• Title/Summary/Keyword: residual reduction

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Synthesis and kinetic of ultrafine titanium carbide particles by Mg-thermal reduction of liquid metal chlorides (마그네슘의 금속염 환원에 의한 초미립 탄화티탄 분말 합성거동)

  • 이동원;백진호;김병기
    • Journal of Powder Materials
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    • v.11 no.4
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    • pp.322-327
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    • 2004
  • Ultrafine titanium carbide particles were synthesized by the reaction of liquid-magnesium and vaporized TiCl$_{4}$+C$_{x}$Cl$_{4}$(x = 1 and 2) solution. Fine titanium carbide particles with about 50 nm were successfully produced by combining Ti and C atoms released by chloride reduction of magnesium, and vacuum was then used to remove the residual phases of MgCl$_{2}$ and excess Mg. Small amounts of impurities such as O, Fe, Mg and Cl were detected in the product, but such problem can be solved by more precise process control. The lattice parameter of the product was 0.43267 nm, near the standard value. With respect to the reaction kinetics, the activation energy for the reactions of TiCl$_{4}$+C$_{2}$Cl$_{4}$and Mg was found to 69 kJ/mole, which was about half value against the use of TiCl$_{4}$+CCl$_{4}$, and such higher reactivity of the former contributed to increase the stoichiometry until the level of TiC$_{0.96}$ and decrease the free carbon content below 0.3 wt.%.

A Study on Balanced-Type Oscillating Mole Drainer (II) (Model Test For Vibration) (평형식진동탄환암거천공기의 연구(II) -모수실험 : 진동에 대하여-)

  • 김용환
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.17 no.4
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    • pp.3962-3969
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    • 1975
  • 1. When the frame of the experimental apparatus was directly fixed on the platform, result from the spectrum density analysis showed that the generated vibration frequecy of the system was nearly-same as the system's own characteristic vibration frequency, 80Hz, in the case of the forcing vibration frequency was 7.5 to 22.5Hz. The reduction ratio of acceleration by balanced type model compare to non-balanced type one was 26.66 percent. 2. When the frame of experimental apparatus was fixed on the platform with putting a shock absorbing rubber between the frame and the platform, the generated vibration frequency of the system was same as forcing vibration frequency. When either frequency or the amplitude of the forcing vibration was increased, the acceleration ratio was increased too. The average reduction ratio was resulted 44.77 per cent. It was concluded that this method of acceleration measurement(the method using a shock absorbing rubber) was a reaonable method, because actual machine will work under such condition. As the vibration frequency and aptitude were increased, the absolute magnitude of acceleration was increased. 3. unbalanced rotating parts, and unbalanced moment of inertia of links were supposed to be causing factors of residual vibration in spite of using the balanced type oscillating mole drainer. This fact suggested that the attachment of the counter weight on the rotating parts which satisfy the condition mw$.$rw=m0e, was necessary. And also, it was expected that the shock absorbing effect could be improved by putting the shock absorbing materials between the moving parts and their supports.

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Room Temperature Preparation of Electrolytic Silicon Thin Film as an Anode in Rechargeable Lithium Battery (실리콘 상온 전해 도금 박막 제조 및 전기화학적 특성 평가)

  • Kim, Eun-Ji;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.8-15
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    • 2012
  • Silicon-based thin film was prepared at room temperature by an electrochemical deposition method and a feasibility study was conducted for its use as an anode material in a rechargeable lithium battery. The growth of the electrodeposits was mainly concentrated on the surface defects of the Cu substrate while that growth was trivial on the defect-free surface region. Intentional formation of random defects on the substrate by chemical etching led to uniform formation of deposits throughout the surface. The morphology of the electrodeposits reflected first the roughened surface of the substrate, but it became flattened as the deposition time increased, due primarily to the concentration of reduction current on the convex region of the deposits. The electrodeposits proved to be amorphous and to contain chlorine and carbon, together with silicon, indicating that the electrolyte is captured in the deposits during the fabrication process. The silicon in the deposits readily reacted with lithium, but thick deposits resulted in significant reaction overvoltage. The charge efficiency of oxidation (lithiation) to reduction (delithiation) was higher in the relatively thick deposit. This abnormal behavior needs to clarified in view of the thickness dependence of the internal residual stress and the relaxation tendency of the reaction-induced stress due to the porous structure of the deposits and the deposit components other than silicon.

Cooking Behavior for the Reduction of Food Wastes (음식물 쓰레기 감량을 위한 조리행동에 관한 연구)

  • 김동희
    • Korean journal of food and cookery science
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    • v.14 no.2
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    • pp.159-167
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    • 1998
  • The purpose of this study was to investigate the cooking behavior of housewives in Seoul to reduce the food wastes. The obtained datas from the questionnaires were analyzed by SPSS program. Among the respondents 60.8% were 40 to 49 years old, and 50.l% had high school education background. Sixtyfive % had 3∼4 family members and 83.9% lived with their husbands and children. The income of 25.0% of the respondents was 1.5 to 2 million wens monthly Their housing environment showed that 37.7% of housing were private houses and 92.0% of kitchen were a stand-up type. Most respondents shopped at a supermarket (64.5%), and they expressed greate, concerns on the date of food production (58.4%) than its wastes (6.0%). Sixtyfour point nine% of the respondents prepared a kuk and chigae every meal and 46.2% of them prepared two meals at a time. Twentytwo point two% of the respondents ate all the kuk or chigae. The residual foods were kuk or chigae (47.6%), side dishes (42.3%), and main dishes (4.9%). Fortyfive point six% of the respondents believed that the improvement of eating habits needed for the reduction of food wastes.

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Static test on failure process of tubular T-joints with initial fatigue crack

  • Wang, Yamin;Shao, Yongbo;Song, Shengzhi;Yang, Dongping
    • Steel and Composite Structures
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    • v.24 no.5
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    • pp.615-633
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    • 2017
  • Fatigue crack initiated in welded tubular joints due to cyclic loading may produce harmful effect on the integrity of the tubular structures. To study such effect, both fatigue and static tests on nine circular tubular T-joint specimens made of carbon steel materials were carried out. The specimens were subjected to tensile loading in both fatigue and static tests. The load-displacement relation, the crack propagation and the failure mode of the specimens are all analyzed. The deterioration of the static strength of the cracked T-joints is also investigated and evaluated through an area reduction factor. Experimental results indicate that the static strength of a tubular T-joint with a surface crack seems to decrease slightly while a through crack has relatively remarkable effect on the reduction of the static strength. Additionally, experimental results also show that the toughness of the materials and the geometry of the specimens play an important role on the failure process of cracked tubular T-joints.

Development of Electrical Steel by Laser Magnetic Domain Refinement for Applying to Transformers of High Energy Efficiency (고효율 변압기용 레이저자구 전기강판 개발)

  • Kwon, Oh-Yeoul;Cha, Sang-Yun;Ha, Kyung-Ho;Kim, Ji-Hyun;Kim, Jae-Kwan
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.625-626
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    • 2008
  • The magnetic domain-refining techniques such as ball scratching, laser irradiation and plasma have been developed to reduce the domain wall spacing and thus iron losses in Fe-3%Si grain-oriented silicon steels. In view point of magnetic properties, it was supposed that the locally residual stresses change the magnetoelastic energy of the material and thus the spacing between $180^{\circ}$ domain walls decreases in order to reduce the magnetostatic energy. The effect of laser irradiation on iron loss and magnetostriction reduction for Fe-3%Si grain-oriented steel were investigated. Since the local tensile stresses were induced at the surface of Fe-3%Si steel by the laser irradiation, the minimum iron loss caused by reducing eddy current loss was obtained in spiete of the decrease of permeability by hindering eddy current loss was obtained in spite of the decrease of permeability by hindering the domain wall movement around the induced stress field. Furthermore, the laser treated 3%Si steel has lower magnetostriction as compared to non laser-treated steel and is less sensitive to applying pre-stresses due to the volume reduction of $90^{\circ}$ domain in materials.

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Arthroscopic Assisted Reduction and Internal Fixation of Lateral Femoral Epiphyseal Injury in Old Adolescent Soccer Player - Report of 1 Case - (청소년기 축구선수에서 원위 대퇴외과 성장판 손상의 관절경하 정복 및 내고정 - 1례 보고-)

  • Lee, Yong-Seuk;Jung, Jae-Kyoung;Kong, Chae-Kwan;Shin, Yoon-Chang
    • Journal of Korean Orthopaedic Sports Medicine
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    • v.6 no.1
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    • pp.66-69
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    • 2007
  • Sports-related knee injuries frequently occur in adolescent period and fractures are more common than ligamentous Injuries in this age group because of physiologic characteristics. We operated an adolescent soccer player with lateral femoral epiphyseal injury using arthroscopic assisted reduction and infernal fixation. In $2^{nd}$ look arthroscopy and metal removal at postoperative 2 years, articular cartilage was healed with good congruity and lower extremity entire long film showed normal axial alignment without residual deformity.

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Floor Impact Noise Reduction Performance of Double-Floor System in Apartments (공동주택 이중바닥구조의 바닥충격음 저감성능)

  • Baek, Gil-Ok;Park, Hong-Gun;Mun, Dae-Ho
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.197-202
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    • 2014
  • Floor Impact Noise is a structure-borne noise which is mainly caused by vibration of concrete slabs. The majority of previous studies have focused on investigating performance of absorbing sheets on the reduction of floor impact noise. But absorbing sheets do not efficiently reduce heavy-weight floor impact noise level because it cannot absorb slab vibration, which is the fundamental noise source. In this study, double-floor system was developed in order to reduce floor impact noise level in residual buildings. This floor system reduces heavy-weight impact noise level by reducing vibration response at the center of slab, which has maximum amplitude in the 1st vibration mode. In order to identify the performance of the double-floor system, experiments were planned. Primary test parameters are span of double floor, arrangement and types of absorbing sheets.

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Magnetic Properties of Fe Powder Core Fabricated by Warm Compaction (온간성형법으로 제조된 Fe 분말 코어의 자성특성)

  • Kim, Se-Hoon;Jo, Tae-Sun;Park, Min-Suh;Kim, Young-Do
    • Journal of Powder Materials
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    • v.14 no.5
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    • pp.298-302
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    • 2007
  • In recent years, a rapid increase in demands for the soft magnetic composite parts has been created and it has been tried to improve their properties by various processing methods, alloying elements and compaction parameters. Warm compaction method has been used for the reduction of residual stress, the improvement of magnetic properties and the higher densities. In this work, the effects of warm compaction and polymer binder on magnetic properties of Fe powder core were investigated. The sintering powder, Fe oxide, was ball-milled for 30n hours. And then ball-milled Fe oxide powder was reduced through hydrogen reduction process. The hydrogen reduced Fe powder and polymer binder were mixed by 3-D turbular mixer. And then the mixed powder was warm-compacted. The magnetic properties such as core loss and permeability were measured by B-H curve analyzer.

Fabrication and Mechanical Properties of TiNi/Al2024 Composites by Hot-Press Method (고온 프레스법에 의한 TiNi/Al2024 복합재료의 제조 및 기계적 특성평가)

  • Son, Yong-Kyu;Bae, Dong-Su;Park, Young-Chul;Lee, Gyu-Chang
    • Transactions of Materials Processing
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    • v.18 no.1
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    • pp.45-51
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    • 2009
  • Shape memory alloy has been used to improve the tensile strength of composite by the occurrence of compressive residual stress in matrix using its shape memory effect. In order to fabricate shape memory alloy composite, TiNi alloy fiber and Al2024 sheets were used as reinforcing material and matrix, respectively. In this study, TiNi/Al2024 shape memory alloy composite was made by using hot press method. In order to investigate bonding condition between TiNi reinforcement and Al matrix, the micro-structure of interface was observed by using optical microscope and diffusion layer of interface was measured by using Electron Probe Micro Analyser. And the mechanical properties of composite with three parameters(volume fraction of fiber, cold rolling amount and test temperature) were obtained by tensile test. The most optimum bonding condition for fabrication the TiNi/Al2024 composite material was obtained as holding for 30min. under the pressure of 60MPa at 793K. The strength of composite material increased considerably with the volume fraction of fiber up to 7.0%. And the tensile strength of this composite increased with the reduction ratio and it also depends on the volume fraction of fiber.