• Title/Summary/Keyword: rheological analysis

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Reinforced Polymer/Clay Nanocomposite Foams with Open Cell Prepared via High Internal Phase Emulsion Polymerization (고내상 에멀션 중합에 의해 제조된 열린 기공을 갖는 고장도 고분자/점토 나노복합 발포체)

  • Song, In-Hee;Kim, Byung-Chul;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.183-188
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    • 2008
  • Reinforced open cell micro structured foams were prepared by the polymerization of high internal phase emulsions incorporating inorganic thickeners. Organoclays were used as oil phase thickener, and sodium montmorillonite was used as aqueous phase thickener. Rheological properties of emulsions increased as oil phase thickener concentration and agitation speed increased, due to the reduced drop size reflecting both competition between continuous and dispersed phase viscosities and increase of shear force. Drop size variation with thickener concentration could be explained by a dimensional analysis between capillary number and viscosity ratio. Upon the foams polymerized by the emulsions, compression properties, such as crush strength and Young's modulus were measured and compared. Among the microcellular foams, the foam incorporated with an organoclay having reactive group showed outstanding properties. It is speculated that the exfoliated silicate layers inside polystyrene matrix, resulting in nanocomposite foam, are the main reason why this foam has enhanced properties.

A Study on Vibration Control Performance of Macpherson Type Semi-Active Suspension System (맥퍼슨 타입 반 능동 현가장치의 진동제어 성능 고찰)

  • Dutta, Saikat;Han, Chulhee;Lee, TaeHoon;Choi, Seung-Bok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.2
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    • pp.157-164
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    • 2016
  • The paper studies a comparison analysis of semi-active control strategies for a Macpherson strut type suspension system consisting of MR(magneto-rheological) damper. As a first step, in order to formulate governing, a dynamic full model of a Macpherson strut is developed considering the kinematics. The nonlinear equation of motion of the strut is then linearized around the equilibrium point. A new adaptive moving sliding model controller is developed for fast response of the system. A newly proposed adaptive moving sliding mode control strategy is then compared with conventional sliding mode controller and skyhook controller. The comparison is made for two different types of road inputs; bump and random road profiles showing superior vibration control performance in time and frequency domains.

Application Evaluation of Asphalt mixtures using SDAR (Solvent DeAsphaltene Residue) (SDAR을 이용한 아스팔트 혼합물의 적용성 평가)

  • Yang, Sung Lin;Im, Jeong Hyuk;Hwang, Sung Do;Baek, Cheolmin
    • International Journal of Highway Engineering
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    • v.17 no.4
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    • pp.53-61
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    • 2015
  • PURPOSES : The objective of this study is to evaluate the SDAR (solvent deasphaltene residue), which is obtained from the solvent deasphalting (SDA) process, as a pavement material. METHODS : The physical properties of the SDAR were evaluated based on its chemical composition, and asphalt mixtures with the SDAR were fabricated and used for the evaluation of mechanical properties. Firstly, the chemical composition of SARA (saturate, aromatic, resin and asphaltene) was analyzed using the TLC-FID (thin-layer chromatography-flame ionization detector). Moreover, the basic material properties of the asphalt binder with the SDAR were evaluated by the penetration test, softening point test, ductility test, and PG (performance grade) grade test. The rheological properties of the asphalt binder with the SDAR were evaluated by the dynamic shear modulus ($G^*$) obtained using the time-temperature superposition (TTS) principle. Secondly, the mechanical properties of the asphalt mixtures with the SDAR were evaluated. The compactibility was evaluated using the gyratory compacter. Moreover, the tensile strength ratio (TSR) was used for evaluating the moisture susceptibility of the asphalt mixtures (i.e., susceptibility to pothole damage). The dynamic modulus $E^*$, which is a fundamental property of the asphalt mixture, obtained at different temperatures and loading cycles, was used to evaluate the mechanical properties of the asphalt mixtures. RESULTS AND CONCLUSION : The SDAR shows stiffer and more brittle behavior than the conventional asphalt binder. As the application of the SDAR directly in the field may cause early failures, such as cracks on pavements, it should be applied with modifiers that can favorably modify the brittleness property of the SDAR. Therefore, if appropriate additives are applied on the SDAR, it can be used as a pavement material because of its low cost and strong resistance to rutting.

Synthesis and Characterization of High Impact Polystyrene/Organically Modified Layered Silicate Nanocomposites (내충격성 폴리스티렌과 유기화 층상 실리케이트 나노복합체의 합성 및 특성)

  • 김관영;임효진;박상민;이성재
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.377-384
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    • 2003
  • High impact polystyrene/organically modified layered silicate (HIPS/OLS) nanocomposites by in situ polymerization were synthesized to investigate the effect of clay on the particle size and properties of rubber. In the OLS, the montmorillonite having benzyl group showed best dispersion in polystyrene phase. With the addition of clay, the intercalated peak from XRB was confirmed, but the peak gradually shifted to lower angle as rubber concentration increased. Thus, it is speculated that the organoclay disperses better in rubber phase than in polystyrene phase. The average rubber particle size increased and the particle size distribution widened as the amount of clay increased, which may be caused by the increase of the viscosity ratio of rubber to polystyrene phases and the unstable dispersion. The materials having clay showed improved thermal properties from thermogravimetric analysis. Rheological properties such as complex viscosity and storage modulus increased as the amount of clay increased.

Studies on Cholesterol Free Mozzarella Cheese Manufacture (Cholesterol Free Mozzarella Cheese 제조에 관한 연구)

  • 전정기;김병용
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.3
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    • pp.587-592
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    • 2004
  • This research was aimed to manufacture the cholesterol free Mozzarella cheese with corn oil that contains high unsaturated fatty acid helping the reduction of serum cholesterol. Cheese stored at 1$0^{\circ}C$ was evaluated with general analysis, volatile free fatty acid, cholesterol, meltability, stretchability, color, rheological properties, and sensory evaluation. Moisture contents decreased during cheese storage period, whereas protein contents and pH value increased significantly (P < 0.05), but fat contents did not show any significant change. Linoleic acid was tile main volatile free fatty acid in a fat of cheese, and cholesterol contents were measured 4.34$\pm$ 0.04 mg/100 g in cheese. The meltability of cheese gradually increased during ripening, while the stretchability decreased. The color of cheese showed translucent yellow. Hardness, springiness, and cohesiveness increased significantly up to 21 days of storage. Compared to control cheese made by conventional way, QDA scores of shiny, oiling off, and melting of cholesterol free cheese were significantly different. These results suggested that health-oriented cholesterol free Mozzarella cheese would be made by addition of the corn oil.

A Study of Performance Evaluation of Warm Asphalt Binder Properties using LEADCAP(R) additive (중온화 첨가제(LEADCAP(R))를 사용한 중온 아스팔트 바인더의 특성 평가)

  • Lee, Jae-Jun;Yang, Sung-Lin;Kwon, Soo-Ahn;Hwang, Sung-Do
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.1-8
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    • 2011
  • The objective of this paper is to evaluate the performance of low $CO_2$ asphalt binder properties using LEADCAP$^{(R)}$(Low Energy and Carbon Asphalt Pavement) additive as function of various aging methods such as RTFO(Rolling thin film oven), Ultraviolet(UV) lay. In order to simulate the short-term aging of asphalt binder that occurs during the hot-mixing asphalt process, the Rolling Thin Film Oven(RTFO) was used. Asphalt binder using LEADCAP$^{(R)}$ is prepared by addition of a photoinitiator activated by ultraviolet lay. The mechanical and rheological properties of the asphalt binder were estimated using UTM(Universal Testing Machine) and DSR(Dynamic Shear Rheometer). The test results showed that the asphalt binder using LEADCAP$^{(R)}$ additive was improved the rutting resistance at testing temperature ($70^{\circ}C$) and increased tensile strength at low temperature. Also, Thermal analysis shows that the Melting Point(Tm) of asphalt binder using LEADCAP$^{(R)}$ additive was constant although the asphalt binder was aged by Ultraviolet.

Performance Evaluation of Vibration Control of Adjacent Buildings According to Installation Location of MR damper (인접건축물의 진동제어를 위한 MR감쇠기의 위치 선정에 관한 연구)

  • Kim, Gee-Cheol;Kang, Joo-Won
    • Journal of Korean Society of Steel Construction
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    • v.24 no.1
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    • pp.91-99
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    • 2012
  • In recently, the vibration control of adjacent buildings have been studied and magneto-rheological(MR) fluid dampers have been applied to seismic response control. MR dampers can be controlled with small power supplies and the dynamic range of this damping force is quite large. This MR damper is one of semi-active dampers as a new class of smart dampers. In this study, vibration control effect according to the installation location of the MR damper connected adjacent buildings has been investigated. Adjacent building structures with different natural frequencies were used as example structures. Groundhook control model is applied to determinate control force of MR damper. In this numerical analysis, it has been shown that displacement responses can be effectively controlled as adjacent buildings are connected at roof floors by MR damper. And acceleration responses can be effectively reduced when two buildings are connected at the mid-stories of adjacent buildings by MR damper. Therefore, the installation floor of the MR damper should be selected with seismic response control target.

Study on the Compact MR fluid Brake for the Training and Sporting Equipment for Leg Rehabilitation (하지 재활운동치료 기구에 적용하기 위한 소형 MR 유체 브레이크에 관한 연구)

  • Park, Woo-Cheul;Lee, Hyun-Chang;Kim, Il-Gyoum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.2878-2885
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    • 2012
  • In this study, the training and sporting equipment for leg rehabilitation featuring the MR fluids is proposed. The compact MR fluid brake is designed and manufactured to apply to the rehabilitation training and sporting mechanism. The resistance characteristic of the MR fluid brake is controllable by varying the magnetic field around the fluid. Under consideration of spatial limitation, design parameters which are related with the magnetic strength are determined to maximize to a torque using finite element method. The FE analysis is performed using a commercial code, ANSYS Workbench. The proposed brake device is manufactured, and its field-dependant torque is experimentally evaluated. When the electric current is supplied, the torque of the MR fluid brake is increased and the response is very fast. Depending on the strength of the current supply, torques of the MR fluid brake also increase similar to Bingham property of MR fluid.

Identification of Cross-WLF Viscosity Model Parameters Using Optimization Technique (최적화기법을 이용한 Cross-WLF점도 모델 계수 추정)

  • Kim, Sun-Yong;Park, Si-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.623-632
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    • 2018
  • Predicting the behavior of rheological polymers is highly shear rate- and temperature-dependent. The Cross-WLF viscosity model has become a powerful solution that describes the shear rate- and temperature-dependent characteristics. To estimate the behavior of polymers in computational simulations, the coefficients of the Cross-WLF model should be well identified. An identification technique was proposed to determine the Cross-WLF viscosity model coefficient. The assumption is that the Cross-WLF viscosity model well describes the real characteristics of polymers when the calculated viscosity with the parameters is identical to the reference data. In this study, Auto-desk Moldflow data were used as a reference. The numerical examples showed that the proposed method accurately identifies the Cross-WLF viscosity model coefficients.

A study on properties of ultra high strength concrete of above 100MPa - fluidity and rheology properties (100MPa급 이상의 초고강도 콘크리트의 특성에 관한 연구 - 유동성 및 rheology 특성)

  • Seo, Il;Lee, Jin-Woo;Park, Hee-Gon;Bae, Yeon-Ki;Cho, Sung-Hyun;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.317-320
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    • 2008
  • In recent year, the ultra high strength concrete has highly increased and been used in many parts of the world. However, the viscosity of the ultra high strength concrete is high because of a low water to binder ratio (w/b). So that in this pater, the shear stress and the shear strain rate are directly measured by the viscometer in order to estimate the rheological properties of the ultra high strength concrete and a linear regression analysis was carried out to determine the plastic viscosity and the yield stress as slope. According to the test results, the yield stress and plastic viscosity are correlated to slump-flow, V-funnel flow time, O-lot flow time

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