite(R)20A) nanocomposites were prepared via melt compounding in a co-rotating twin-screw extruder. For comparison, the widely used PP-g-MA was also used as a reference. The content of organoclay was fixed at 5phr based on the total weight of polymer resins. The structures of nanocomposites were characterized by XRD, rheometry in small amplitude oscillatory shear, SEM, and TEM, respectively. It was found that PP/Surlyn/OMMT nanocomposites displayed higher intercalation degree and better dispersion effect than the corresponding PP/PP-g-MA/OMMT counterpart. Additionally, their mechanical properties and wettability were measured.

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Effect of Metallocene-catalyzed Polyethylene on the Rheological and Mechanical Properties of Poly(phenylene sulfide)/Polyethylene Blends

  • Lee, Bo-Sun;Chun, Byoung-Chul;Chung, Yong-Chan
    • Fibers and Polymers
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    • 제5권2호
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    • pp.145-150
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    • 2004
  • Blends of poly(phenylene sulfide) (PPS) and polyethylene, either linear low density polyethylene (LLDPE) or metallocene-catalyzed polyethylene (MPE), that were prepared by melt blending, were investigated. From the rheological properties as determined by capillary rheometry, the melt viscosity of both PPS/LLDPE and PPS/MPE blends was low when PE was in dispersed phase, but high melt viscosity was observed for both blends with PPS in dispersed phase. Significant differences depending on the composition were found in the mechanical properties such as percent elongation at break and notched Izod impact strength. In addition, dispersed phase morphology of the blends was analyzed by a scanning electron microscope (SEM), together with brief discussion about the difference between them.