• Composites Research
• /
• v.31 no.4
• /
• pp.161-170
• /
• 2018

Cylindrical composite lattice structures are manufactured by filament winding process. The fiber volume fraction non-uniformity and resin rich layers that can occur in the manufacturing process affect the stiffness and strength of the structure. Through the cross-section examination of the hoop and helical ribs, which are major elements of the composite lattice structure, we observed the fiber volume fraction non-uniformity and resin rich layers. Based on the results of the cross-section examination, the stiffness of the ribs was analyzed through the experimental and theoretical approaches. The results show that the fiber volume fraction non-uniformity and resin rich layers have an obvious influence on the rib stiffness of composite lattice structure.

• Polymer(Korea)
• /
• v.25 no.1
• /
• pp.122-132
• /
• 2001

Thermoplastic film infusion process was investigated by using a rubber tool, which intrinsically contains a thermally-expandable characteristic and effectively compensates for the pressure loss caused by thermoplastic polymer infusion. Increasing temperature up to the melting temperature of matrix, the polymer melt subsequently infused into the dry fabric, but the pressure was successfully sustained by the rubber tool. Even with the decreased resin volume, the rubber tool produced sufficiently high elastic force for continuous resin infusion. Combining D'Arcy's law with the compressibility of rubber tool and elastic fiber bed, a film infusion model was developed to predict the resin infusion rate and pressure change as a function of time. In addition, the film infusion process without the rubber tool was viewed and analyzed by a compression process of the elastic fiber bed and viscous resin melt. The compressibility of fiber bed was experimentally measured and the multiple-step resin infusion was well described by the developed model equations.

• Composites Research
• /
• v.30 no.6
• /
• pp.393-398
• /
• 2017

The shrinkage distribution of a dental composite (Clearfil AP-X, Kuraray, Japan) used for dental restoration was observed using a digital image correlation method. In order to analyze the shrinkage distribution formed during and after light irradiation, digital images were taken with different photographing conditions for each period. Optimal photographing conditions during LED irradiation were obtained through a preliminary experiment in which the exposure time was applied from 0.15 ms to 0.55 ms in 0.05 ms intervals. The DIC analysis results showed that the strain was non-uniform. For the initial 20 s of light irradiation the composite resin shrank to the level of 50~60% of the final curing shrinkage. Such large shrinkage amount of the composite resin lump affected the tensile stress concentration near the adhesive region between the composite resin and the substrate.

• Elastomers and Composites
• /
• v.35 no.2
• /
• pp.89-97
• /
• 2000

Waterborne epoxy resins have been developed in order to meet environmental regulations for reduction of the emission of organic solvents from coating industry As each generation has filled a performance gap in the previous technology, new waterborne epoxy resin has developed. Initially, waterborne epoxy resins were used primarily on masonry, but the subsequent generations have found utility for the protection of metallic substrates as well. Indeed, the third generation systems have been formulated to produce the high performance industrial maintenance primers which possess the desirable combination of good corrosion resistance and low volatile organic compound levels. This paper outlines the important guidelines for formulating waterborne epoxy primers from waterborne epoxy resin that has recently developed in our company. The importance of using the appropriate resin-curing agent system at the optimized epoxy to amine ratio is stressed.

• The Journal of Korean Academy of Prosthodontics
• /
• v.45 no.6
• /
• pp.724-734
• /
• 2007

Statement of problem. Translucency and masking effect of provisional crown and fixed partial denture materials is an important esthetic consideration. But, provisional resin materials differ substantially in their ability to mask underlying colors. Purpose. The purpose of this study was to evaluate the translucency differences of provisional resin materials at various thicknesses and the correlation between the translucency and the masking efficiency. Material and methods. Two polymethyl methacrylate resins (Jet Tooth Shade, Alike) and three resin composites (Protemp 3 Garant, Luxatemp and Revotek LC) were used. Specimens (n=6) were fabricated from each material in 0.3, 0.5, 0.8, 1.0, 1.5, 2.0 and 3.0 mm thickness. The CIELAB parameters of each specimens were measured using a spectrophotometer. The translucency parameter (TP) values and the masking effect $({\Delta}ME^*{_{ab}})$ values were computed and all data were statistically analyzed by one-way ANOVA and the multiple comparisons Scheffe test. The correlation between the thickness and the TP values and the correlation between the thickness and the ${\Delta}ME^*{_{ab}}$ values were also evaluated by correlation analysis and regression analysis. Results. The TP values and the ${\Delta}ME^*{_{ab}}$ values were significantly related to the thickness in all specimens. The TP values were more sensitive to the change of thickness than the ${\Delta}ME^*{_{ab}}$ values. The order of the translucency by brand was different from the order of the masking effect by brand in all thickness groups. Conclusion. Within the limitations of this study, the translucency and masking effect of the provisional resin materials investigated were significantly related to their thickness. The masking effect of provisional resin was correlated with the translucency parameter, but the order of the masking effect by brand was different from the order of the translucency parameter.

• Journal of dental hygiene science
• /
• v.9 no.2
• /
• pp.189-195
• /
• 2009

Two diketones, 1,2-phenylpropanedione (PD) and diacetyl (DA) were investigated as new visible light photosensitizers for dental composite resin of bis-GMA in order to improve the photopolymerization effect. The photopolymerization efficiency of bis-GMA composite resin containing PD and DA was studied by IR absorption spectroscopy. And the results were compared with that of camphorquinone (CQ). Relative photopolymerization efficiency of the photosensitizers increased in the order of DA < CQ < PD. Thus. PO is a new visible light photosensitizer for dental composite resin with higher photopolymerization efficiency than that of CQ.

• Composites Research
• /
• v.22 no.6
• /
• pp.45-51
• /
• 2009

The marginal integrity at the composite resin-tooth interface has been analyzed in real time through acoustic emission (AE) monitoring during the polymerization shrinkage of composite resin subjected to the light exposure. It was found that AE signals were generated by the polymerization shrinkage. Most AE hit events showed a blast type signal having the principal frequency band of 100-200kHz. Bad bonding states were indicated by many hit events in the initial curing period of 1 minute with high contraction rate. The quantity of hit events for the human molar dentin specimen was much less than that for the steel ring specimen but more than that for the PMMA ring specimen. The better the bonding state, the less the AE hit events. The AE characteristics were related with the tensile crack propagation occurring in the adhesive region between the composite resin and the ring substrate as well as the compressive behavior of the ring substrate, which could be used for a nondestructive characterization of the marginal disintegrative fracture of the dental restoration.

• Composites Research
• /
• v.28 no.1
• /
• pp.1-5
• /
• 2015

In this paper the influence of fiber orientation of basalt and carbon inter-ply fabrics on the flexural properties of hybrid composite laminates was experimentally investigated. Four types of basalt/carbon/epoxy inter-ply hybrid composite laminates with varying angle ply orientation of reinforced basalt fiber and fixed orientation of carbon fiber were fabricated using hand lay-up technique. Three point bending test was performed according to ASTM 7264. The fracture surface analysis was carried out by scanning electron microscope (SEM). The results obtained from the four laminates were compared. Lay-up pattern of $[0B/+30B/-30B/0C]_S$ exhibits the best properties in terms of flexural strength and flexural modulus. Scanning electron microscopy results on the fracture surface showed that the interfacial de-bonding between the fibers and epoxy resin is a dominant fracture mode for all fiber lay-up schemes.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.9
• /
• pp.793-797
• /
• 2007

In this paper, the long time breakdown characteristic of the epoxy composite, which is widely used in the insulation system for high voltage application, was estimated with Weibull distribution. In the procedure of the estimation, the short time breakdown characteristics for the epoxy composite specimens, which were made with the variation of hardener and/or filler, were tested firstly. Then the long time voltage-to-time test was implemented. Finally, the long time breakdown voltage of each specimen was estimated with the parameters obtained from the statistical treatment with Weibull distribution. Base on the results, it has been found that the optimal weight ratio of epoxy resin/hardener/filler that has the excellent long time breakdown characteristic was 100/100/65. It was due to the silane treatment which relieves the electric field at the interface between filler and epoxy.

• Journal of the Korean Ceramic Society
• /
• v.26 no.5
• /
• pp.617-624
• /
• 1989

Piezoelectric composites of O-3 connectivity were prepared by thermosetting barium titanate-phenolic resin composite under various cruing pressure. Among three kinds of pore in O-3 type ceramic-polymer composite, such as matrix pores, particle pores, and ceramic-polymer interface pores, the effect of interface porosity on the dielectric and piezoelectric constant was investigated. In pure barium titanate ceramics, the porosity factor of dielectric and piezoelectric constants were 5.7 and 5.0, respectively. However, in BaTiO3-polymer composite, the interface porosity factor of the piezoelectric constant was greater than that of the dielectric constant, interface porosity factor b in d33 was 9.8 and in r 4.6. On the other, piezoelectric voltage constant g33 was independent of the porosity of barium titanate ceramics. But in composite system, the piezoelectric voltage constant g33 was decreased with interface porosity.