• 영어어문교육
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• 제10권2호
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• pp.89-111
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• 2004

The purpose of this article is to study the effect of finger play teaching method on the reproduction of children's English words. The hypotheses are as follows: 1) there will be the difference of the reproduction of children's English words between the experimental group(that is taught by finger play teaching method) and the controlled group (that is taught by only oral teaching method). 2) there will be the difference of children's retention capacity of reproducing English words between the experimental group and the controlled group, The researcher made the time series data The measure tool was the check list for reproduction test of children's English words that was made by Run-Soon Oh and J. Eden(2004). The researcher analyzed the data using the Repeated Measures ANOVA and the Analysis of Covariance. The findings of research are as follows: 1) the more the frequency of teaching increases, the more there are the difference of reproducing English words according to frequencies and groups. The reproduction capacity of the experimental group is better than that of the controlled group. A degree of statistical significance is p<.001. 2) The difference of retention capacity of reproducing English words between the experimental group and the controlled group is a statistical significant, p<.05. The experimental group is better than the controlled group.

• Water Engineering Research
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• 제3권1호
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• pp.31-44
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• 2002

The effect of diurnal cycle, intermittent visit of observation satellite, sensor installation, partial coverage of remote sensing, heterogeneity of soil properties and precipitation to the soil moisture estimation error were analyzed to present the global sampling strategy of soil moisture. Three models, the theoretical soil moisture model, WGR model proposed Waymire of at. (1984) to generate rainfall, and Turning Band Method to generate two dimensional soil porosity, active soil depth and loss coefficient field were used to construct sufficient two-dimensional soil moisture data based on different scenarios. The sampling error is dominated by sampling interval and design scheme. The effect of heterogeneity of soil properties and rainfall to sampling error is smaller than that of temporal gap and spatial gap. Selecting a small sampling interval can dramatically reduce the sampling error generated by other factors such as heterogeneity of rainfall, soil properties, topography, and climatic conditions. If the annual mean of coverage portion is about 90%, the effect of partial coverage to sampling error can be disregarded. The water retention capacity of fields is very important in the sampling error. The smaller the water retention capacity of the field (small soil porosity and thin active soil depth), the greater the sampling error. These results indicate that the sampling error is very sensitive to water retention capacity. Block random installation gets more accurate data than random installation of soil moisture gages. The Walnut Gulch soil moisture data show that the diurnal variation of soil moisture causes sampling error between 1 and 4 % in daily estimation.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.608-612
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• 2012

We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

• 한국염색가공학회지
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• 제23권2호
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• pp.140-145
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• 2011

The effects of nonionic surfactant solutions of 0.1g/dL on detergency and liquid wetting/retention properties of soiled polyester/cotton(65/35) cloth were studied. Soiled polyester/cotton(65/35) cloth (EMPA 104) and 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85) were used in the study. The water retention and liquid retention capacity values of soiled cloth were decreased compared with those of unsoiled cloth. The wetting and water retention of soiled cloth improved with addition of surfactants, whereas water retention ratio(W/H) values didnot change markedly. Generally surfactants with low surface tension and high HLB (Hydrophile-lipophile balance) were more effective in improving the wetting/retention properties of soiled cloth. Nonionic surfactants having high ethylene oxide contents of 20 moles; i.e., Tween 20, 40, 60 & 80, showed better detergency than low ethylene oxide contents of 4 moles; i.e., Tween 21, 61 & 81. As HLB values of surfactants and $cos{\theta}$ of the soiled cloth increase, the detergency values of soiled cloth increased.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.320-326
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• 2018

본 연구에서는리튬이온전지음극활물질로 Graphite의 전기화학적특성을향상시키기 위하여 Graphite/Silicon/Carbon (G/Si/C) 복합소재를 제조하였다. 제조된 G/Si/C 합성물은 XRD, TGA, SEM을 사용하여 물성을 분석하였다. 또한 $LiPF_6$ (EC:DMC:EMC=1:1:1 vol%) 전해액에서 리튬이차전지의 충 방전 사이클, 율속, 순환전압전류 및 임피던스 테스트를 통해 전기화학적 성능을 조사하였다. G/Si/C 전극을 사용한 리튬이온전지는 Graphite 전극을 사용한 전지보다 우수한 특성을 나타내었으며 Silicon 함량이 늘어날수록 용량은 높아지나 안정성이 저하됨을 확인하였다. 또한 $25{\mu}m$ 이하의 Silicon을 사용하였을 때 용량과 안정성 모두 향상되는 것을 나타내었다. Silicon (${\leq}25{\mu}m$) 10 wt%인 경우 G/Si/C 복합소재는 495 mAh/g의 초기 방전 용량, 89%의 용량 보존율과 2 C/0.1 C에서 80%의 속도 특성을 보였다.

• 한국세라믹학회지
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• 제48권6호
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• pp.531-536
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• 2011

Al doped $LiMn_2O_4$ ($LiMn_2O_4:Al$) synthesized by several Al doping process and Solid State method. The Al contents in $Mn_{1-x}Al_xO_2$ for $LiMn_2O_4:Al$ were analyzed 1.7 wt% by EDS. The $LiMn_2O_4:Al$ confirmed cubic spinel structure and approximately 5 ${\mu}m$ particles regardless of three kinds of doping process by solid state method. In the result of electrochemical performances, initial discharge capacity had 115 mAh/g in case of $LiMn_2O_4$ and 111 mAh/g of $LiMn_2O_4:Al$ after 100th cycle at room temperature. But the capacity retention results showed that $LiMn_2O_4$ and $LiMn_2O_4:Al$ were 44% and 69% respectively in the 100th cycle at 60$^{\circ}C$. Therefore we are confirmed that $LiMn_2O_4:Al$ increased the capacity retention about 25% than $LiMn_2O_4$, thus the effect of Al dopping on $LiMn_2O_4$ capacity retention.

• 전기화학회지
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• 제27권1호
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• pp.47-54
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• 2024

본 연구에서는 유황의 절연 특성 및 리튬 폴리 설파이드 용출로 인해 전지 수명 저하를 최소화하기 위해 ZIF67/rGO를 사용하였다. rGO로 포장이 된 ZIF67는 탄소 스펀지 내에 공간을 더 많이 만들어주며, 다량의 유황을 보관할 수 있다. 유황@ZIF67/rGO 복합체를 합성하고, 스펀지 형태로 제조함으로써 유황의 담지 능력을 향상시켰다. 그 결과로서 높은 초기용량을 보였으며, 약 1093 mAh g^-1의 값을 나타내며 100사이클 후에 84%의 용량유지율을 보임을 확인하였다. 코발트와 탄소의 복합화를 통하여 유황과의 상호작용이 높아 ZIF67/rGO는 리튬유황전지의 양극 활물질인 유황을 담지하는 담지체로서의 높은 성능을 나타남을 확인하였으며, 높은 초기용량과 용량유지율이 개선되었음을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제31권5호
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• pp.1257-1261
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• 2010

The electrochemical performances of anode composites comprising elemental silicon (Si), silicon monoxide (SiO), and graphite (C) were investigated. The composite devoid of elemental silicon (SiO:C = 1:1) and its carbon coated composite showed reduced capacity degradation with measured values of 606 and 584 mAh/g at the fiftieth cycle. The capacity retention nature when the composites were cycled followed the order of Si:SiO:C = 3:1:4 < Si:SiO:C = 2:2:4 < SiO:C = 1:1 < SiO:C = 1:1 (carbon coated). A comparison of the capacity retention properties for the composites in terms of the silicon content showed that a reduced silicon content increased the stability of the composite electrodes. Even though the carbon-coated composite delivered low capacity during cycling compared to the other composites, its low capacity degradation made the anode a better choice for lithium ion batteries.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1299-1304
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• 2014

The electrochemical performance of Li-S cells was investigated in various ternary electrolyte solutions composed of 1,2-dimethoxyethane (DME), tetra(ethylene glycol) dimethyl ether (TGM), and 1,3-dioxolane (DOX). The discharge capacity values and cycle data obtained at each composition were statistically treated with the Minitab program to obtain mixture contour plots, from which the optimal composition of the ternary solvent systems was predicted. The discharge capacities and capacity retention were quite dependent on the electrolyte composition. It was estimated from the contour plots of the capacity at 1.0 C that the discharge capacity sharply increased with a decrease in the TGM content. High capacities greater than 900 mAh/g at 1.0 C were expected for the electrolyte composition with a volume ratio of DME/TGM/DOX = 1/0/1. In contrast, it was predicted from the mixture contour plot of the capacity retention that the cycle performance would significantly increase with an increase in the DME content.

• 한국토양비료학회지
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• 제37권2호
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• pp.55-58
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• 2004

본 연구에서는 국내에서 사용중인 몇 가지 원예용 배지재료의 수분특성을 유럽표준배지분석법에 따라 수분보유곡선을 작성함으로써 살펴보았다. 유기성배지로는 피트모스, 코이어, 바크, 톱밥, 생왕겨를 사용하였고. 무기성배지로는 펄라이트. 팽화 버미큘라이트, 입상암면, 클레이볼을 사용하였다. 수분특성곡선은 유럽표준배지분석법을 사용하여 수두 변화에 따른 수분함랑(v/v)으로 작성하였다. 유기성배지 중 피트와 코이어는 유사한 수분특성을 나타내었으며 쉽게 이용 가능한 수분함량 (easily available water)이 30% 이상으로 식물생육에 적합한 보수성을 나타내었다. 반면 바크, 톱밥, 생왕겨와 무기성 배지들은 -10 cm의 낮은 수두하에서도 보유되는 수분함량이 매우 낮았고 식물이 쉽게 이용 가능한 수분함량 또한 매우 낮아 통기성은 충분하나 보수력이 부족하여 작물재배시 수분부족현상이 자주 발생할 것으로 보였다. 한편. 원예용 배지는 같은 종류의 배지라도 원산지에 따라 수분 특성에 차이를 보였으며, 입자가 미세하고, 시비 또는 부숙처리를 가한 것일수록 높은 수분보유능력을 나타내었다.