• Korea-Australia Rheology Journal
• /
• v.19 no.2
• /
• pp.81-88
• /
• 2007

Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.

• Korea-Australia Rheology Journal
• /
• v.12 no.1
• /
• pp.77-81
• /
• 2000

Rheological behavior of thermoset/thermoplastic blends of epoxy/polyethersulphone (PES) was monitored during curing of the epoxy resin. During the isothermal curing of the mixture, a fluctuation in viscosity just before the abrupt viscosity increase was observed. This fluctuation is found to be due to the phase separation of PES from the matrix epoxy resin during the curing. The experimentally observed viscosity fluctuation is simulated with a simple two phase suspension model in terms of the increase in domain size. The viscosity profiles obtained experimentally at different isothermal curing temperatures are in good agreement with the predictions from the simple model taking into account the viscosity change due to the growth of PES domain and the network formation of the epoxy matrix.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.39 no.3
• /
• pp.41-51
• /
• 2007

In order to elucidate the effects of types and mixing ratio of GCC and clay, coating color concentration, and types of rheology modifiers on high solid coating, various coating colors were prepared, high shear viscosity was measured and then rheology of the coating colors was analyzed. Coating color concentration was able to be increased from 67% to 69% and from 68% to 71% with a higher GCC ratio and with the rheology modifier instead of the synthetic thickener, keeping similar or improved coating color rheology and coated paper quality. The rheological properties of high solid coating color were superior with smaller average particle sizes of clay and latex, wider size distribution of GCC and higher added amount of latex.

• Korea-Australia Rheology Journal
• /
• v.11 no.4
• /
• pp.305-311
• /
• 1999

The shear behavior of polymers obtained by means of devices such as capillary and cone-and-plate rheo-meters is commonly used to assess their processing performance and as a characterization tool. However, the number of instances when two polymers have the same shear properties but perform differently during certain types of processing operations (e.g. film blowing and sheet extrusion) indicate that shear properties alone may not be sufficient to characterize polymeric fluids. We begin by defining the kinematics of shear-free or extensional flow and the associated material functions. The extensional and shear behavior of three different types of polyethylene (PE) are then compared to illustrate the points that one cannot ascertain the extensional properties of polymer melts from their shear properties and, furthermore, there may not be a simple relation between properties obtained from one type of extensional flow and those of another type. The kinematics of most processing flows are extensional rather than shear in nature, and , hence, the performance of polymers during processes such as fiber spinning, film casting, film blowing, thermoforming, blow molding, and even extrusion is more readily accounted for through extensional viscosity measurements. Methods for carrying out extensional flow measurements are then reviewed including approximate methods. To illustrate the sensitivity of extensional viscosity measurements to subtle changes in the molecular architecture of PEs, results are presented for samples with a narrow molecular weight distribution but with varying numbers of long chain branches. Finally, constitutive equations which allow one to separate shear and extensional flow behavior are discussed as any attempts to simulate the subtle processing differences between two polymers will require constitutive equations of this nature.

• Transactions of Materials Processing
• /
• v.14 no.4 s.76
• /
• pp.351-359
• /
• 2005

The semi-solid processing is now becoming of great interest for the production of various parts by pressure die casting. Also, the rheo-casting has been substituted for thixo-casting, because the rheo-casting can control the solid particles to globular and non-dendritic solid phase. In the rheo-casting process, the important thing is to control the solid particles behavior in semi-solid materials. So in this paper, to control solid particles behavior in semi-solid materials, we experimented about the die filling tests during the semi-solid die casting in 0.3, 0.4, 0.5 and 0, 6 solid fraction. The die filling in semi-solid die casting were simulated by MAGMA soft/thixo module. By the die filling tests and computer simulation, the effect of solid particles behavior in rheology flow had been investigated.

• Korea-Australia Rheology Journal
• /
• v.21 no.3
• /
• pp.185-191
• /
• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2004.10a
• /
• pp.774-777
• /
• 2004

A rheology casting technology has some advantages compared with conventional forming processes such as die casting, squeeze casting and hot/cold forming. The liquid segregation is important on mechanical properties of materials using rheology casting. In this study, so, molecular dynamics simulations were performed for the control of liquid segregation. Because the dynamics of fluid flow about nano-scaled materials is completely different from continuum, molecular dynamics simulations were used. The behavior of particles was far from the truth according to boundary conditions in simple flow. But various movement of particles appear at two or more molecular simulations.

• Korea-Australia Rheology Journal
• /
• v.13 no.4
• /
• pp.179-187
• /
• 2001

As part of continuing efforts to investigate nonlinear dynamics and stability of film casting process, our earlier results obtained by Lee et al. (2001b) have been extended in the present study to cover the film casting of both extension thickening and extension thinning fluids. The same instability mechanism and draw resonance criterion previously derived have been found valid here, and a rather complex dynamic behavior of film width in contrast to that of film thickness has also been confirmed. The effect of fluid viscoelasticity on draw resonance, however, exhibits opposite results depending on whether the fluid is extension thickening or thinning, i.e., it stabilizes film casting in the former while destabilizing in the latter. The encapsulation extrusion method which recently has been successfully employed to stabilize industrially important paper coating process, has been theoretically explained in the present study as to why such stabilization is possible.

• Proceedings of the SCSK Conference
• /
• 2003.09b
• /
• pp.286-293
• /
• 2003

In cosmetic formulations, texture plays a key role in ingredient choice and formulation optimization. But texture parameters are often measured by sensorial analysis in the last stages of formulation development. Rheology or texture analysis, used separately, has the benefit of characterizing the behavior of raw materials (e.g. polymers) and controlling and predicting the stability of formulations. SEPPIC has developed rheology and texture analysis protocols to obtain a better understanding of the influence of raw materials on the cosmetic texture of formulations. When used in combination, these two methodologies are complementary and provide useful data regarding the impact of raw material choice on all the development steps: manufacturing procedure, formulation stability, skin feeling.

• Korea-Australia Rheology Journal
• /
• v.14 no.2
• /
• pp.49-55
• /
• 2002

To understand the large amplitude oscillatory shear (LAOS) behavior of complex fluids, we have investigated the flow behavior of a network model in the LAOS environment. We applied the LAOS flow to the model proposed by Vaccaro and Marrucci (2000), which was originally developed to describe the system of associating telechelic polymers. The model was found to predict at least three different types of LAOS behavior; strain thinning (G' and G" decreasing), strong strain overshoot (G' and G" increasing followed by decreasing), and weak strain overshoot (G' decreasing, G" increasing followed by decreasing). The overshoot behavior in the strain sweep test, which il often observed in some complex fluid systems with little explanation, could be explained in terms of the model parameters, or in terms of the overall balance between the creation and loss rates of the network junctions, which are continually created and destroyed due to thermal and flow energy. This model does not predict strain hardening behavior because of the finitely extensible nonlinear elastic (FENE) type nonlinear effect of loss rate. However, the model predicts the LAOS behavior of most of the complex fluids observed in the experiments.he experiments.