• 한국산업보건학회지
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• 제31권2호
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• pp.173-183
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• 2021

Objectives: This study evaluated the skin permeability of lawsone in henna hair dyes to understand the exposure characteristics of henna hair dyes in the human body. It examined the protective effects of protectants by applying protectants A, B, and C to test skin. Methods: Skin absorption tests were conducted using Franz diffusion cells according to OECD test guideline 428. After applying one kind of natural henna hair dye and chemical henna hair dye, respectively, to a standardized pig skin model, samples of receptor fluid were collected at 1h, 3h, 6h, and 24h. The skin permeation of lawsone was determined using HPLC. After the skin absorption experiment, the skin to which hair dye was applied was analyzed to determine the residual amount of lawsone in the skin. Results: The cumulative permeation of both natural and chemical henna hair dyes increased over time, and the natural henna hair dye had a flux value (t=3.194, p<.05) high both in the K_p value (t=3.207, p<.05) and the residual amount (t=22.701, p<.001). For skin treated with a protectant, the cumulative permeation of natural henna hair dye 24h control and the cumulative permeation of protectant A, B, and C increased over time. Flux and K_p values were in the order control > protectant A > protectant C > protectant B. The residual amount (F=4.469, p<.05) was in the order of protectant C > protectant A > protectant B > control. At 3h, the dye application time of natural henna hair dye, the lawsone flux value (F=4.454, p<.05) and K_p value (F=4.455, p<.05) were higher in the control group than in the protectant groups. The 24h cumulative permeation of the chemical henna hair dye increased with time in both the control and the protectant groups, and the flux and K_p values were in the order of protectant A > protectant C > protectant B > control. The residual amount (F=7.901, p<.01) was in the order of protectant B > protectant A> protectant C > control. Conclusions: Within the normal dyeing time for henna hair dye (three hours for natural henna hair dyes and 30 minutes for chemical henna hair dyes) lawsone skin penetration was not observed even when no protective agent was applied. After that time, however, evidence of skin penetration and retention of lawsone and the protective effect of protective agents were observed.

• 한국염색가공학회지
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• 제34권2호
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• pp.93-101
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• 2022

In this study, the dyeing properties of supercritical fluid dyed cotton fabrics were investigated which use two types of dyes, such as C.I. Disperse orange and C.I. Disperse red 167. Dyeing temperature, pressure and leveling time were equally applied at 130 ℃, 250 bar, and 60 minutes with reference to the related literature, and experiments were performed at concentrations of 0.04, 0.1, 0.4 and 0.8 % o.w.f with different concentrations. Dyeability was confirmed through measurement of washing fastness and color coordinate, and a calibration curve of each dye was drawn up and the absorbance of the residual dye was measured to confirm the amount of residual dye and the dye exhaustion rate at the corresponding concentration. As a result of color difference measurement, as the concentration increased, the L^* value decreased and the K/S value increased. However, as the concentration increased, the increase in K/S value decreased compared to the input amount, and this tendency was more obvious in C.I. Disperse red 167 than in C.I. Disperse orange 155. The dye exhaustion rate which was calculated by using the amount of residual dye in the pot was also C.I. Disperse orange 155 was 96.16 % and C.I. Disperse red 167 was 94.57 %. However, as the dyeing concentration increased, the dye exhaustion rate decreased, that C.I. Disperse orange was 95.33 % and C.I. Disperse red 167 was 90.63 %. As a result of the washing fastness test for both dyes, dyed samples of which concentrations were 0.4 and 0.8 % o.w.f decreased by 0.5 ~ 1.0 grade. This is predicted because the dye did not completely adhere to the amorphous region of the cotton fiber and the dye simply adsorbed. The fastness to rubbing also maintained at least grade 3-4 up to the 0.1 % o.w.f concentration, but at the concentration of 0.4 % o.w.f or higher, it fell to grade 1 or lower, showing a very poor friction fastness.

• 한국염색가공학회지
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• 제33권1호
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• pp.31-39
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• 2021

In this study, the dyeing properties of supercritical fluid dyed nylon fabrics were investigated which use two types of dyes for dyeing nylon. For other dyeing conditions were referred to related literature, and dyeing was performed with different dyeing concentrations. Dyeability was confirmed through measurement of washing fastness and color coordinate, and a calibration curve of each dye was drawn up and the absorbance of the residual dye was measured to confirm the amount of residual dye and the dye exhaustion rate at the corresponding concentration. As a result of color difference measurement, the color intensity increased as the concentration increased, but the increase was insignificant at high concentration. This tendency was more obvious in C.I. Disperse Orange 155 than in C.I. Disperse Yellow 42. The dye absorption rate also decreases as the concentration increases, but at 0.85% o.w.f concentration, C.I. Disperse Yellow 42 was 97.29% and C.I. Disperse Orange 155 was 93.77%. For both dyes, the wash fastness dropped by 0.5 to 1 class from the sample that was dyed at a concentration of 0.5% o.w.f in the wash fastness test.

• 한국염색가공학회지
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• 제32권4호
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• pp.217-225
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• 2020

In this study, the dyeing characteristics of nylon fabric which is dyed with supercritical fluid were investigated. There were two dyes used in the dyeing experiment: C.I. Disperse Red 167 and C.I. Disperse Violet 93. Dyeing temperature, pressure, and leveling time were fixed at 110℃, 250bar, 60minutes, and the experiment was conducted with dyeing concentration of 0.1, 0.3, 0.5, and 0.85% o.w.f. The analysis of the experimental results was found out through the measurement of washing fastness and color coordinate. In addition, the calibration curve of each dye was drawn up and the amount of remaining dye was checked by measuring the absorbance of the residual dye. As a result of color difference measurement, as the concentration increased, the L⁎ value decreased and the K/S value increased. However, the increase in K/S value compared to the amount of input decreased as the concentration increased. The comparative experiment on the amount of residual dye(C.I. Disperse Red 167) in the pot showed that 99.14% of the amount was dyed at the concentration of 0.1% o.w.f, while it rapidly decreased to 77% at 0.85% o.w.f. C.I. Disperse Violet 93 dye also decreased from 0.5% o.w.f to 93.91%. In the washing fastness experiment of both dyes, the level of washing fastness began to decrease from samples dyed at 0.5% o.w.f. It may be because the simply absorbed dye was produced instead of completely being fixed in the amorphous region of the nylon fiber.

• Membrane and Water Treatment
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• 제7권6호
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• pp.477-493
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• 2016

Immediate use of activated carbon incorporated polysulfone membrane application for dye separation was reported in this work. Dimethylformamide (DMF) was used as the solvent for the membrane preparation. The membrane thus prepared were characterized in terms of surface morphology, ATR-FTIR, AFM, experimental results as membrane performance. The resultant nanofiltration (NF) membranes were tested with Congo red dye concentration 200 mg/L. The water permeability was found to be considerably higher than that reported in literature. Experimental results show that the real rejection of the Congo red is 99.57% over the transmembrane pressure 100 psi using 30% activated carbon incorporated membrane. Prepared NF membranes shows the corresponding permeates fluxes were $40Lm^{-2}h^{-1}$ to $82Lm^{-2}h^{-1}$ with different activated carbon percentage incorporated in polysulfone membrane. The present study demonstrated that dye rejection enhanced NF may be a feasible method for the dye wastewater treatment. The overall observations thus indicated that toxic residual dyes can be appreciably separated from the membrane technology, provided that the accompanying polymeric membrane, activated carbon as binding agents and the process parameter levels are astutely selected.

• 한국물환경학회지
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• 제23권1호
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• pp.27-32
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• 2007

This study focused on estimating the feasibility of a strong basic anion exchanger (PA312OH) as a sorbent for the removal of residual reactive dye and saving chemicals and water. Cellulose reactive dye C.I.RB49 was tested because reactive dye is the largest single group of dyes and that dye needs larger amount of inorganic salts as dyeing agent but nearly 50% of reactive dyes may be lost to the effluent. The adsorption characteristics of PA312OH for C.I.RB49 were as follows. Ion-selectivity among the dye and inorganic salts was Dye > ${SO_4}^{2-}$ > ${CO_3}^{2-}$ > $Cl^-$. C.I.RB49 was exchanged more than 3 times ${SO_4}^{2-}$ and ${CO_3}^{2-}$ and $Cl^-$ was not exchanged absolutely. The exchanging velocity was increased exponentially with increasing temperature. This result is positive effect on treating the high temperature dyeing process wastewater. The exchanged dye percents to initial were 96.8% and 99% at flow rate 20.5 mL/min. and 3.7 mL/min.. The exchanging capacity of PA312OH for C.I.RB49 was 215.2 mg/g at conc.=369.2 mg/L, Temp.=$25^{\circ}C$. 74% inorganic salts were recrystallized from real dark reactive color dyeing wastewater treated with PA312OH.

• 한국염색가공학회지
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• 제4권2호
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• pp.76-83
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• 1992

Wool tropical and nylon taffeta were treated with low temperature plasma of $O_2$, $N_2$, NH$_3$, CF$_4$ and CH$_4$ for the intervals of 10 to 300 sec, and then dyed with leveling and milling type acid dyes in presence or absence of buffer solution. From the color depth of dyed fabrics, effect of plasma gases, treated time, dyeing time and temperature on dyeing property was studied. The results of the experiment can be summarized as follows: 1) The plasma treatments except methane gas increased the color depth of dyed wool fabrics, but not that of dyed nylon fabrics regardless of the plasma gases used. 2) The color depth of wool fabrics dyed in the dye bath without buffer solution was increased by the low temperature plasma, especially increased much more by CF$_4$ plasma treatment. It is found that with the identification of F- ion in the residual dye bath the hydrogen fluoride gas was adsorbed on wool fabrics in the plasma treatment. 3) The color depth of wool fabrics was increased with the time of $O_2$ and CF$_4$ plasma treatments. 4) In both cases of the leveling and milling type acid dyes, the rate of dyeing was increased in the low temperature plasma treatments, and it is found that the leveling type acid dye increased the color depth at relatively low temperature below 4$0^{\circ}C$, compared with the milling type acid dye.

• The International Journal of Costume Culture
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• 제7권1호
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• pp.40-47
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• 2004

The purpose of this research was to examine the degradation rate of alizarin in accelerated degradation conditions using the GC-MS quantitative analysis. Alizarin dye solution (2.5 x 10/sup -3/ M conc.) were kept in 150℃ oven for total of 7 days and the degradation rate was examined each day. 2.5 × 10/sup -4/M conc. alizarin dye solution was mixed with H₂O₂ according to [H₂O₂]/[dye] ratio 40 and were kept under 365㎚ UV for 2 hours, analyzed after 0, 30, 60, 90, 120min using the GC-MS. Gas chromatogram showed alizarin peak at 9.96 - 10.13 min. retention time range and residual peaks in the wide range from 9.6 to 11.1 min. Oven degradation exhibited an initial decrease in the amount of alizarin, which was followed by increasing amount in 4/sup th/ day. The decrease in the alizarin was significantly shown by the 7/sup th/ day. Same pattern was also observed in the H₂O₂/UV/O₂ degradation samples and was verified ed by the UV-VIS spectra. The differences in the amount of alizarin between 1/sup st/ day and 4/sup th/ day samples, 4/sup th/ day and 7/sup th/ day samples, and Control and 7/sup th/ day samples of the oven degradation were significant at alpha .20.

• 한국해양학회지
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• 제30권5호
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• pp.467-479
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• 1995

영일만의 해수유동구조 및 확산특성을 해석하기 위하여 만내 및 만외에서 25시간 연속축류, 표류판 추적, 염료 확산 실험 및 홍수시 형산강 유출수의 항공촬영 등의 체 계적인 해양관측을 실시하였다. 영일만 표층에서 해수유동은 조류보다는 바람과 해류 의 영향을 크게 받고, 중층에서는 해류에 의한 지배적인 영향을 받고 있다. 표층에서 향류는 주로 만의 서쪽해안과 중앙부를 통해 만 내로 유입하였다가 반시계 방향으로 회전하면서 만의 동쪽해안을 따라 만 외로 유출한다. 만의 동쪽해안에서 표층항류는 바람의 영향에 관계없이 만외로 유출하는 흐름인 북-북동방향의 흐름이 발생하고 있으 나, 만의 서쪽해안에서 표층 항류는 바람과 형산강 유출수의 영향을 크게 받는다. 즉, 남-서풍이 탁월하게 발생할 때 나 홍수니 형상강 유출량이 많을 경우 서쪽해안에서 표 층항류는 북-북동방향으로 흐른다. 중층에서 항류는 만의 서쪽해안을 따라 만내로 유 입하였다고 좌선회하면서 만의 동쪽해안을 따라 만외로 유출하는 흐름인 북동방향의 이름이 발생한다. 만의 중앙부에서 실시한 순간점원 방출에 의한 염료운의 확산양상은 표류판의 이동경로와 거의 일치하였으며, Fick의 이론에 의한 염료운의 겉보기 확산계 수는 1.14$\times$$10^4$$cm^2$/s이었다. 그리고, 홍수시 현산강의 유출수는 영일만의 서쪽해안 을 따라 띠모양을 이루면서 만외로 유출 확산되고 있다.

• 자원환경지질
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• 제37권4호
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• pp.383-389
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• 2004

지표 및 심토환경에서 물과 용액의 유동특성을 파악하는 것은 토양 및 지하수의 오염을 저감하고 방지하거나 기 오염 지역을 조사하고 정화하는데 있어서 필수적인 요소이다. 본 연구에서는 이 비형광, 비독성의 식용색소인 청색1호(Brilliant Blue FCF, $C_{37}H_{34}N_{2}Na_{2}O_{9}S_{3}$)를 염료 추적자로 이용하여 화강암에서 발달된 잔적토양에서의 침투 유형 및 그 특성을 조사하였다. 디지털 촬영된 수직 및 수평 착색영상은 지형정보 영상처리 프로그램인 ER Mapper, Version6.2를 이용하여 염료착색범위(dye coverage)로 전환되었다. 균질기반유동(homogeneous matrix flow)은 미약 입상 구조를 보이는 A 층위에서 발생하였으며, 상대적으로 세립조직인 A층위와 조립조직인 C층위의 경계에서는 선침투류(先浸透流, fingering)의 특징을 보여주었다. 모암인 화강암 조직의 기원인 거정질 광맥(pegmatitic vein)과 식물 뿌리는 C 층위에서 선택적 유동(preferential flow)을 유도하였음을 확인하였다.