Park, SangJun;Oh, YoungHwan;Jo, BoYeon;Lee, JaeShin;Lee, SangWha;Jeong, JaeHyun
Korean Chemical Engineering Research
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v.53
no.6
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pp.730-739
/
2015
108 microorganism types (79 types of fungi and 29 types of bacteria) were isolated from 25 automobiles generating bad odor when the air conditioner was turned on, and 43 types of fungi and 23 types of bacteria were identified. The analysis of condensate generated by the air conditioners in the automobiles indicated pH 6.4~7.1, 12.5~34.2 mg/L carbon source, 0.9~18.6 mg/L nitrogen source, 0.5~27.8 mg/L ion contents, and 0.1~7.7 mg/L mineral contents. The biofilms were formed by the mesophiles under the summer temperature/humidity condition ($26^{\circ}C$, 70% R.H.), and they were regenerated when the environmental factors (nutritional contents and temperature/humidity) were appropriate even after they were artificially removed. Although the antimicrobials removed 99.9% of planktonic cells within 15 minutes, they were not effective in removing biofilm. Up to 1,950 ppmv of ethanol was observed in the automobile treated with the antimicrobials. Although the figure is lower than the acute toxicity level when inhaled by humans, the health safety of the chemical substances used in the antimicrobials needs to be reviewed.
Ni-base superalloys are used extensively in industry, both in aeroengines and land based turbines. About 60% by weight of most modern gas turbine engine structural components are made of Ni-base superalloys. To satisfy practical demands, the efficiency of gas turbine engines has been steadily and systematically increased by design modifications to handle higher turbine inlet or firing temperatures. However, the increase in operating temperatures has lead to a decrease in the life of components and increase in costs of replacement. Moreover, around 80% of the large frame size industrial/utility gas turbines operating in the world today were installed in the mid-sixties to early seventies and are now 25 to 30 years old. Consequently, there are greater opportunities now to repair and refurbish the older models. Basically, there are two major factors influencing the weldability of the cast alloys: strain-age cracking and liquation cracking. Susceptibility to strain-age cracking is due to the total Ti plus AI content of the alloy; Liquation cracking is due either to the presence of low melting constituents or constitutional liquation of constituents. Though Rene 41 superalloy has 4.5wt.% total Ti and Al content and falls just below the safe limit proposed by Prager et al., controlled grain size and special heat treatments are needed to obtain crack-free welds. Varying heat treatments and filler materials were used in a laboratory study, then the actual welding of service parts was carried out to verity the possibility of crack-tree weld of components fabricated from Rene 41 superalloy. The microstructural observations indicated that there were two kinds of carbides in the FCC matrix. MC carbides were located along the grain boundaries, while M$_{23}$C$_{6}$ carbide was located both inter and intra granularly. Two kinds of filler materials, Rene 41 and Hastelloy X were used to gas tungsten arc weld a patch into the sheet metal, along with varying pre-weld heat treatments. The microstructure, hardness and tensile tests were determined. The service distressed parts were categorized into three classes: with large cracks, with medium cracks and with small or no visible cracks. No significant difference in microstructure among the specimens was observed. Specimens were cut from the corner and the straight edge of the patch repair, away from the corner. The only cracks present were found to be associated with inadequate surface preparation to remove oxidation. Guidelines for oxide removal and the welding procedures developed in the research enabled crack-free welds to be produced.d.
Urban areas generate large amounts of stormwater and non-point source (NPS) pollutants during rainfall events. These are caused by various land use runoffs, vehicular and human activities and increased impervious cover. The increased runoff and NPS pollutants cause water quality deterioration in the receiving waters and adversely affect the aqua-ecosystem. These environmental impacts could be reduced through the application of low impact development (LID) techniques. In Korea, more than 80% of the total rainfall occurs in summer and most of these were 10 mm or less. Therefore, if the LIDs developed were able to cope with rainfall of 10 mm and below, NPS management could be efficiently conducted. This research was performed to determine the effect of varying amounts of rainfall on the performance capability of an established infiltration and filtration facility (IF facility) that can be applied to Korea's common rainfall ranges. The IF facility area was 1.75% of the catchment area, however the facility treated more than 40% and 60% runoff volume and pollutant reduction respectively for a 10 mm rainfall. Lastly, higher volume and pollutant reduction could be attained when the LID area was at least 2% of the entire catchment.
In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc.. Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux $2m^3/m^2{\cdot}day$. But in Flux $5m^3/m^2{\cdot}day$, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux $10m^3/m^2{\cdot}day$, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and $UV_{254}$ showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.
Kim, Jin-Soo;Kim, Sun-Jong;Oh, Kwang-Young;Oh, Seung-Young;Kim,Je-Su;Jeong, Young-Ho
Journal of Korea Water Resources Association
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v.36
no.5
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pp.787-797
/
2003
The characteristics of concentrations and loads of Total Nitrogen(T-N), Total Phosphorus(T-P), and Chemical Oxygen Demand (COD) in mountain stream water were examined from September 2000 through August 2001. The 92.5-ha study watershed in Chungbuk Province consists of 59% mixed forest and 30% coniferous forest. Streamflow was measured and water samples were collected at about 10 day intervals for dry days and at 2-6 hour intervals for a storm event at the study watershed outlet. The mean concentration of COD in streamflow for rainy days was significantly (p < 0.05) higher than for dry days. The mean concentrations of T-N and T-P in vegetation growing season (May to October) were lower than those in vegetation dormant season (November to April). Low concentrations of pollutants during vegetation growing season are likely due to the heavy demand for nutrients by the vegetation and biological activity associated with a warming of soil. The ratios of pollutants loads during storm periods to annual pollutants loads were 87% for T-N, 83% for T-p, and 87% for COD. The unit loads of pollutants for study area were estimated at 5.9 kg/ha $\cdot$ yr for T-N, 0.15 kg/ha $\cdot$ yr for T-p, and 23.9 kg/ha $\cdot$ yr for COD. The removal efficiency of pollutants in study area were 24% for T-N, 58% for T-P and 66% for COD, indicating that a study area shows water purification function.
This study was to evaluate the performance of the Double stage Pore controllable fiber (DP) filter system as the pre-treatment of the RO membrane. The evaluation for the pre-treatment filter was performed through the indirect method, SDI (Silt Density Index) measurement of the filtrate. This study was done during Jan. 3 of 2009 to Dec. 3 of 2009 at OO Water Treatment Plant that was suppling industrial water to plants, and the raw water was contaminated lake water and it was fed to the system after clarification with coagulation. The average turbidity of the feed water and that of the filtrate was 0.79 NTU (0.28~4.01 NTU), and 0.16 NTU (0.04~0.50) respectively. And so the average turbidity removal efficiency was 77%. The filtrate flow rate and the backwash water flow rate was about 230 $m^3$/day and about 8.7 $m^3$/day respectively, and so the backwash rate was 3.8%. The data for some samples were obtained after a few days storage, and it caused the higher turbidity and SDI15 as the storage time was increased. But average SDI value of the filtrate was 3.6 (2.26~5.00) which was lower than minimum value required by the RO membrane manufacturer as the RO feed water to guarantee the life time of the RO membrane. So, the DP filter system was enough for the application as the pre-treatment of the RO membrane.
Pressurized membrane module systems, including hollow fiber type of Microfiltration (MF) and Ultrafiltration (UF) membranes are being increasingly used in drinking water treatment due to their high removal efficiency of pathogen. However, when fibers are damaged in pressurized membrane system, the pathogen will be able to penetrate the membrane. Therefore, it is essential to guarantee the regulatory requirements for water quality by an effective on-line or off-line condition integrity monitoring methods. Recently, pressure decay test (PDT) which is one of membrane integrity tests has been reflected to drinking water treatment plants using pressurized membrane module. In this paper, three different method were used to perform PDT and three different sensitivity values were analyzed through experiments. Three types of direct integrity test methods were applied to pressure feed side, filtrate side and bidirectional pressure decay test. The results of these experiments show that the sensitivity was increasing when the volume of pressurized gas was decreasing. The sensitivity is inversely proportional to the gas volume. Furthermore, it is desirable to increase pressure difference between feed side and permeate side in order to achieve higher sensitivity in the PDT by membrane damage.
Livestock products like meat, milk and egg have been principal food sources for human beings since the historic periods of time. Nowadays consumption of these food items have been avoided due to its high contents of SFA, cholesterol and total fat which are major culprits of chronic adult diseases causing major deaths of people. However, the relationship between livestock products and diseases is not always true because the amounts of fat and cholesterol and types of fatty acids in meat and meat by-products depend on the part of the meat and types of animals. Although meat intakes do not always cause mai or adult diseases, still the developmental necessity does exist for animal foods equipped with biologically active properties, which in turn can improve nutritional status and health more than ever Meat with high protein lean part and low fat can be produced by applying synthetic somatotropin and beta-adrenergic agonists like clenbuterol, cimaterol etc. during breeding. This application brings benefits like higher growth rate, lower fat contents and improve feed efficiency ratios. Meats fortified with long chain PUFA($\omega$-3 fatty acids) can also be produced by modulating feed composition.Egg Products have faced the reduced sales annually because of its high cholesterol contents. Recently brand eggs fortified with special nutrients or chemical components having functional proper ties in the human body system are very popular Research Interests have been focused on eggs with low cholesterol and high omega-3 fatty acids. Low cholesterol eggs and high omega-3 eggs can be produced in several different ways, but popular way to increase is feeding the feeds with different oil sources containing high omega-3 and 6 fatty acids such as fish oil, perilla oil, linseed oil and lecithin etc. But proper compositon of feed formula should be found and economically beneficial. Brand eggs fortified with vitamin, mineral, unknown growth factors are also manufactured. Low cholesterol and high $\omega$-3 PUFA milk are marketed recently Cholesterol removal technology is not completely established and has several limitations to be overcome. Milk fortified with $\omega$-3 fatty acids is made by incorporating high &13 fatty acid foods in feed despite of extraordinary way of fatty acid metabolism In cow. All these biologically active products will be very beneficial and useful for human consumption when limitations of manufacturing technology such as safety and lowered sensory qualities are resolved. Furthermore, thorough and precise tests and quality control for these products should be performed to ensure the effectiveness and usefulness in terms of improving health and nutritional status in general. However one caution should be pointed out to lay people informing that these items are nothing but a food and not panacea. Therefore, it is important to remember that the only way of maintaining good health is absolutely through consuming balanced diet.
The effects of the compounds and concentrations of nitrogenous electron acceptor, the ratio of electron donor/electron acceptor (C/N), and the complexity of electron donor on the emission of $N_2O$ during wastewater denitrification were quantitatively investigated in this study. The higher ${NO_3}^-$ and ${NO_2}^-$ concentrations, the more $N_2O$ emission was observed. ${NO_2}^-$ has strong effect on $N_2O$ emission as it emitted morc $N_2O$ than ${NO_3}^-$, 50 mg/L of ${NO_2}^-$-N gave the highest conversion (9.3%) and yield (9.8%) of $N_2O$ while ${NO_3}^-$-N (50 mg/L) gave 5.6% conversion and 11.0% yield. Lower C/N ratio decreases nitrogen removal efficiency, but it increases the conversion of $N_2O$ because of the incomplete denitrification by the limited organic carbon. When real domestic wastewater is used as the electron donor of the denitrification, $N_2O$ emission is reduced to 1/10 of the emission when single carbon (acetate) is used. It is thought that multiple carbon source utilizes many denitrification pathways and it seems to be helpful for the reduction of $N_2O$ emission.
To produce biodiesel efficiently from fish oil containing 4% free fatty acid, esterification and trans-esterification were carried out with Vietnam catfish oil, which was kindly provided from GS-bio company. Heterogeneous solid acid catalysts such as Amberlyst-15 and Amberlyst BD-20 and sulfuric acid as homogeneous acid catalyst were used for the esterification of free fatty acids in the fish oil. Sulfuric acid showed the highest removal efficiency of free fatty acid and the shortest reaction time among three acid catalysts. The base catalysts for trans-esterification such as KOH, $NaOCH_3$ and NaOH were compared with each other and KOH was determined to be the best transesterification catalyst. Some solid material, which assumed to be saponified product from glycerol and biodiesel, were observed to form in the fish oil biodiesel when using $NaOCH_3$ and NaOH as the transesterification catalyst. The initial acid value of fish oil was proven to have a negative effect on biodiesel conversion. Of the three catalysts, KOH catalyst transesterification was shown to have high content of FAME and the optimal ratio of methanol/oil ratio was identified to be 9:1.
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