• Title/Summary/Keyword: residue study

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A Study on the Quality of the Domestic Fly Ash as an Additive for Concrete (콘크리트용 혼화재(混和材)로서 국산 플라이애쉬의 품질에 관한 실험적 연구)

  • Moon, Han Young;Seo, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.213-221
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    • 1987
  • To use fly ash as an additive for concrete, authors collected 15 kinds of domestic fly ashes and tested the chemical compositions and physical properties of the fly ashes. Fluidity of the fly ash paste was also investigated. The result shows that the chemical compositions of the fly ashes were in the range of regulation of Korean Industrial Standards except ignition loss and the following relationships in fly ash were studied; specific surface and residue in standard sieve, specific surface and unit weight, residue in standard sieve and ignition loss. For the given flow properties, fly ash paste required higher water-binder ratio than cement paste.

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Water Gas Shift Reaction Research of the Synthesis Gas for a Hydrogen Yield Increase (수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구)

  • Kim, Min-Kyung;Kim, Jae-Ho;Kim, Woo-Hyun;Lee, See-Hoon
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.9-14
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    • 2009
  • Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

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Chemical Water Quality of Lake Eui-Am

  • Choe, Sang;Kwak, Hi-Sang
    • 한국해양학회지
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    • v.6 no.2
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    • pp.63-77
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    • 1971
  • An year-long survey of chemical water quality for Lake Eui-am in Kang-won Province, Korea, was conducted from June 1970 to May 1971 to study the water quality and seasonal variations of productivities in relation to selected physical and chemical environmental factors. A monthly series of water samples were taken at the deepest basin of 18m depth of the lake. Water quality parameters determined were water temperature, Secchi disc reading(transparency), pH, O$\_$2/, CO$\_$2/, alkalinity, acidity, Cl, hardness, Ca, Mg, total residue, total ignitious residue, COD, BOD$\_$5/, nutrients, total-Fe, soluble Fe, Mn and Cu. On the whole, the results indicate that the chemical water quality of Lake Eui-am is high, and vary with season. The lake water is characterized that higher levels of dissolved oxygen(8.6 ml/L in mean of whole water) or percent saturation of dissolved oxygen(114%), and of nitrate nitrogen (523 $\mu\textrm{g}$/L). On the other hand, CO$\_$2/(9.6ppm), chlorides(3.5ppm), Ca(7.7ppm) Mg(2.2ppm), hardness(28.5ppm), silica(2.4ppm) and BOD$\_$5/(1.08ppm) are quite low. In terms of nutrient levels, the lake water exhibit slight signs of eutrophication. The high values for nitrate nitrogen, soluble iron and Cu of the lake water suggest that there are some imputs such as domestic and industrial discharges to the lake.

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Effect of Choice Feeding on Performance, Gastrointestinal Development and Feed Utilization of Broilers

  • Yao, Junhu;Tian, Xiaoyan;Xi, Haibo;Han, Jincheng;Xu, Ming;Wu, Xiaobing
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.1
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    • pp.91-96
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    • 2006
  • The experiment was conducted to study the effect of choice feeding on growth performance, carcass quality, gastrointestinal development and feed utilization of 22-49 days old broilers. One hundred and forty four 22-day-old broilers were randomly allocated to 3 treatments with 4 replicates per treatment and 12 birds per replicate. Three feeding regimes are complete diet (control), ground corn and protein concentrate (treatment I), and soybean meal and balancer (treatment II). Protein concentrate is the residue part of complete diet without corn, and balancer is the residue part of complete diet without soybean meal. Treatment I and II are designed for the broilers to freely choose the two parts of diet. The results showed that: (1) broilers under choice feeding (treatment I and II) had lower performances compared with the control; (2) gastrointestinal development and the efficiency ratios that broilers converted dietary crude protein and lysine to body weight gain were improved in treatment I (p<0.05); (3) there were no significant differences in the apparent metabolizabilities of dietary dry matter, crude protein and gross energy, and deposition ratios of dietary nitrogen and energy, and carcass quality among three feeding regimes (p>0.05).

Ginsenoside Composition and Quality Characteristics of Red Ginseng Extracts prepared with Different Extracting Methods (추출방법에 따른 홍삼추출액의 사포닌 조성과 품질특성)

  • Lee, Gang Seon;Nam, Ki Yeul;Choi, Jae Eul
    • Korean Journal of Medicinal Crop Science
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    • v.21 no.4
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    • pp.276-281
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    • 2013
  • This study was conducted to compare the contents of ginsenoside according the water extract conditions of red ginseng. In method A, red ginseng extract was prepared at $75^{\circ}C$ for 18 hours by 1 time extraction, and method B, the preparation was done at $85^{\circ}C$ for 18 hours by 1 time extraction. In method C, the primary extract prepared at $75^{\circ}C$ for 9 hours was blended with the secondary extract prepared by re-extracting the red ginseng residue obtained after the primary extraction, at $85^{\circ}C$ for 9 hours. Method D was the same procedure as method C but the extraction temperature for the primary extraction was $85^{\circ}C$ and that for the secondary extraction was $95^{\circ}C$. The contents of total and $Rb_1$, $Rg_1$ and $Rg_3$ ginsenoside were highest in Method C. The content of prosapogenin (ginsenoside $Rg_2$, $Rg_3$, $Rb_1$ and $Rb_2$) was highest in Method B. There was no consistent tendency in Brix, pH, Hue value and absorbance among extraction methods.

Dilute Acid Pretreatment for Conversion the Agricultural Residue into Bioenergy (농산부산물의 바이오에너지 전환을 위한 묽은산 전처리)

  • Won, Kyung-Yoen;Jeong, Tae-Su;Choi, Won-Il;Oh, Kyeong-Keun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.511-511
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    • 2009
  • Lignocellulosic biomass is the most abundant organic material on earth and also promising raw material for bioenergy production. Agricultural residues in the process of bio-oil extraction, is an abundant and low-cost lignocellulosic material. The technology for conversion of lignocellulosic biomass resources to fuels and chemicals, such as ethanol, has been under development for decades. One of the well-studied technologies that are currently being commercialized is to use a dilute acid-catalyzed pretreatment followed by enzymatic hydrolysis and fermentation to produce ethanol. In this work, the dilute-acid hydrolysis of agricultural residues was optimized through the utilization of statistical experimental design. Evaluation criteria for optimization of the pretreatment conditions were based on high xylose recovery and low inhibitor contents in the hydrolyzates. The purpose of this study was to gain a more accurate understanding of the quantities of acid required for effective hydrolysis and the reactivity trade-offs with reaction time and temperature that will enable overall process optimization.

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Simultaneous detection method for pesticide residues in meat by gas chromatograph-mass selective detector (Gas chromatograph-mass selective detector를 이용한 식육 중 잔류농약의 동시분석)

  • Hong In-Suk;Choi Yoon-Hwa;Kweon Taek-Boo;Lee Jung-Hark
    • Korean Journal of Veterinary Service
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    • v.28 no.3
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    • pp.285-294
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    • 2005
  • This study was conducted to investigate the extraction method for the determination of organochlorine, organophosphorus and synthetic pyrethroid pesticide residues in beef fat by gas chromatography-mass selective detector(GC-MSD). Twenty one pesticide residues in fat were determined using a simple and rapid procedure based on solid- phase extraction(SPE) clean-up cartridges with octadecyl $(C_{18})-bonded$ porous silica, florisil, $10\%$ deactivated florisil. a tandem $C_{18}$ and florisil and a tandem $C_{18}$ and $10\%$ deactivated florisil. Solvent-solvent extraction using acetonitrile was not satisfied to eliminate fat interference for pesticide residue analysis by GC-MSD, and the recoveries of the method in fat ranged from 16.2 to $57.3\%$ except DDT$(83.2\%)$. The recoveries of SPE methods using a tandem $C_{18}$ and Florisil was $59.6\~123.8\%$ except fenitrothion $(135.2\%)$. the SPE method was verified the satisfactory performance of pre-treatment for pesticide residues analysis in fat by GC-MSD. The efficiency of florisil deactivated with $10\%$ water has been not proved significantly on recoveries of pesticide residues in fat.

Utilization of Ligno-cellulosic Biomass(III)-Acid Hydrolysis of Exploded Wood after Delignification (목질계 바이오매스의 이용(제3보)-탈리그닌 처리한 폭쇄재의 산가수분해-)

  • 양재경;장준복;임부국;이종윤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.18-27
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    • 1997
  • This study was performed to obtained the optimal delignified condition of exploded wood on the acid hydrolysis with sulfuric acid. Wood chips of pine wood(Pinus desiflora), oak wood(Quercus serrata) and birch wood (Betula platyphylla var. japonica) were treated with a high pressure steam (20-30kgf/$\textrm{cm}^2$, 2-6 minutes). The exploded wood was delignified with sodium hydroxide and sodium chlorite, and then hydrolyzed with sulfuric acid. The result can be summerized as follows ; In the exploded wood treated with sodium hydroxide, the optimal concentration of sodium hydroxide was 1% as content of lignin in the exploded wood. Lignin content of exploded wood treated with sodium chlorite was lower then that sodium hydroxide. The maximum reducing sugar yield of exploded wood treated with 1% sodium hydroxide was lower than non-treated exploded wood. In the case of sodium chlorite treated, the maximum reducing sugar yield was hgher than non-treated exploded wood. Sugar composition of acid hydrolysis solution was composed of xylose and glucose residue, and the rate of glucose residue was increased in high pressure condition.

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Development of the Sample Pretreatment Technique using Microwave for Analysis of Insecticide Imidacloprid Residues (마이크로파를 이용한 잔류 살충제 Imidacloprid 분석용 시료전처리 기술개발)

  • Ahn, S.Y.;Cho, H.K.;Lee, E.Y.
    • Journal of Biosystems Engineering
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    • v.32 no.2 s.121
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    • pp.121-129
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    • 2007
  • This study was conducted to elucidate extraction efficiency by microwave technique in comparison with sonication technique for extraction of insecticide residue in pear. In the analysis of the extraction efficiency of microwave for a pear spiked with imidacloprid, the extraction efficiency by microwave power of 300 W with extraction temperature of $80^{\circ}C$, heating time of 1 to 3 minute was shown to be similar with the extraction time 20 minutes by sonication. The optimal condition. in consideration of economical condition and treatment time, for microwave extraction of imidacloprid in the pear were 300 watts of power supply, $100^{\circ}C$ of extraction temperature, 1 minute of heating time and 10 mL of acetone volume. A new microwave vessel was developed to rapidly process the sample of the insecticide imidacloprid residues in the pear. This vessel was designed to include a reaction chamber and a filtration equipment, and a gathering chamber. The system could curtail a pretreatment time to 21 minutes than sonication and 7.9 minutes than the previous microwave vessel.

Structural Basis of Functional Conversion of a Floral Repressor to an Activator: A Molecular Dynamics Simulation Study

  • Kang, Suk-Ki;Lee, Ju-Yong;Lee, Myeong-Sup;Seok, Cha-Ok
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.408-412
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    • 2008
  • FLOWERING LOCUS T (FT) and TERMINAL FLOWER 1 (TFL1) in Arabidopsis are homologous proteins that perform opposite functions: FT is an activator of flowering, and TFL1 is a repressor. It was shown before that change of a single amino acid (His88) of TFL1 to the corresponding amino acid (Tyr) of FT is enough to convert the floral repressor to an activator. However, structural basis of the functional conversion has not been understood. In our molecular dynamics simulations on modified TFL1 proteins, a hydrogen bond present in native TFL1 between the His88 residue and a residue (Asp144) in a neighboring external loop became broken by change of His88 to Tyr. This breakage induced conformational change of the external loop whose structure was previously reported to be another key functional determinant. These findings reveal that the two important factors determining the functional specificities of the floral regulators, the key amino acid (His88) and the external loop, are correlated, and the key amino acid determines the functional specificity indirectly by affecting the conformation of the external loop.