DOI QR코드

DOI QR Code

An Estimation of Breakdown Time of the Epoxy Composites according to Filler and Silane Treatment

충진제와 실란처리에 따른 에폭시 복합체의 파괴시간 예측

  • 신철기 (부천대학 디지털산업전자과)
  • Published : 2007.09.01

Abstract

In this paper, the long time breakdown characteristic of the epoxy composite, which is widely used in the insulation system for high voltage application, was estimated with Weibull distribution. In the procedure of the estimation, the short time breakdown characteristics for the epoxy composite specimens, which were made with the variation of hardener and/or filler, were tested firstly. Then the long time voltage-to-time test was implemented. Finally, the long time breakdown voltage of each specimen was estimated with the parameters obtained from the statistical treatment with Weibull distribution. Base on the results, it has been found that the optimal weight ratio of epoxy resin/hardener/filler that has the excellent long time breakdown characteristic was 100/100/65. It was due to the silane treatment which relieves the electric field at the interface between filler and epoxy.

Keywords

References

  1. B. Ellis, 'The Kinetics of Cure and Network Formation-chemistry and Technology of Epoxy Resin, Bryan Ellis, Edit.', Blackie Academic & Professional, p. 77, 1993
  2. Lee, K.-Y., Lee, K.-W., and Choi, Y.-S., 'Improved thermal, structural and electrical properties of elastic-epoxy blends system', KIEE International Transactions on Electrophysics and Applications, Vol. 4C, Part 5, p. 230, 2004
  3. Rygal, R. Latour-Slowikowska, H. Slowikowski, and J. Paziewska, D., 'The influence of the filler characteristics on the surface resistivity of epoxy composition applied in SF insulation system', Conf. Rec., 1992 IEEE Inter. Symp. Elec. Insul., Baltimore, U.S.A, p. 279, 1992
  4. W. R. Ashcroft, 'Curing Agent for Epoxy Resins - Chemistry and Chemistry and Technology of Epoxy Resins, Bryan Ellis, Edit.', Blackie Academic & Professional, p. 37, 1993
  5. T. Imai, Y. Hirano. H. Hirai. S. Kojima, and T. Shimizu, 'Preparation and proprtties of epoxy-organically modified layered silicate nanocomposites', Proc. IEEE ISEI, p. 379, 2002
  6. 김탁용, 이덕진, 홍진웅, '흡수 열화에 따른 Epoxy/$SIO_{2}$ 복합체의 전기적 특성 및 수명예측', 전기전자재료학회논문지, 13권, 9호, p. 758, 2000
  7. 市田, 鈴木, '信賴性の 分布と統計', 日科技連, 1990
  8. B. Ellis, 'Introduction to the Chemistry, Synthesis, Manufacture and Characteristics of Epoxy Resins-chemistry and Technology of Epoxy Resins, Bryan Ellis, Edit.', Blackie Academic & Professional, p. 1, 1993
  9. Y. Yosida, 'The degradation of adhesion between epoxy and filler with absorption of water boiling for epoxy composite filled with silica particles', T. IEE of Japan, Vol. 117-A, No. 11. 1997