• 공업화학
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• 제9권5호
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• pp.786-790
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• 1998

리튬이온이차전지에 사용되는 탄소부극의 성능을 향상시키기 위하여 새로운 탄소부극으로서 K-GIC를 합성하여 전기화학적 특성을 조사하였다. K의 삽입량은 KCl 수용액의 농도가 $2>3>1mole/{\ell}$의 순으로 증가하였으며 $1mole/{\ell}$의 KCl 수용액으로 처리하였을 때 K와 C의 mole 비는 156~388 carbon/potassium이었다. K-GIC의 합성조건을 $1mole/{\ell}$ KCl 수용액으로 $700^{\circ}C$에서 1시간으로 처리하였을 때 가장 우수한 리튬의 삽입과 탈삽입 거동을 나타냈으며 가역성 또한 우수하였다.

• Bulletin of the Korean Chemical Society
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• 제20권1호
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• pp.35-41
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• 1999

Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.

• Bulletin of the Korean Chemical Society
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• 제20권5호
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• pp.508-516
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• 1999

Polycrystalline powder of LixNi0.85Co0.15O2 was synthesized by pyrolyzing a powder precursor obtained by the PVA-precursor method. Coin cells of lithium-ion rechargeable battery were assembled, whose the cathodes were fabricated from the crystalline powders of LixNi0.85Co0.15O2 synthesized by the method. The effect of synthetic variation on the property of the cell was tested by carrying out 100 consecutive cycles of charge-dis-charge on the cells. The property of the cell was largely influenced by the pyrolysis conditions applied for the synthesis of the LixNi0.85Co0.15O2. Depending on whether the pyrolysis was carried out in standing air or in the flow of dry air, the discharge capacity and cycle-reversibility of the cell varied in large extent. When the powder precursor was pyrolyzed in standing air, a minor phase of lithium carbonate was remained in the LixNi0.85Co0.15O2. The carbon containing powder precursor had to be pyrolyzed in the flow of dry air to eliminate the minor phase. In the flow of dry air, the lithium carbonate in the precursor was eliminated over 500-700。C without any prominent heat event. By controlling the flow of air over the precursor during its pyrolysis, particle size could also be altered. The effect of flowing dry air, during first step pyrolysis or during second step heat treatment, on the property of the cell was discussed.

• 약학회지
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• 제21권3호
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• pp.167-171
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• 1977

A new assay method for delta-l-dehydrogenated-3-ketoco-rticosteroid in the presence of proteinous material or whole-cell-enzyme and 3-ketocorticosteroid has been developed. This method makes use of the linear relationship between the ratio of absorbances at 265 nm and at 242 nm and the fractional concentration of delta-1-3-ketosteroid. Theoretical values were calculated based on the absorbances of proteinous material at fixed concentrations of the 3-ketosteroid and delta-1-dehydrogenated-3-ketosteroid. The values obtained experimentally showed good agreement with the values obtained experimentally showed good agreement with the values theoretically predicted. The new assay method developed for the steroid mixtiure containing proteinous material is of some practical importance. The use of such assay method enables one to determine the enzyme activity and the rate of enzyme reaction or conversion rather quickly, easily and accurately. By the use of this assay method, the reaction kinetics of whole-cell-enzyme has also been studied. It was found that it followed the simple Michaelis-Menten type enzyme kinetics. Also the reversibility of this reaction with actively metabolizing cell was examined. It was found that delta-l-dehydrogenated-3-ketosteroid could not be hydrogenated reversibly to 3-ketosteroid by this enzyme system.

• 정보보호학회논문지
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• 제18권3호
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• pp.51-59
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• 2008

생체 정보 인식은 사용자의 인증을 위한 수단으로써 많은 연구가 진행 되어 오고 있다. 그 중 얼굴 인식 분야에서 특성벡터를 이용한 사용자의 얼굴 인식 기법이 존재한다. 이 기법은 전체 얼굴 데이터 집합에서 벡터 공간을 만들어 내고 생체정보 템플릿을 사상시켜 추상화된 데이터를 생성하는 기법이다. 그러나 생체 정보의 보안성을 일컫는 개념인 취소 가능한 특성(Cancelable Feature)을 기대 할 수 는 없다. 이 논문에서는 특성 벡터를 이용한 얼굴 인증 시스템에서 변환된 생체정보 데이터의 복원에 대한 보안 문제를 지적하고, 예상 가능한 공격 시나리오를 실험을 통해 보인다.

• Journal of Microbiology and Biotechnology
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• 제31권2호
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• pp.233-239
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• 2021

Cyanobacteriochromes (CBCRs) are phytochrome-related photoreceptor proteins in cyanobacteria and cover a wide spectral range from ultraviolet to far-red. A single GAF domain that they contain can bind bilin(s) autocatalytically via heterologous recombination and then fluoresce, with potential applications as biomarkers and biosensors. Here, we report that a novel red/green CBCR GAF domain, SPI1085g2 from Spirulina subsalsa, covalently binds both phycocyanobilin (PCB) and phycoerythrobilin (PEB). The PCB-binding GAF domain exhibited canonical red/green photoconversion with weak fluorescence emission. However, the PEB-binding GAF domain, SPI1085g2-PEB, exhibited an intense orange fluorescence (λabs.max = 520 nm, λfluor.max = 555 nm), with a fluorescence quantum yield close to 1.0. The fluorescence of SPI1085g2-PEB was selectively and instantaneously quenched by copper ions in a concentration-dependent manner and exhibited reversibility upon treatment with the metal chelator EDTA. This study identified a novel PEB-binding cyanobacteriochrome-based fluorescent protein with the highest quantum yield reported to date and suggests its potential as a biosensor for the rapid detection of copper ions.

• Journal of the Korean Wood Science and Technology
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• 제31권6호
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• pp.1-7
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• 2003

The phase transformation from cellulose I into cellulose II in woods by way of Na-cellulose I was examined by x-ray diffraction analysis.The formation of Na-cellulose I in woods increased with the increase of treating time in alkali solution. When compression wood was treated with 20% NaOH solution at room temperature for 1 day, the x-ray diagram showed only Na-cellulose I. On the other hand, the x-ray diagram of tension wood showed a mixture of cellulose I and Na-cellulose I. Cellulose I of tension wood could not be transformed completely into Na-cellulose I even after 10-day treatment, but was transformed into Na-cellulose I after 30-day treatment. Na-cellulose I of compression and tension woods was converted to the cellulose I pattern and the mixture of cellulose I and cellulose II, respectively, after washing with water and drying at 20℃. Cellulose I regenerated from Na-cellulose I in wood could not be converted to cellulose II by delignification. Thus, it revealed that the delignification of the alkali-treated wood did not affect their cellulose structures. From the results, therefore, it can be concluded that lignin in woods prevents the formation of the stable Na-cellulose I and the conversion from cellulose I to cellulose II. This means that the conversion of chain polarity of wood cellulose hardly occurs during mercerization because cellulose microfibrils are fixed by lignin which not to be intermingled.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제16권12호
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• pp.4024-4041
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• 2022

Robust reversible watermarking has attracted widespread attention in the field of information hiding in recent years. It should not only have robustness against attacks in transmission but also meet the reversibility of distortion-free transmission. According to our best knowledge, the most recent robust reversible watermarking methods adopt a single image as the carrier, which might lead to low efficiency in terms of carrier utilization. To address the issue, a novel dual-image robust reversible watermarking framework is proposed in this paper to effectively utilize the correlation between both carriers (namely dual images) and thus improve the efficiency of carrier utilization. In the dual-image robust reversible watermarking framework, a two-layer robust watermarking mechanism is designed to further improve the algorithm performances, i.e., embedding capacity and robustness. In addition, an optimization model is built to determine the parameters. Finally, the proposed framework is applied in different domains (namely domain-independent), i.e., Slantlet Transform and Singular Value Decomposition domain, and Zernike moments, respectively to demonstrate its effectiveness and generality. Experimental results demonstrate the superiority of the proposed dual-image robust reversible watermarking framework.

• 한국초전도ㆍ저온공학회논문지
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• 제11권4호
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• pp.12-15
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• 2009

The $I_c$ degradation behavior of critical current in differently processed YBCO and SmBCO CC tapes with IBAD template has been investigated. It has been known that the residual strain in the CC tape will influence the shape of the $I_c$-strain window; $I_c$ may show a peak value if there exist a residual strain induced in the tape during manufacturing. The difference of residual strain may be resulted from the adopted different deposition techniques. In this study, bending test of CC tapes has been done using the Goldacker bending test rig which can produce both compressive and tensile bending strain continuously or alternately to the sample. For SmBCO CC tapes, in continuous compressive bending test, $I_c$ showed a minimal increase and did not degrade up to the largest strain that can be applied using the bending rig equivalent to 1.15% based on the sample thickness. However, in the case of alternate application of compressive and tensile bending strain, $I_c$ showed a larger degradation and a lower reversible limit when compared with the case of continuous application of the bending strain. When $I_c$ started to degrade significantly at the tension side, the reversibility ended, also at the compression side which is resulted from the permanent deformation like delamination or cracks that was induced due to tensile bending strain.

• 한국초전도ㆍ저온공학회논문지
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• 제9권2호
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• pp.11-14
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• 2007

The critical current, $I_c$, degradation behaviors with bending strain were investigated in a commercially available YBCO coated conductor tape. In particular, the strain reversibility of $I_c$ and the influence of repeated bending on $I_c$ have been studied. Also, repeated bending at 77 K was done in order to understand the Ie behavior under cyclic bending strains. A reversible behavior of $I_c$ has been found up to a high bending strain of 1.60% for the RABiTS/MOD processed CC sample with copper reinforcement. Under repeated bending, the Ie showed a 95% $I_c$ retention up to 100 cycles for bending strains of 1.0% or less. The n-value behavior showed a good agreement with the $I_c$ degradation behavior, representing that any cracking did not occur on the YBCO film resulting from the reinforcement provided by the copper stabilizers.