• Title/Summary/Keyword: residual chlorine

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Studies on Pollution and Reduction of Synthetic Detergents by Tap Water Treatment (합성세제의 오염과 상수정수처리에 의한 그 제거효과에 관한 조사연구)

  • Kwon, Sook-Pyo;Chung, Yong;Sim, Kyl-Soon
    • YAKHAK HOEJI
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    • v.21 no.4
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    • pp.200-210
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    • 1977
  • This investigation was undertaken from February 1976 to September 1976. The detergents in municipal sewages from the Chung Kae Stream, Ahn Yang Stream, and Bong Won Stream were determined at 1.5ppm, 0.93ppm, and 3.36ppm in average respectively. The concentrations of detergents determined in the Han river were 0.013ppm of Kwang Na Ru, 0.11ppm of Duk Do, 0.370ppm of Bo Kwang Dong, and 0.285ppm of Ka Yang Dong basin respectively. And the potable waters of Sung Book Ku and Sung Dong Ku from Ku Eu water pumping station located up-stream of the Han river were less polluted at 0.045ppm and 0.037ppm in average. Young Deung Po Ku and Su Dae Moon Ku had been relatively polluted at 0.181ppm and 0.133ppm. The coagulant, alum [$Al_{2}(SO_{4})_{3}$] could eliminated the small amount of detergent by coagulation. The eliminated rates were about 13% by 5ppm and 22.7% by 20ppm of aluminum sulfate in sewage contained 10ppm of turbidity. The sand and the charcoal adsorbed some detergent as the following Langmuir's equations: For the charcoal, m/x=0.029.$\times$1/Ce-11.43 For the charcoal, m/x=2.705log1/Ce-5.46 Where m: amount of snad and active carbon used(g) x: amount of detergent adsorbed from liquid(g) Ce:concentration in the liquid at equilibrium(miles) The adsorption effect of sand would be neglected. In the low concentration of detergent solution, one gram of active carbon adsorbed 0.263g of detergent. It was determined that one gram of chlorine reduced 5.5g pf DBS om keeping up 0.2ppm of residual chlorine by disinfection process with chlorine compound.

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Efficacy of Chlorine for Reducing Bacterial Populations and Bacteriological Contamination on Carcass and Treatment Water at Different Stage of Poultry Processing (도계처리 단계별 도체와 처리수의 세균오염 및 염소처리 효과)

  • 이철현;변유성;황보원;조광제;강호조
    • Korean Journal of Veterinary Service
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    • v.20 no.2
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    • pp.169-175
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    • 1997
  • This study was carried out to assess the effect of the chlorine treatment into water for processing chicken products in each stage of slaughtering, with a special viewpoint related with reducing the viable number of microorganisms by which the water and the chicken body were contaminated. The mean bacterial number on chicken samples after picking process was log5.37$\pm$0.20~5.84$\pm$0.160CFU/$\textrm{cm}^2$. When assessed by standard plate count method, it was the higher one than any other processing stage in which eviscerating, pinning, packaging, and chilling was followed in order of the mean bacterial number. The coliform bacterial numbers on carcasses after sampling from different processing stages were log2.11$\pm$0.63~2.88$\pm$0.25MPN/$\textrm{cm}^2, which show almost similar numbers in each processing stage. But, after chilling process the number was decreased slightly. The bacterial counts in the water for scalding and chilling showed log3.43 $\pm$ 0.59~5.06$\pm$0.21 and log4.30$\pm$0.21~6.62$\pm$0.33CFU/$m\ell$, respectively. In the coliform counts for the water taken out from the 2nd chilling tank, the number was log1.97$\pm$0.35~2.91$\pm$0.22MPN/$m\ell$ which showed higher than those of the 1st and the 3rd chilling tank water. The effect of chlorination in reducing the bacterial numbers was accepted at the residual chlorine concentration of 1$m\ell$/$\ell$by showing the reduction from $10^8$ to $10^4$CFU level and the numbers were decreased less than 10CFU at the concentration of 5mg/$\ell$, when assessed by viable cell counts. In conclusion, these results suggested that chlorination In chilling water with final concentration of 5mg/$\ell$was strongly recommended to reduce the bacterial numbers on final chicken products.

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A Case Study on Chlorine Dioxide Usage at a Conventional Water Treatment Plant (기존 정수장 이산화염소 시범도입 사례연구)

  • Lee, Song-Hee;Lee, Byung-Doo;Kim, Jin-Keun;Seog, Kwon-Soo;Lee, Joung-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.115-119
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    • 2005
  • As the regulations on DBPs are tightened, many water treatment plants (WTPs) in Korea have already introduced or will introduce enhanced coagulation, alternative disinfectants and advanced treatments such as ozonization and granular activated carbon to improve drinking water qualify. After a phenol leakage accident at the Nakdong-River in 1991, 26 WIPs in Korea introduced carbon dioxide generators, but there has been no accumulation of significant operating data. This research summarizes things that should be considered for the introduction of carbon dioxide disinfection process to WTPs based on one year operation data from A WTP that has had high concentration of DBP during a specific period in the summer. The removal efficiency of DBP was $30{\sim}40%$, but those of 2-MIB, Geosmin were less than 10%. The generation rate of $ClO_2$ by-products such as chlorite and chlorate were $70{\sim}100%$ of input dosage, but the ratios increased over time. At the same time, strong chlorine odors may be produced in the distribution system when $ClO_2$ was used with $Cl_2$ as a result of reaction between the chlorite and residual chlorine.

Studies on Manufacture of Mineral Water with Wood Charcoals (목질탄화물을 이용한 미네랄수 제조에 관한 연구)

  • Shin, Soo-Jeong;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.460-466
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    • 2014
  • To evaluate wood charcoal as raw material for mineral water production, dissolution of inorganic ions from charcoal to water, pH and adsorption ability of chlorine in water were investigated as main variables. More potassium ion was dissolved in water as higher temperature manufactured charcoal but other ions showed no difference with different charcoal making temperatures. Highest dissolved cation was potassium followed by calcium and sodium. Among wood species, charcoal from Quercus variabilis and Platanus occidentalis showed significantly higher potassium content in water than that of larch, red pine and white pine. Other cations had similar pattern to the potassium but their difference was not apparent as much as potassium. pH value of water treated with charcoal was higher for wood charcoals from Platanus occidentalis (pH 8.5) and Quercus variabilis (pH 8.4) which contained higher inorganic cations. In chlorine removal in water by charcoal, all wood charcoals showed greater chlorine removal than that of the control, but softwood charcoals resulted in higher removal than those of hardwoods. There was no significant difference in the dissolution of cations and pHs between particle charcoal and whole charcoal. With easy of control, whole charcoal is better for mineral water making raw material than particle charcoal does.

Effect of Distribution System Materials and Water Quality on Heterotrophic Plate Counts and Biofilm Proliferation

  • CHANG , YOUNG-CHEOL;JUNG, KWEON
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1114-1119
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    • 2004
  • The biofilms on pipe walls in water distribution systems are of interest since they can lead to chlorine demand, coliform growth, pipe corrosion, and water taste and odor problems. As such, the study described in this paper is part of an AWWARF and Tampa Bay Water tailored collaboration project to determine the effect of blending different source waters on the water quality in various distribution systems. The project was based on 18 independent pilot distribution systems (PDS), each being fed by a different water blend (7 finished waters blended in different proportions). The source waters compared were groundwater, surface water, and brackish water, which were treated in a variety of pilot distribution systems, including reverse osmosis (RO) (desalination), both membrane and chemical softening, and ozonation-biological activated carbon (BAC), resulting in a total of 7 different finished waters. The observations from this study consistently demonstrated that unlined ductile iron was more heavily colonized by a biomass than galvanized steel, lined ductile iron, and PVC (in that order) and that the fixed biomass accumulation was more influenced by the nature of the supporting material than by the water quality (including the secondary residual levels). However, although the bulk liquid water cultivable bacterial counts (i.e. heterotrophic plate counts or HPCs) did not increase with a greater biofilm accumulation, the results also suggested that high HPCs corresponded to a low disinfectant residual more than a high biofilm inventory. Furthermore, temperature was found to affect the biofilms, plus the AOC was important when the residual was between 0.6 and 2.0 mg $Cl_2/l$. An additional aspect of the current study was that the potential of the exoproteolytic activity (PEPA) technique was used along with a traditional so-called destructive technique in which the biofilm was scrapped off the coupon surface, resuspended, and cultivated on an R2A agar. Both techniques indicated similar trends and relative comparisons among the PDSs, yet the culturable biofilm values for the traditional method were several orders of magnitude lower than the PEPA values.

Synthesis of Ultrafine and Less Agglomerated TiCN Powders by Magnesiothermic Reduction (마그네슘 열환원에 의한 저응집 초미립 TiCN 분말합성)

  • Lee, Dong-Won
    • Journal of Powder Materials
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    • v.19 no.5
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    • pp.356-361
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    • 2012
  • The ultra-fine and less agglomerated titanium carbonitride particles were successfully synthesized by magnesiothermic reduction with low feeding rate of $TiCl_4+1/4C_2Cl_4$ solution. The sub-stoichiometric titanium carbide ($TiC_{0.5{\sim}0.6}$) particles were produced by reduction of chlorine component by liquid magnesium at $800^{\circ}C$ of gaseous $TiCl_4+1/4C_2Cl_4$ and the heat treatments in vacuum were performed for 5 hours to remove the residual magnesium and magnesium chloride mixed with produced $TiC_{{\sim}0.5}$. The final $TiC_{{\sim}0.5}N_{0{\sim}0.5}$ particle with near 100 nm in mean size and high specific surface area of $65m^2/g$ was obtained by nitrification under nitrogen gas at $1,150^{\circ}C$ for 2 hrs.

Initial Bacterial Groups in the Development of Biofilm in Drinking Water (수돗물속 생물막 형성의 초기 세균)

  • Lee, Dong-Geun
    • Journal of Environmental Health Sciences
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    • v.33 no.5
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    • pp.428-433
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    • 2007
  • To clarify the pioneer group in the development of biofilms in high chlorine residual water, a semi-pilot model system was operated and 16S rDNA V3 targeted PCR-DGGE was submitted. Biofilm formation occurred rapidly in the model of a drinking water distribution system. It reached $10^3\;CFU/cm^2$ or more on the surface of stainless steel, PVC, and galvanized iron in chlorinated (1.0 mg/l) water within a week. Within a week, uncultured Proteobacteria- and Bacillales group-like sequences were detected and Sphingomonas-like sequences were identified from all season and all pipe materials tested. Hence Sphingomonas species were regarded as the potential pioneer group in the development of biofilm in drinking water and this results would be useful for the prevention of biofilm formation and safety of drinking tap water.

The Effects of Fluorine Passivation on $SF_6$ Treatment for Anti-corrosion after Al(Cu 1%) Plasma Etching (Al(Cu 1%)막의 플라즈마 식각후 부식 억제를 위한 $SF_6$ 처리시 fluorine passivation 효과)

  • 김창일;권광호;백규하;윤용선;김상기;남기수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.3
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    • pp.203-207
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    • 1998
  • After etching Al-Cu alloy films using $SiCl_4/Cl_2/He/CHF_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS (X-ray photoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, the $SF_6$ plasma treatment subsequent to the etch has been carried out. A passivation layer is formed by fluorine-related compounds on etched Al-Cu alloy surface after $SF_6$ treatment, and the layer suppresses effectively the corrosion on the surface as the RF power of $SF_6$ treatment increases. The corrosion could be suppressed successfully with $SF_6$ treatment in the RF power of 150watts.

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Introduction of Water Quality Certification System for Confidence Improvement of Tap Water (수돗물 신뢰도 향상을 위한 품질 인증 제도 도입)

  • Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.2
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    • pp.155-163
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    • 2015
  • Many advanced treatment processes have been introduced to WTPs, however, the consumer confidence on tap water is still low and the percentage of drinking water directly from the tap is less than 2 %. One of the methods to improve the credibility of tap water is to introduce a drinking water certification system. By introducing the system, water treatment processes can be optimized, which in turn, can significantly improve drinking water quality. In this paper, 6 water quality parameters(i.e., turbidity, CT, residual chlorine, geosmin, 2-MIB, Mn) which have significant influences on tap water quality and consumer confidence were identified, and their recommended guidelines were proposed. 3-Star or 5-Star certification can be awarded to the WTPs which have met the certification criteria. The drinking water certification system can be carried out as a voluntary program among drinking water suppliers.

Application of THM Predictive Model in Water Distribution System (국내 상수관로에 대한 THM 발생 예측모델의 적용)

  • Lee, Doo-Jin;Kim, Young-Il;Sohn, Jin-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.3-11
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    • 2007
  • THM models have been developed in several researchers in order to better understand and manage the presence of THM in water distribution system. Several developed models were demonstrated in this study for estimating THM concentrations in target water distribution system. In order to investigate the performance of developed THM models, lab and field test were investigated. Predicted THM concentrations by all kind of models were showed good correlation with observed values. When the developed models were compared with lab and field test, the Rodriguez model during tested models was most predictive than the other models.