• Title/Summary/Keyword: removal efficiency

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Development of Practical Advanced Oxidation Treatment System for Decontamination of Soil and Groundwater Contaminated with Chlorinated Solvents (TCE, PCE): Phase II (염소계 화합물(TCE, PCE)로 오염된 토양 및 지하수 처리를 위한 실용적 고도산화처리시스템 개발 (II))

  • Kim, Sang-Yeek;Sohn, Seok-Gyu;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.15 no.2
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    • pp.10-17
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    • 2010
  • Advanced oxidation processes (AOPs) have advantages to reduce the processing time and mineralize contaminants dissolved in groundwater. Recently, remediation techniques for organic contamination in groundwater have been studied, and technology using $UV/H_2O_2$ is generally accepted as one of the most powerful and reliable alternative for the remediation of groundwater contamination. In this study, $UV/H_2O_2$ technology, which generates hydroxyl radical ($\cdot$ OH) as known for strong non-selective oxidant, was used to degrade chlorinated solvents (TCE and PCE), and it was expanded to apply continuous stirred tank reactor (CSTR) system (i.e. combinations of three CSTR). The tested parameters for CSTR system were retention time and groundwater/$H_2O_2$ injection volume ratio. To find optimum parameters for CSTR system, various retention time (6 min ~ 90 min) and groundwater/$H_2O_2$ injection volume ratio (5/1 ~ 119/1) were tested. Other conditions for CSTR were adapted from the batch test results, which concentration of $H_2O_2$ and UV dose were 29.4 mM (0.1%) and 4.3 kWh/L, respectively. Based on the experimental results, the optimum parameters for CSTR system were 20 min for retention time and 119/1 for groundwater/$H_2O_2$ injection volume ratio. Applying these optimum conditions, chlorinated solvents (TCE and PCE) were removed at 99.9% and 99.6%. Moreover, the effluent concentrations of TCE and PCE are 0.036 mg/L and 0.087 mg/L, respectively, which are satisfied the regulatory level (TCE 0.3 mg/L, PCE 0.1 mg/L). Consequently, the CSTR system using $UV/H_2O_2$ technology can achieve high removal efficiency in the event of treatment of groundwater contaminated by chlorinated solvents (TCE and PCE).

Life Cycle Assessment of the Carbon Emissions of MLE process and Denitrification Process Using Granular Sulfur (MLE공법과 황이용 탈질 프로세스의 전과정 탄소 배출량 평가)

  • Moon, Jin-young;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.619-627
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    • 2012
  • In order to determine reduction of greenhouse gas emissions (GHGs) when the submerged membrane bioreactor with granular sulfur (MBR-GS) is used in wastewater treatment plant (WTP), the amount of GHGs was compared and analyzed in the advanced treatment process of P wastewater treatment plant (WTP). The amount of GHGs was estimated by classifying as construction and operation phase in WTP. The amount of GHGs in construction phase was evaluated from multiplying raw materials by using carbon emission factors. Also the amount of GHGs in operating phase was calculated by using total electricity consumption and carbon emission factor. The construction of anoxic tank and secondary settling tank is unnecessary, because the MBR-GS conducts simultaneously the nitrification and denitrification in aeration tank and filtration by hollow fiber membrane. The amount of $CO_2$, $CH_4$, and $N_2O$ emitted by constructing the MBR-GS was 6.44E+06 kg, 8.16E+03 kg and 1.38E+01 kg, respectively. The result shows that the GHGs was reduced about 47 % as compared with the construction in the MLE process. In operating the MBR-GS, the electricity is not required in the biological reactor and secondary setting tank. Thus, the amount of $CO_2$, $CH_4$, and $N_2O$ emitted by operating in the MBR-GS was 7.39E+05 kg/yr, 5.80E+02 kg/yr and 2.44E+00 kg/yr, respectively. The result shows that the GHGs were reduced about 37 % as compared with the operation in the MLE process. Also, $LCCO_2$(Life Cycle $CO_2$) was compared and analyzed between MLE process and MBR-GS. The amount of $LCCO_2 $emitted from the MLE process and MBR-GS was 3.56E+04 ton $CO_2$ and 2.12E+04 ton $CO_2$, respectively. The result shows that the GHGs in MBR-GS were reduced to about 40 % as compared in the MLE process during life cycle. As a result, sulfur-utilizing autotrophic denitrification process (SADP) is expected to be utilized as the cost-effective advanced treatment process, owing to not only high nitrogen removal efficiency but also the GHGs reduction in construction and operation stage.

Biogas Production from Sewage Sludge in 30L Microbial Electrolysis Cell (30L 미생물전기분해전지의 하수슬러지로부터 바이오가스 생산 특성)

  • Lee, Myoung-Eun;Ahn, Yongtae;Shin, Seung Gu;Seo, Sun-Chul;Chung, Jae Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.25-33
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    • 2019
  • Operating characteristics of a 30 L microbial electrolysis cell (MEC) for producing biogas from sewage sludge was studied. During the 32-day inoculation period, carbon dioxide concentration decreased and methane concentration increased with operating time, and the overall methane content of biogas was 69.1% with a production rate of 171.6 mL CH4/L·d. In fed-batch experiments for 6 operating cycles, CH4 concentration of 66.5~77.2% was obtained at a production rate of 184.9~372.9 mL CH4/L·d, COD, TS and VS removal efficiency ranged from 28.2 to 42.1%, 20.7 to 37.5% and 18.5 to 36.9%, respectively. The MEC system was observed to be stabilized as operating cycles were repeated after inoculation. In the last operating cycle, 5221 mL/L of methane was produced with CH4 yield of 316.7 L CH4/kg CODrem, and the energy recovery was 73%.

Proposal of a Step-by-Step Optimized Campus Power Forecast Model using CNN-LSTM Deep Learning (CNN-LSTM 딥러닝 기반 캠퍼스 전력 예측 모델 최적화 단계 제시)

  • Kim, Yein;Lee, Seeun;Kwon, Youngsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.10
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    • pp.8-15
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    • 2020
  • A forecasting method using deep learning does not have consistent results due to the differences in the characteristics of the dataset, even though they have the same forecasting models and parameters. For example, the forecasting model X optimized with dataset A would not produce the optimized result with another dataset B. The forecasting model with the characteristics of the dataset needs to be optimized to increase the accuracy of the forecasting model. Therefore, this paper proposes novel optimization steps for outlier removal, dataset classification, and a CNN-LSTM-based hyperparameter tuning process to forecast the daily power usage of a university campus based on the hourly interval. The proposing model produces high forecasting accuracy with a 2% of MAPE with a single power input variable. The proposing model can be used in EMS to suggest improved strategies to users and consequently to improve the power efficiency.

A new protocol of the sliding mechanics with Micro-Implant Anchorage(M.I.A.) (Micro-Implant Anchorage(MIA)를 이용한 Sliding mechancis)

  • Park, Hyo-Sang
    • The korean journal of orthodontics
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    • v.30 no.6 s.83
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    • pp.677-685
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    • 2000
  • Anchorage plays an important role in orthodontic treatment. Because of limited anchorage Potential and acceptance problems of intra- or extraoral anchorage aids, endosseous implants have been suggested and used. However, clinicians have hesitated to use endosseous implants as orthodontic anchorage because of limited implantation space, high cost, and long waiting period for osseointegration. Titanium miniscrews and microscrews were introduced as orthodontic anchorage due to their many advantages such as ease of insertion and removal, low cost, immediate loading, and their ability to be placed in any area of the alveolar bone. In this study, a skeletal Class II Patient was treated with sliding mechanics using M.I.A.(micro-implant anchorage). The maxillary micro-implants provide anchorage for retraction of the upper anterior teeth. The mandibular micro-implants induced uprighting and intrusion of the lower molars. The upward and forward movement of the chin followed. This resulted in an increase of the SNB angle, and a decrease of the ANB angle. The micro-implants remained firm and stable throughout treatment. This new approach to the treatment of skeletal Class II malocclusion has the following characteristics . Independent of Patient cooperation. . Shorter treatment time due to the simultaneous retraction of the six anterior teeth . Early change of facial Profile motivating greater cooperation from patients These results indicate that the M.I.A. can be used as anchorage for orthodontic treatment. The use of M.I.A. with sliding mechanics in the treatment of skeletal Class II malocclusion increases the treatment simplicity and efficiency.

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Internal Flow Analysis of Urea-SCR System for Passenger Cars Considering Actual Driving Conditions (운전 조건을 고려한 승용차용 요소첨가 선택적 촉매환원장치의 내부 유동 해석에 관한 연구)

  • Moon, Seong Joon;Jo, Nak Won;Oh, Se Doo;Lee, Ho Kil;Park, Kyoung Woo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.3
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    • pp.127-138
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    • 2016
  • Diesel vehicles should be equipped with urea-selective catalytic reduction(SCR) system as a high-performance catalyst, in order to reduce harmful nitrogen oxide emissions. In this study, a three-dimensional Eulerian-Lagrangian CFD analysis was used to numerically predict the multiphase flow characteristics of the urea-SCR system, coupled with the chemical reactions of the system's transport phenomena. Then, the numerical spray structure was modified by comparing the results with the measured values from spray visualization, such as the injection velocity, penentration length, spray radius, and sauter mean diameter. In addition, the analysis results were verified by comparison with the removal efficiency of the nitrogen oxide emissions during engine and chassis tests, resulting in accuracy of the relative error of less than 5%. Finally, a verified CFD analysis was used to calculate the interanl flow of the urea-SCR system, thereby analyzing the characteristics of pressure drop and velocity increase, and predicting the uniformity index and overdistribution positions of ammonia.

Determination of Detention Basin Size for NPS Control in TMDL Area (수질오염총량관리제하에서 친환경 개발사업을 위한 자연형 비점저감시설의 규모 산정)

  • Jung, Yong-Jun;Lee, Eun-Ju;Lee, So-Young;Lim, Keong-Ho;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.9 no.2
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    • pp.1-8
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    • 2007
  • Since 2000, environmental policies and regulations in Korea are rapidly changing to TMDL(Total Maximum Daily Load) and nonpoint source control. This is due to bad water quality in drinking water sources. Although many environmental facilities having high removal efficiency are constructed and applied in nationwide for controling various pollutants from wastewaters, the water quality in rivers is worse and worse because of nonpoint pollution. In fact, TMDL is a new environmental regulation controling total daily loadings from watershed areas. Actually, the nonpoint pollutant is originated from various landuses and its control is based on TMDL regulation. Therefore, this research is performed to determine the size of detention basin to control nonpoint pollutants from resort developing areas. The detention basin is one of best management practices, which is useful for controling pollutants and flooding from the developing areas. However, it should be designed and constructed with cost effective method. Recent 10 years rainfall data are used to determine the size of detention basin. The cost effective size is determined to 7.4mm accumulated rainfall.

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The improvement of the operating process of sewage treatment plants in the upstream area of dam by MASS FLOWmodelling (MASS FLOW 모델링을 통한 댐상류지역의 공공하수처리시설 공정개선방안)

  • Lee, Hyunseop;Lee, Jiwon;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.22 no.2
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    • pp.130-138
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    • 2020
  • As of 2017, the sewerage penetration rate of Seoul and metropolitan cities is more than 90%, and the number of domestic sewage treatment plants increased by 25% from 3,064 in 2010 to 4,072 in 2017. Among them, sewage treatment plant operated by SBR system is 585, which is 17% higher than 2010. In order to improve the water quality of the water source and improve the operation of the small sewage facilities, the improvement of the process was studied by applying the modelling to 49 facilities of the sewage treatment plant in Andong Imha dam area with more than 500㎥/day 3 places and 46 places less than 500㎥/day. As an improvement plan for modelling, candidate data were derived by reviewing operation data for 5 years. 49 facilities are operated by 12 types of operating processes. Among them, 1 place mort than 500㎥/day with SBR method and 9 facilities with less than 500㎥/day were selected by dividing 46 sites into 3 types. As a result of applying modelling to more than 500㎥/day, it was possible to improve the quality of discharged water through SRT control and it was found that applying model to sites of small scale treatment plants can improve the removal efficiency of TP by up to 14.4%. As a result, the data of this study could be used to improve and improve the operation of sewage treatment plants and RCSTP(Rural Community Sewage Tratment Plant).

Characteristics of Ti-SPAC as Fluidizing Phase Photocatalyst (Ti-구형활성탄의 유동상 광촉매 특성 평가)

  • Lee, Joon-Jae;Suh, Jeong-Kwon;Hong, Ji-Sook;Park, Jin-Won;Lee, Jung-Min
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.375-381
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    • 2006
  • In this sturdy, spherical activated carbon(SPAC) contained $TiO_2$ was made by ion-exchanged treatment and heat treatment for applying fluidizing bed system. The ion-exchange resin was treated by $TiCl_3$ aqueous solution. The treated resin and raw resin were heat-treated under nitrogen condition to convert into Ti-SPAC. During the heat-treatment, burn-off weight amounts and the element were measured by means of TGA and TGA/MS, individually. The physicochemical properties of Ti-SPAC was characterized by means of XRD, SEM, EDS, BET, EPMA, ESR, intensity and titanium content. The Ti-SPAC had spherical shape with diameter size about $350{\mu}m{\sim}400{\mu}m$ and $617m^2/g$ specific surface area. Structure of $TiO_2$ in Ti-SPAC was anatase and rutile form. Also, $TiO_2$ on SPAC were found that the $TiO_2$ were uniformly distributed through EPMA analysis. Moreover, the Ti-SPAC showed indirect photocatalyst activity estimation through ESR analysis, characteristics of photocatalyst potentially. Over all results, Ti-SPAC was used in fluidizing bed UV/photocatalyst system to remove HA(Humic Acid). That results were HA removal efficiency was about 70% and Ti-SPAC intensity was preserved during reaction. Ti-SPAC showed practical possibility as photocatalyst in fluidizing bed system.

Characteristics of Cyanide Decomposition by Hydrogen Peroxide Reduction (과산화수소에 의한 시안의 분해특성)

  • 이진영;윤호성;김철주;김성돈;김준수
    • Resources Recycling
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    • v.11 no.2
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    • pp.3-13
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    • 2002
  • The characteristics of cyanide decomposition in aqueous phase by hydrogen peroxide have been explored in an effort to develop a process to recycle waste water. The self-decomposition of $H_2O$$_2$at pH 10 or below was minimal even in 90 min., with keeping about 90% of $H_2O$$_2$undissociated. On the contrary, at pH 12 only 9% of it remained during the same time. In the presence of copper catalyst at 5 g Cu/L, complete decomposition of $H_2$O$_2$was accomplished at pH 12 even in a shorter time of 40 min. The volatility of free cyanide was decisively dependent on the solution pH: the majority of free cyanide was volatilized at pH 8 or below, however, only 10% of it was volatilized at pH 10 or above. In non-catalytic cyanide decomposition, the free cyanide removal was incomplete in 300 min. even in an excessive addition of $H_2$$O_2$at a $H_2$$O_2$/CN molar ratio of 4, with leaving behind about 8% of free cyanide. On the other hand, in the presence of copper catalyst at a Cu/CN molar ratio of 0.2, the free cyanide was mostly decomposed in only 16 min. at a reducedH202/CN molar ratio of 2. Ihe efnciency of HBO2 in cyanide decomposition decreased with increasing addition of H2O2 since the seu-decomposition rate of $H_2$$O_2$increased. At the optimum $H_2$$O_2$/mo1ar ratio 0.2 of and Cu/CN molar ratio of 0.05, the free cyanide could be completely decomposed in 70 min., having a self-decomposition rate of 22 mM/min and a H$_2$$O_2$ efficiency of 57%.