• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.3
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• pp.655-668
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• 1994

Conventional deodorization filters using soil and compost reach the capacity limitation of deodorization in short period, because its removal mechanism primarily depends on adsorption. Therefore, in this study the experiment was performed on the removal of ammonia which is a strong inorganic malodor, frequently emitted from night soil treatment plants and sewage treatment plants, by seeding activated sludges on the bio-peat containing higher organic contents, water conservation capacity, permeability and lower pressure drop. As a result, in raw peat filter natural ammonia outlet was observed in consequence of pH increase resulted from ammonia ionizing in liquid phase. Ammonia removal mechanism primarily depended on the adsorption onto the anion colloidal substances in peat. In peat bio-filter, theoretical ammonium salts ratio was higher than that of raw peat, resulted from slight pH increase by microorganism activity, however, the experimetal value of ammonia-nitrogen accumulated in bio-peat was lower than that of raw peat because of nitrification by nitrifying bacteria. In the initial reaction period, adsorption was predominant in the ammonia removal mechanism, but nitrification was conspicuous after the middle period. Mass balance of nitrogen was established using experimental data of input $NH_3$ loading, output $NH_3$ loading, $NH_4{^+}$-N, $NO_x$-N, and Org-N. The critical time of unsteady state, which is the maximum activating point of microorganism in bio-filter, was determined using experimental data, and the ammonia adsorption curve was computed using regression analysis. On the basis of the results obtained by above analysis, the delay days for the saturation of adsoption capacity in peat bio-filter was calculated.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.398-401
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• 2003

Bacillus species predominantly outgrown in a night soil treatment system were isolated and characterized. Cell interactions took place among them and cell population changed under various culture conditions. Maximum removal of $NH_4\;^+-N$ and cell production occurred under the conditions of 30% DO and C/N ratio of 8. Additions of 0.8% peptone and 0.3% yeast extract to a basal medium influenced the growth of isolates and the removal of $NH_4\;^+-N$ in flask culture, and metal ions such as Ca, Fe and Mg also did. During the flask experiment of nitrogen removal under an aerobic condition, active nitrification by the isolates occurred largely in 1 h with the decrease of COD and alkalinity destructed was only 74.6% of theoretical value. From the nitrogen balance, the percentage of nitrogen lost in the flask culture was estimated to be 29.0%. This conversion of ammonia to $N_2$ under an aerobic condition was confirmed by GC analysis. The B3 process using the Bacillus species seemed to have some economic advantage.

• Korean Journal of Ecology and Environment
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• v.46 no.1
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• pp.116-127
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• 2013

At weekly intervals, we monitored continuous changes in water quality by constructed floating wetland equipped with the four different filter media (sponge, volcanic stone, activated carbon and magnesium hydroxide) in a eutrophic lake from March 2011 to May 2012. We also investigated phyto- and zooplankton communities both in the influent and the effluent water through the floating wetland. Over a 10-month time period, average turbidity (66%), suspended solids (79%) and chlorophyll-a (80%) concentrations were remarkably reduced in the effluent water compared to the influent (P<0.001). The average removal rates of $NO_2-N$ and $NH_3-N$ were 24% and 20%, respectively (P<0.05). The average removal rates of $NO_3-N$ and TN were less than 10% (P>0.05). On the other hand, the average removal rates of $PO_4-P$ and TP were more than 65% (P<0.01). Interestingly, the abundance of phytoplankton in the effluent was decreased about 2.6 times compared to that of the influent, whereas the abundance of zooplankton in the effluent was increased about 3.5 times compared to that of the influent. Overall, particulate matters (SS, Chl-a and TP) and dissolved nutrients ($NO_2-N$, $NH_3-N$ and $PO_4-P$) were particularly reduced at high rates. Therefore, application of our constructed floating wetland in a eutrophic lake improved the water quality and demonstrated a potential for algal bloom mitigation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.2
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• pp.970-976
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• 2013

An evaluation of the organic matter removal efficiency showed high removal efficiencies of 91.1~96.3% and 91.4~97.5% for TCODcr and TBOD5, respectively, for 9hr or longer of HRT. However, the removal efficiencies decreased to 86.9~90.5% and 88.0~90.9%, respectively for 6hr of HRT. $NH_3$-N showed a high removal efficiency of 95% or higher for 9hr or longer of HRT. The total nitrogen removal efficiency was 67.6~76.7% for 9~12hr of HRT, and it decreased to 50% for 6hr of HRT, which seems to be due to the insufficient carbon source required for denitrification. The T-P removal efficiency was 32% on average. To comply with the legal standards, a chemical phosphorus removal process is needed after the reactor.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.3
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• pp.367-375
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• 2006

Sequencing Batch Reactor (SBR) is well adopted for community wastewater treatment for its simplicity, performance and various advantageous treatment options. SBR is now drawing attention for its process modification such as coupled with membrane bioreactor, reverse osmosis or applying different media to achieve high removal efficiency. This study focused on the improved efficiency of carbon, nitrogen and phosphorous removal by applying zeolite materials called bioceramics to the SBR. Two laboratory-scale SBR units were operated in the same operating conditions - one with bioceramics called Bioceramic SBR (BCSBR) and the other without bioceramics used as control. Routine monitoring of COD, TP, $NH_3-N$, $NO_3-N$ was performed throughout this study. COD removal was about 80% to 100% and phosphorous removal was about 60% in the process whereas $NH_3-N$ removal efficiency was found to be 99.9% in the BCSBR unit. Addition of bioceramics also improved sludge characteristics such as sludge dewaterability, specific gravity and particle size. BCSBR can withstand high ammonia shock loading leading to the better treatment capacity of high ammonia containing wastewater. The cause of improved removal efficiencies within the biological reactor could be attributed to the biochemosorption mechanisms of bioceramics. Absorption/adsorption or desorption capacity of bioceramics was tested through laboratory experiments.

• Journal of Animal Science and Technology
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• v.51 no.4
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• pp.337-342
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• 2009

The feasibility of reutilization of magnesium ammonium phosphate (MAP) or struvite slurry recovered from the process through microwave irradiation was studied in this experiment. For this purpose, 4 different operations were performed with or without Mg source addition and different levels of MAP recycled in a batch reactor. Dissolution rate of MAP, ${NH_4}^+$ elimination pattern and physicochemical changes of MAP during microwave irradiation were also studied. The result showed that only 33% orthophosphate ($PO_4-P$) and 27% $NH_4-N$ removal occurred without adding any external Mg source (run A), whereas 87% $PO_4-P$ and 40% $NH_4-N$ removed when 1.0 M ratio of $MgCl_2$ (run B) was added based on $PO_4-P$ in influent. Although the addition of 1.0 molar ratio of microwave irradiated MAP (Run C) removed lower $PO_4-P$ and $NH_4-N$ than 1.0 M $MgCl_2$ (run B), $PO_4-P$ removal was double when compared with no Mg addition (run A). Addition of half MAP and half $MgCl_2$ (run D) showed the similar removal efficiency (88% $PO_4-P$ and 35% $NH_4-N$) with sole $MgCl_2$ addition (run B). Based on these results, the reutilization of MAP irradiated by microwave would be a feasible way to enhance the removal efficiencies of N and P, as well as curtail the Mg chemical usage. Track study showed that $NH_4-N$ gradually increased at initial stage of microwave irradiation of MAP, and then started eliminating from liquor as temperature increased over $45^{\circ}C$. Dissolution rate of ${PO_4}^{-3}$ during microwave irradiation was proportional to the initial MAP concentration, having $0.0091x^{0.6373}$ mg/sec. It was found from the scanning electron microscope (SEM) study that physical structure of MAP crystal started breaking down into small cube granules within very short time by electromagnetic vibration force during microwave irradiation and then gradually melted down into solution.

• Journal of Environmental Science International
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• v.13 no.9
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• pp.779-878
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• 2004

This study was conducted to analyze the operating conditions of predenitrification process to improve the treatment efficiency in low organic loading sewage plant in use today, and to investigate the treatment efficiency of pilot plant added night soil as well as the nitrogen removal characteristics of pilot plant added carbon sources. In the operation under the condition of $BOD_{5}$ sludge load 0.03-0.28kg $BOD_{5}$/kg VSS/d and oxic ammoniac nitrogen sludge load 0.02-0.24 $kgNH_{4}^{+}$-N/kg MLVSS/d, nitrification efficiency is higher than 95%. In order to achieve 70% nitrogen removal at the T-N sludge loading 0.06kg T-N/kg VSSㆍd and the SRT 6～11 days, optimum operating factors were revealed to $CODc_{r}$/T-N ratio 9, recycle ratio 2.6, and denitrification volume ratio 0.33. At this time, denitrification capacity was approximately 0.09 kg $NO_{3}^{-}$-N/kg $CODc_{r}$; specific nitrification rate was 3.4mg $NH_{4}^{+}$-N/g MLVSS/hr; and specific denitrification rate was 4.8mg $NO_{3}^{-}$-N/g MLVSS/hr.

• Journal of Aquaculture
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• v.7 no.3
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• pp.177-187
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• 1994

The objective of the present study were to evaluate nitrification characteristics and determine optimum treatment conditions of three phase fluidized bed reactor for recycling water treatment of aquaculture. When the loading rates were 2.739-0.086kg $COD/m^3/day$ and 1.575-0.128kg $NH_4\;^+-N/m^3/day$, COD and ammonia removal efficiencies were $56.3-94.7\%\;and\; 67.3­92.6\%$, respectively. The maximum removal rates of COD and ammonia were 1200mg/l/day and 488mg/l/day, respectively. Ammonia removal rates were more than $90\%$ beyond 1hr HRT. The ammoniaremoval efficiency was sensitive to the variation of media concentration and air flowrate.

• International Journal of Highway Engineering
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• v.9 no.3
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• pp.75-82
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• 2007

Washed wastewater generated from the intermittent cleaning process of the three tunnel sites located in the Seoul area showed high concentrations of SS, $COD_{Cr}$, T-N, $NH_3-N$, $NO_3-N$, Zn, Cu, Cr(+6), Mn, Mg, Phenol, $CN^-$ and E-Coli based on the water quality analysis. These characteristics of the deteriorative wastewater depend on the sampling method, cleaning frequency, released amount of washing water, inner material of tunnel wall, traffic volume, and type of drainage systems. Gravitational separation experiment of SS with collected tunnel wastewater showed considerable removal of pollutants such as 80% of $COD_{Cr}$, 30% of T-N and 90% of T-P simultaneously. GAC isotherm test was conducted to remove dissolved portion of the pollutants, and resulted in high removal efficiencies above 80% of $COD_{Cr}$, T-N, Zn, Cu, Mn, Phenol, CN in the experimental condition of GAC dosage of $50g/1/{\ell}$.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.7
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• pp.700-704
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• 2008

Nitrite and free ammonia have been known as substrate inhibitors in anaerobic ammonium oxidation. To reduce inhibitory effect of these substrates, the NH$_3$-N/NO$_2$-N ratio in the influent could be properly controlled in anaerobic ammonium oxidation process. Five kinds of NH$_3$-N/NO$_2$-N ratio were assayed in batch to find optimum NH$_3$-N/NO$_2$-N ratio, curtailing substrate inhibition. As the results of batch test, the highest T-N removal efficiency of 88% was obtained at 1.00 : 1.30 of NH$_3$-N/NO$_2$-N ratio. In addition, rate constants for ammonium and nitrite in zero-order kinetics were found to be the highest values as 7.66 mg/L$\cdot$hr and 11.89 mg/L$\cdot$hr at 1.00 : 1.30 ratio, respectively. However, as for the specific anammox activity, the ratio of NH$_3$-N/NO$_2$-N ratio was recommended as 1 : 1.15 which can maintain the highest SAA during continuous operation and preclude the accumulation of nitrite in the reactor.