• Journal of the Korean Ceramic Society
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• v.48 no.3
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• pp.228-235
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• 2011

Sintering behavior and lightweight characteristics of porcelain by addition of FAHM (Fly-Ash Hollow Microsphere) were evaluated. Green body of Backja composition (general porcelain) in which FAHM was added(15 and 20 wt%) was made by slip casting method. The green body was sintered at 1270 and $1290^{\circ}C$ and maintained for 1h. The bulk density and linear shrinkage of the sintered body with FAHM (20 wt%) decreased. As the contents of FAHM. increased, mullite and cristobalite phases increased. In the microstructure, FAHM shells remained after sintering, and the generation of mullite fibers around FAHM shells also were confirmed. the weight of porcelain with of 20% FAHM decreased by 40% and residual FAHM shells promoted the mullite of generation in the matrix.

• Journal of Hydrogen and New Energy
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• v.10 no.2
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• pp.101-106
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• 1999

Hydrogen solubility in internally oxidized Pd-Mo(Al) alloys has been studied at 323 K from the measurements of pressure-composition(p-c) isotherms. Internal oxidation of $Pd_{0.985}Al_{0.015}$ and $Pd_{0.97}Mo_{0.03}$ alloys results in the precipitation of Al and Mo particles in a matrix of pure Pd. It has been observed that the presence of the aluminum and molybdenum oxide precipitates results in an enhanced hydrogen solubility in the dilute phase region of Pd-H in a Pd/aluminum(molybdenum)oxide composites. Hydrogen solubility enhancements due to the presence of residual stresses around ceramic particles have been observed from p-c isotherms determined at 323 K after oxidation at 1073 K. The solubility enhancements in completely internally oxidized alloys are greater than that in partially oxidized alloys. The stress fields near the ceramic precipitates are the major source of the solubility enhancements. Transmission electron microscopy indicates that alumina precipitates are nanometer-sized and coherent with the Pd matrix after oxidation.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.2053-2058
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• 2004

The pressurized light water cooled, medium power (330 MWt) SMART (System-integrated Modular Advanced ReacTor) has been under development at KAERI for a dual purpose : seawater desalination and electricity generation. The SMART design verification phase was followed to conduct various separate effects tests and comprehensive integral effect tests. The high temperature / high pressure thermal-hydraulic test facility, VISTA(Experimental Verification by Integral Simulation of Transient and Accidents) has been constructed to simulate the SMART-P (the one fifth scaled pilot plant) by KAERI. Experimental tests have been performed to investigate the thermal-hydraulic dynamic characteristics of the primary and the secondary systems. Heat transfer characteristics and natural circulation performance of the PRHRS (Passive Residual Heat Removal System) of SMART-P were also investigated using the VISTA facility. The coolant flows steadily in the natural circulation loop which is composed of the steam generator (SG) primary side, the secondary system, and the PRHRS. The heat transfers through the PRHRS heat exchanger and ECT are sufficient enough to enable the natural circulation of the coolant.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.42 no.10 s.340
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• pp.19-28
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• 2005

In this paper, we analyzed tuning characteristics of the widely tunable SGDFB laser diode integrated with SGDBR. The improved time-domain model is used to analyse the laser diode. From the numerical analysis, the length of phase control region in the SGDFB section influences on the output power and the tuning range. Also, it was confirmed that the tuning range is affected by the length of the laser diode, the residual reflectivity at the facet, and the position of the facet.

• Aerospace Engineering and Technology
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• v.12 no.1
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• pp.189-199
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• 2013

This paper summarizes results of second stage attitude control of KSLV-I third flight test. The results show that three axes attitude control at coasting phases of KSLV-I was successfully accomplished by the reaction control system, and pitch and yaw attitude control at thrusting phase where second stage kick motor burns was also normally accomplished by using the thrust vector control system. It is verified that the second stage controller performed successfully for all flight phases regardless of some disturbances due to mass center offset, slag effects, and residual thrust of kick motor. These results may provide an important basis in enhancing domestic technology level of attitude control of launch vehicle.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.368-375
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• 2000

Fracture toughness of particulate composites of Al2O3/SiC, Al2O3/ZrO2 and Al2O3/ZrO2/SiC was analysed theoretically. According to the suggested particle bridging model for obtaining the R-curve height, the crack extension resistance for the long crack was linearly proportional to the residual calmping stress at the interface between the second phase and the matrix. It was also a function of the particle size and the content. It was confirmed that the rising R-curve behavior of Al2O3 containing 30 vol% SiC particles of 3${\mu}{\textrm}{m}$ was owing to the strong crack bridging by SiC particles. For Al2O3/ZrO2/SiC composites, the tensional stress from the 3${\mu}{\textrm}{m}$ SiC particles was large enough to activate the spontaneous transformation of the ZrO2. The crack extension resistance due to the particle bridging mechanism did not seem to be affected much by the coupled toughening, but its resultant toughness increase could be significantly smaller due to the dependency on the matrix toughness.

• Bulletin of the Korean Chemical Society
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• v.22 no.1
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• pp.68-76
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• 2001

We have employed chemical modification to identify amino acids essential for the catalytic activity of alliinase (EC 4.4.1.4) from garlic (Allium sativum). Alliinase degrades S-alkyl-L cysteine sulfoxides, causing the characteristic odor of garlic. The activity of alliinase was rapidly and completely inactivated by N-bromosuccinimide(NBS) and slightly decreased by succinic anhydride and N-acetylimidazole. These results indicate that tryptophanyl, lysyl, and tyrosyl residues play an important role in enzyme catalysis. The reaction of alliinase with NBA yielded a characteristic decrease in both the absorbance at 280 nm and the intrinsic fluorescence at 332 nm with increasing reagent concentration of NBS, consistent with the oxidation of tryptophan residues. Kinetic analysis, fluorometric titration of tryptophans and correlation to residual alliinase activity showed that modification of only one residue present on alliinase led to complete inhibition of alliinase activity. To identify this essential tryptophan residue, we employed chemical modification by NBS in the presence and absence of the protecting substrate analogue, S-ethyl-L-cysteine (SEC) and N-terminal sequence analysis of peptide fragment isolated by reverse phase-HPLC. A fragment containing residues 179-188 was isolated. We conclude that Trp182 is essential for alliinase activity.

• Elastomers and Composites
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• v.54 no.2
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• pp.97-104
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• 2019

Emulsion styrene-butadiene rubber silica wet masterbatch (ESBR silica WMB) technology was studied to develop highly filled and highly dispersed silica compounds, involving the preparation of a composite by co-coagulating the modified silica and the rubber latex in a liquid phase. Previous studies have shown that when manufacturing ESBR silica WMB/Butadiene silica dry masterbatch (BR silica DMB) blend compounds, preparing BR silica dry masterbatch and mixing it with ESBR silica WMB gave excellent results. However, WMB still has the problem of lower crosslink density due to residual surfactants. Therefore, in this study, tetrabenzylthiuram disulfide (TBzTD) was added instead of diphenyl guanidine (DPG) in the ESBR silica WMB/BR silica DMB blend compounds and sulfur/CBS contents were increased to evaluate their cure characteristics, crosslink densities, mechanical properties, and dynamic viscoelastic properties. TBzTD was found to be more effective in increasing the crosslink density and to produce superior properties compared to DPG. In addition, with increasing sulfur/CBS contents, mechanical properties and rolling resistance were enhanced due to high crosslink density, but the abrasion resistance was not significantly changed because of the toughness.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.466-474
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• 2021

A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.1
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• pp.56-62
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• 2024

By introducing curing kinetics and chemo-rheology for the epoxy resin formulation for ultra-high voltage gas insulated switchgear (GIS) Insulating Spacers, a study was conducted to simulate the curing behavior, flow and warpage analysis for optimization of the molding process in automatic pressure gelation. The curing rate equation and chemo-rheology equation were set as fixed values for various factors and other physical property values, and the APG molding process conditions were entered into the Moldflow software to perform optimization numerical simulations of the three-phase insulating spacer. Changes in curing shrinkage according to pack pressure were observed under the optimized process conditions. As a result, it was confirmed that the residence time in the solid state was shortened due to the lowest curing reaction when the curing holding pressure was 3 bar, and the occurrence of deformation due to internal residual stress was minimized.