• Title/Summary/Keyword: resonance behavior

Search Result 359, Processing Time 0.031 seconds

Polymerization and Thermal Characteristics of Acrylonitrile/Dicyclohexylammonium 2-Cyanoacrylate Copolymers for Carbon Fiber Precursors

  • Kim, Ki-Young;Park, Woo-Lee;Chung, Yong-Sik;Shin, Dong-Geun;Han, Jin-Wook
    • Carbon letters
    • /
    • v.12 no.1
    • /
    • pp.31-38
    • /
    • 2011
  • This study experimentally investigated dicyclohexylammonium 2-cyanoacrylate (CA) as a potential comonomer for polyacrylonitrile (PAN) based carbon fiber precursors. The P(AN-CA) copolymers with different CA contents (0.19-0.78 mol% in the feed) were polymerized using solution polymerization with 2,2-azobis(isobutyronitrile) as an initiator. The chemical structure and composition of P(AN-CA) copolymers were determined by proton nuclear magnetic resonance and elemental analysis, and the copolymer composition was similar to the feeding ratio of the monomers. The effects of CA comonomer on the thermal properties of its copolymers were characterized differential scanning calorimetry (DSC) in nitrogen and air atmospheres. The DSC curves of P(AN-CA) under nitrogen atmosphere indicated that the initiation temperature for cyclization of nitrile groups was reduced to around $235^{\circ}C$. The heat release and the activation energy for cyclization reactions were decreased in comparison with those of PAN homopolymers. On the other hand, under air atmosphere, the P(AN-CA) with 0.78 mol% CA content showed that the initiation temperature of cyclization was significantly lowered to $160.1^{\circ}C$. The activation energy value showed 116 kJ/mol, that was smaller than that of the copolymers with 0.82 mol% of itaconic acids. The thermal stability of P(AN-CA), evidenced by thermogravimetric analyses in air atmosphere, was found higher than PAN homopolymer and similar to P(AN-IA) copolymers. Therefore, this study successfully demonstrated the great potential of P(AN-CA) copolymers as carbon fiber precursors, taking advantages of the temperature-lowering effects of CA comonomers and higher thermal stability of the CA copolymers for the stabilizing processes.

Deep Cerebral Venous Thrombosis : Successful Treatment by Systemic Urokinase Followed by Heparin - Case Report - (뇌 심부 정맥 혈전증 : 전신적 유로키나제 혈전용해술 후 헤파린 투여 치료법의 성공 증례 - 증 례 보 고 -)

  • Park, Jae Hyo;Yang, Ji Ho;Yoo, Do Sung;Cho, Kyoung Suok;Huh, Pil Woo;Kwon, Seong Hh;Kim, Dal Soo;Kang, Joon Ki
    • Journal of Korean Neurosurgical Society
    • /
    • v.30 no.1
    • /
    • pp.99-104
    • /
    • 2001
  • We present two cases of deep cerebral venous thrombosis(DCVT) with the totally occluded straight sinus. A 42-year-old female received with altered mentality . She has taken antihistamine for six years to treat the paranasal sinusitis. Another 34-year-old female who used the oral contraceptive for 11 months presented with acute behavior change . Both of these patients were diagnosed by computed tomography(CT), magnetic resonance(MR) imaging, and cerebral angiography. They were fully recovered with systemic urokinase thrombolysis followed by heparin therapy. We report that the intravenous thrombolysis was potentially effective management strategy in our cases of DCVT with the totally occluded straight sinus.

  • PDF

Analysis of Pineal Cyst ; Clinical and Radiological Characteristics (송과체 낭종의 임상적, 방사선학적 특성 분석)

  • Kim, Yong-Su;Jung, Shin;Yoon, Sang-Won;Lee, Jung-Kil;Kim, Tae-Sun;Kim, Jae-Hyoo;Kim, Soo-Han;Kang, Sam-Suk;Lee, Je-Hyuk
    • Journal of Korean Neurosurgical Society
    • /
    • v.29 no.7
    • /
    • pp.899-903
    • /
    • 2000
  • Objective : Object : A 7-year retrospective clinical and MRI study was reviewed to evaluate the characteristics of pineal cyst. We evaluated results of clinical and radiologic change of pineal cyst during follow up period. Patients and Methods : From 1992 to 1999, 50 patients with pineal cyst were visited for evaluation. Follow up clinical information was obtained from patients or clinical record through phone conversation. also radiologic findi-ngs of pineal cyst in mid-sagittal MRI were reviewed in detail. Results : Pineal cysts were usually asymptomatic and detected incidentally during evaluation of other diseases. Sagittal MRI is the most useful diagnostic test. The radiologic findings of pineal cyst were isointensity on T1WI comared to CSF and slightly high signal intensity on T2WI. Cyst wall was variably enhanced on Gad-enhanced T1WI. The average size of cyst was $13.9{\times}13.0mm$. The pineal cyst was classified into five groups according to previous report. Long term behavior of these lesions are not apparent, but in our study they showed no specific changes in clinical and radiological aspects during 25 months. Conclusion : Although long-term follow up results are needed, the pineal cyst are considered as normal variants. In our 25 months follow up results, there was no rapid change of cyst both clinically and radiologically. Therefore, frequent radiologic evaluation seems unnecessary except type III pineal cyst.

  • PDF

Two Cases of Primary Osteolytic Intraosseous Meningioma of the Skull Metastasizing to Whole Skull and the Spine

  • Kim, Hyool;Jung, Tae-Young;Kim, In-Young;Lee, Jung-Kil
    • Journal of Korean Neurosurgical Society
    • /
    • v.51 no.3
    • /
    • pp.151-154
    • /
    • 2012
  • We report here two cases of primary intraosseous meningioma with aggressive behavior. A 68-year-old man presented with a one year history of a soft, enlarging mass in the right parietal region. Magnetic resonance image (MRI) revealed a 6 cm sized, heterogeneously-enhancing, bony expansi1e mass in the right parietal bone, and computed tomograph (CT) showed a bony, destructive lesion. The tumor, including the surrounding normal bone, was totally resected. Dural invasion was not apparent Diagnosis was atypical meningioma, which extensively metastasized within the skull one year later. A 74-year-old woman presented with a 5-month history of a soft mass on the left frontal area. MRI revealed a 4 cm sized, multilobulated, strongly-enhancing lesion on the left frontal bone, and CT showed a destructive lesion. The mass was adhered tightly to the scalp and dura mater. The lesion was totally removed. Biopsy showed a papillary meningioma. The patient refused adjuvant radiation therapy and later underwent two reoperations for recurred lesions, at 19 and at 45 months postoperative. The patient experienced back pain 5 years later, and MRI showed an osteolytic lesion on the 11th thoracic vertebra. After her operation, a metastatic papillary meningioma was diagnosed. These osteolytic intraosseous meningiomas had atypical/malignant pathologies, which metastasized to whole skull and the spine.

Vibration Control for Tower of Suspension Bridge under Turbulence using TMD (난류하에서의 TMD에 의한 현수교 주탑의 진동제어)

  • Kim, Ki Du;Hwang, Yoon Koog;Byun, Yun Joo;Chang, Dong Il
    • Journal of Korean Society of Steel Construction
    • /
    • v.9 no.2 s.31
    • /
    • pp.181-191
    • /
    • 1997
  • Before cables are constructed, tower of suspension bridge is behaved as a cantilever type. Buffeting occured by unsteady loading of the tower due to velocity fluctuation in the oncoming flow has a wind velocity consistent with fundamental frequency of the tower and may give rise to large response by the tower resonance. To reduce the dynamic response by buffeting, the behavior of tower with TMD(Tuned Mass Damper) has studied using finite element method in time domain. The buffeting was obtained by transforming the velocity spectrum in frequency domain to random variable in certain time domain. The most probable maximum displacement which can be occured during the time interval was obtained using peak factor. The optimum location for TMD installation and TMD specification were decided by parametric study. Also, the effect of vibration control about various wind velocity was studied by the TMD which has optimum specification and location.

  • PDF

Interactivity of Neural Representations for Perceiving Shared Social Memory

  • Ahn, Jeesung;Kim, Hye-young;Park, Jonghyun;Han, Sanghoon
    • Science of Emotion and Sensibility
    • /
    • v.21 no.3
    • /
    • pp.29-48
    • /
    • 2018
  • Although the concept of "common sense" is often taken for granted, judging whether behavior or knowledge is common sense requires a complex series of mental processes. Additionally, different perceptions of common sense can lead to social conflicts. Thus, it is important to understand how we perceive common sense and make relevant judgments. The present study investigated the dynamics of neural representations underlying judgments of what common sense is. During functional magnetic resonance imaging, participants indicated the extent to which they thought that a given sentence corresponded to common sense under the given perspective. We incorporated two different decision contexts involving different cultural perspectives to account for social variability of the judgments, an important feature of common sense judgments apart from logical true/false judgments. Our findings demonstrated that common sense versus non-common sense perceptions involve the amygdala and a brain network for episodic memory recollection, including the hippocampus, angular gyrus, posterior cingulate cortex, and ventromedial prefrontal cortex, suggesting integrated affective, mnemonic, and social functioning in common sense processing. Furthermore, functional connectivity multivariate pattern analysis revealed that interactivity among the amygdala, angular gyrus, and parahippocampal cortex reflected representational features of common sense perception and not those of non-common sense perception. Our study demonstrated that the social memory network is exclusively involved in processing common sense and not non-common sense. These results suggest that intergroup exclusion and misunderstanding can be reduced by experiencing and encoding long-term social memories about behavioral norms and knowledge that act as common sense of the outgroup.

Elastic Behavior of Contact Lense(I) : Effect of Vibration (콘택트 렌즈의 탄성에 관한 연구(I) : 진동에 의한 영향)

  • Kim, Dase-Soo
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.4 no.2
    • /
    • pp.1-16
    • /
    • 1999
  • Differential equations and its numerical solution program using Turbo-C were formulated to describe the radical distribution and average displacement amplitude of vibrating dehydrated contact lens(HEMA) driven by sinusoidal or rectangular pressure. The natural resonant frequency of the lens diaphram(thickness 0.08mm, diameter 14mm, curvature radius 8mm) was measured to be 5730 Hz from the extrapolation of frequency vs addedmass to the diaphram curve. The Young's modulus of the lens was measured to be $4{\times}10^9$ Pa with altering the original shape. The effect of parameters such as thickness, effective radius, damping coeff., amplitude of driving pressure on the vibration characteristics was illustrated by the computer simulation of the derived program. When the frequency of driving pressure coincides with the integral multiple of fundamental resonance frequency of the lens the wave pattern changes from arc to bell-shape along the radial position of the diaphram. If this happens to the contact lens on the cornea in vivo, it might create the feel of pull of the lens due to the increased rise of central part of the lens.

  • PDF

Mild encephalopathy with a reversible splenial lesion in a girl with acute pyelonephritis

  • Yeom, Jung Sook;Koo, Chung Mo;Park, Ji Sook;Seo, Ji-Hyun;Park, Eun Sil;Lim, Jae-Young;Woo, Hyang-Ok;Youn, Hee-Shang
    • Clinical and Experimental Pediatrics
    • /
    • v.61 no.2
    • /
    • pp.64-67
    • /
    • 2018
  • We report the case of a 12-year-old girl who had mild encephalopathy with a reversible splenial lesion (MERS) associated with acutepyelonephritis caused by Escherichia coli. The patient was admitted with a high fever, and she was diagnosed with acute pyelonephritis based on pyuria and the results of urine culture, which detected cefotaxime-sensitive E. coli. Although intravenous cefotaxime and tobramycin were administered, her fever persisted and her C-reactive protein level increased to 307 mg/L. On day 3 of admission, she demonstrated abnormal neuropsychiatric symptoms, such as delirium, ataxia, and word salad. Magnetic resonance imaging (MRI) of the brain performed on day 4 showed marked hyperintensities in the bilateral corpus callosum and deep white matter on diffusion-weighted images, with corresponding diffusion restriction on apparent diffusion coefficient mapping. No abnormalities or pathogens were detected in the cerebrospinal fluid; however, lipopolysaccharides (LPS, endotoxin) were detected in plasma (41.6 pg/mL), associated with acute neurological deterioration. Her clinical condition gradually improved, and no neurological abnormalities were observed on day 6. Follow-up brain MRI performed 2 weeks later showed near-disappearance of the previously noted hyperintense lesions. In this patient, we first proved endotoxemia in a setting of MERS. The release of LPS following antibiotic administration might be related to the development of MERS in this patient. The possibility of MERS should be considered in patients who present with acute pyelonephritis and demonstrate delirious behavior.

Intravenous levetiracetam versus phenobarbital in children with status epilepticus or acute repetitive seizures

  • Lee, Yun-Jeong;Yum, Mi-Sun;Kim, Eun-Hee;Ko, Tae-Sung
    • Clinical and Experimental Pediatrics
    • /
    • v.59 no.1
    • /
    • pp.35-39
    • /
    • 2016
  • Purpose: This study compared the efficacy and tolerability of intravenous (i.v.) phenobarbital (PHB) and i.v. levetiracetam (LEV) in children with status epilepticus (SE) or acute repetitive seizure (ARS). Methods: The medical records of children (age range, 1 month to 15 years) treated with i.v. PHB or LEV for SE or ARS at our single tertiary center were retrospectively reviewed. Seizure termination was defined as seizure cessation within 30 minutes of infusion completion and no recurrence within 24 hours. Information on the demographic variables, electroencephalography and magnetic resonance imaging findings, previous antiepileptic medications, and adverse events after drug infusion was obtained. Results: The records of 88 patients with SE or ARS (median age, 18 months; 50 treated with PHB and 38 with LEV) were reviewed. The median initial dose of i.v. PHB was 20 mg/kg (range, 10-20 mg/kg) and that of i.v. LEV was 30 mg/kg (range, 20-30 mg/kg). Seizure termination occurred in 57.9% of patients treated with i.v. LEV (22 of 38) and 74.0% treated with i.v. PHB (37 of 50) (P=0.111). The factor associated with seizure termination was the type of event (SE vs. ARS) in each group. Adverse effects were reported in 13.2% of patients treated with i.v. LEV (5 of 38; n=4, aggressive behavior and n=1, vomiting), and 28.0% of patients treated with i.v. PHB (14 of 50). Conclusion: Intravenous LEV was efficacious and safe in children with ARS or SE. Further evaluation is needed to determine the most effective and best-tolerated loading dose of i.v. LEV.

A Study on PFC Buck-Boost AC-DC Converter of Soft Switching (소프트 스위칭형 PFC 벅-부스트 AC-DC 컨버터에 관한 연구)

  • Kwak, Dong-Kurl
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.12 no.6
    • /
    • pp.465-471
    • /
    • 2007
  • The system efficiency of the proposed Buck-Boost AC-DC converter is increased by soft switching method. The converter includes to merit of power factor correction (PFC) from sinusoidal control of input current. The switching behavior of control switches operates with soft switching by partial resonance, and then the proposed converter has high system efficiency with decrement of switching power loss. The input current waveform in proposed converter is got to be a sinusoidal form of discontinuous quasi-pulse row in proportion to magnitude of AC input voltage under the constant duty cycle switching. Therefore, the input power factor is nearly unity. The output voltage of the converter is regulated by PWM control technique. The discontinuous mode action of current flowing into inductor makes to simplify control method and control components. The proposed PFC Buck-Boost converter is analyzed to compare with the conventional PFC Buck-Boost converter. Some computer simulative results and experimental results confirm to the validity of the analytical results.