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http://dx.doi.org/10.7317/pk.2014.38.1.108

Oxidative Gelation of Dopamine-modified Polyaspartamides by NaIO4  

Jeon, Young Sil (School of Chemical Engineering, Sungkyunkwan University)
Bui, Quang Tri (School of Chemical Engineering, Sungkyunkwan University)
An, Jung Hyun (School of Chemical Engineering, Sungkyunkwan University)
Chung, Dong June (Department of Polymer Science & Engineering, Sungkyunkwan University)
Kim, Ji-Heung (School of Chemical Engineering, Sungkyunkwan University)
Publication Information
Polymer(Korea) / v.38, no.1, 2014 , pp. 108-112 More about this Journal
Abstract
Novel adhesive polyaspartamides containing catechol and primary amine pendent groups were synthesized through successive ring-opening aminolysis reactions of dopamine (DOP) and ethylenediamine (EDA) with polysuccinimide (PSI). The oxidative gelation of aqueous dopamine-modified polyaspartamide was observed by adding $NaIO_4$ as the oxidizing reagent. FTIR, UV-vis and oscillatory rheometry was used to elucidate the oxidative cross-linking toward gel formation. The prepared gel was characterized by the swelling degree, thermogravimetric analysis (TGA), and by scanning electronic microscopy (SEM).
Keywords
dopamine-modified; polyaspartamide; oxidative gelation; adhesive;
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1 H. S. Lee, S. M. Dellatore, W. M. Miller, and P. B. Messersmith, Science, 318, 426 (2007).   DOI   ScienceOn
2 J. H. Waite and X. X. Qin, Biochemistry, 40, 2887 (2001).   DOI   ScienceOn
3 M. Yu and T. J. Deming, Macromolecules, 31, 4739 (1998).   DOI   ScienceOn
4 F. Xiaowu, L. Lijun, L. D. Jeffrey, and P. B. Messersmith, J. Am. Chem. Soc., 127, 15843 (2005).   DOI   ScienceOn
5 B. P. Lee, L. D. Jeffrey, and P. B. Messersmith, Biomacromolecules, 3, 1038 (2002).   DOI   ScienceOn
6 H. Shao, K. N. Bachus, and R. J. Stewart, Macromol. Biosci., 9, 464 (2009).   DOI   ScienceOn
7 C. E. Brubaker, H. Kissler, L. J. Wang, D. B. Kaufman, and P. B. Messersmith, Biomaterials, 31, 420 (2010).   DOI   ScienceOn
8 H. S. Lee, Y. H. Lee, A. R. Statz, J. S. Rho, T. G. Park, and P. B. Messersmith, Adv. Mater., 20, 1619 (2008).   DOI   ScienceOn
9 K. Yamada, T. Chen, G. Kumar, O. Vesnovsky, L. D. T. Topoleski, and G. F. Payne, Biomacromolecules, 1, 252 (2000).   DOI   ScienceOn
10 S. H. Ku, J. K. Ryu, S. K. Hong, H. S. Lee, and C. B. Park, Biomaterials, 31, 2535 (2010).   DOI   ScienceOn
11 E. P. Holowka and T. J. Deming, Macromol. Biosci., 10, 496 (2010).
12 J. R. Moon and J. H. Kim, Polym. Int., 59, 630 (2010).
13 J. R. Moon, M. W. Kim, D. J. Kim, J. H. Jeong, and J. H. Kim, Colloid Polym. Sci., 289, 63 (2010).
14 J. R. Moon and J. H. Kim, Macromol. Res., 16, 489 (2008).   DOI
15 J. R. Moon, Y. H. Park, and J. H. Kim, J. Appl. Polym. Sci., 111, 998 (2009).
16 J. H. Park, J. R. Moon, K. H. Hong, and J. H. Kim, J. Polym. Res., 18, 273 (2011).   DOI
17 J. H. Waite and M. L. Tanzer, Science, 212, 1038 (1981).   DOI
18 S. I. Kim, C. M. Son, Y. S. Jeon, and J. H. Kim, Bull. Korean Chem. Soc., 30, 3025 (2009).   DOI
19 J. H. An, N. T. Huynh, Y. S. Jeon, and J. H. Kim, Polym. Int., 60, 1581 (2011).   DOI   ScienceOn
20 J. H. Waite, Integr. Comp. Biol., 42, 1172 (2002).   DOI   ScienceOn
21 A. R. Statz, R. J. Meagher, A. E. Barron, and P. B. Messersmith, J. Am. Chem. Soc., 125, 4253 (2003).   DOI   ScienceOn