• 제목/요약/키워드: release rate constant

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Burning Characteristics of Wood-based Materials using Cone Calorimeter and Inclined Panel Tests

  • Park, Joo-Saeng;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • 제30권3호
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    • pp.18-25
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    • 2002
  • Research to discuss the fire performance of materials requires tools for measuring their burning characteristics and validated fire growth models to predict fire behavior of the materials under specific tire scenarios using the measured properties as input for the models. In this study, burning characteristics such as time to ignition, weight loss rate, flame spread, heat release rate, total heat evolved, and effective heat of combustion for four types of wood-based materials were evaluated using the cone calorimeter and inclined panel tests. Time to ignition was affected by not only surface condition and specific gravity of the tested materials but also the type and magnitude of heat source. Results of weight loss rate, measured by inclined panel tests, indicated that heat transfer from the contacted flame used as the heat source into the inner part of the specimen was inversely proportional to specific gravity of material. Flame spread was closely related with ignition time at the near part of burning zone. Under constant and severe external heat flux, there was little difference in weight loss rate and total heat evolved between four types of wood-based panels. More applied heat flux caused by longer ignition time induced a higher first peak value of heat release rate. Burning characteristics data measured in this study can be used effectively as input for fire growth models to predict the fire behavior of materials under specific fire scenarios.

A novel analytical approach for advection diffusion equation for radionuclide release from an area source

  • Esmail, S.;Agrawal, P.;Aly, Shaban
    • Nuclear Engineering and Technology
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    • 제52권4호
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    • pp.819-826
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    • 2020
  • The method of the Laplace transform has been used to obtain an analytical solution of the three-dimensional steady state advection diffusion equation for the airborne radionuclide release from any nuclear installation such as the power reactor in an area source. The present treatment takes into account the removal of the pollutants through the nuclear reaction. We assume that the pollutants are emitted as a constant rate from the area source. This physical consideration is achieved by assuming that the vertical eddy diffusivity coefficient should be a constant. The prevailing wind speed is a constant in 𝑥- direction and a linear function of the vertical height z. The present model calculations are compared with the other models and the available data of the atmospheric dispersion experiments that were carried out in the nuclear power plant of Angra dos Reis (Brazil). The results show that the present treatment performs well as the analytical dispersion model and there is a good agreement between the values computed by our model and the observed data.

Pharmaceutical Studies on Chitosan Matrix: Controlled release of aspirin from chitosan device

  • Lee, Chi-Young;Kim, Sung-Ho
    • Archives of Pharmacal Research
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    • 제10권2호
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    • pp.88-93
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    • 1987
  • Chitosan ($\beta$-D-glucosaminan) is chemically prepared from chitin (N-acetyl-$\beta$- D-glucosaminan) which is an unutilized natural resource. We now report on the suitability of the chitosan matrix for use as vehicles for the controlled release of drugs. Salicylic acid and aspirin were used as model drugs in this study. The permeation of salicylic acid in the chitosan membranes was determined in a glass diffusion cell with two compartments of equal volume. Drug release studies on the devices were conducted in a beaker containing 5% sodium hydroxide solution. Partition coefficient (Kd) value for acetate membrane (472) is much greater than that for fluoro-perchlorate chitosan membrane (282). Higher Kd value for acetate chitosan membrane appears to be inconsisstent with the bulk salicylic acid concentration. The permeability constants of fluoro-perchlorate and acetate chisotan membranes for salicylic acid were 3.139 ${\times}10^{-7}cm^2$ min up to 60 min and that of 30% aspirin in the devices was 4.739${\times}10^{-7}cm^2$sec upto 60 min. As the loading dose of aspirin in a chitosan device increased, water up-take of chitosan device increased, but in case of salicylic acid it decreased. The release rate increased with increase in the molecular volume of the drugs. Thses result suggest that the release mechanism may be controlled mainly by diffusion through pores.

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압축코팅법에 의한 3단계 약물방출형 지속성제제의 제조 및 용출특성 (Preparation and Dissolution Characteristics of the Compression-Coated Controlled Release Tablet Exhibiting Three-step Release)

  • 김철수;권혁노;차봉진;권종원;양중익;민신홍
    • Journal of Pharmaceutical Investigation
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    • 제22권2호
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    • pp.133-137
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    • 1992
  • A novel oral controlled release tablet which may offer more uniform drug level in the body than simple zero-order was developed. The tablet is composed of three layers; outer film layer, middle part compression-coated hydroxypropylmethylcellulose (HPMC) matrix layer, and inner core layer. Each layer contains nicardipine HCl as a model drug. In vitro dissolution test showed that the tablet released the drug in clear three steps; a rapid initial release, followed by a constant rate of release, and then a second phase of fast release of drug. The dissolution characteristics could be modified easily by changing the grade of HPMC, thickness of matrix layer, content of methylcellulose in matrix layer, content of active ingredient in each layer. The pH of dissolution medium did not affect the release profile. This three-step release system is expected to raise the blood concentration rapidly to effective level and to maintain effective blood level longer than simple slow-release systems.

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정적연소실내의 디젤분무증발과 연소특성에 관한 연구 (A Study on the Diesel Spray Evaporation and Combustion Characteristics in Constant Volume Chamber)

  • 김상호;김석준;이만복;김응서
    • 한국자동차공학회논문집
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    • 제2권6호
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    • pp.102-109
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    • 1994
  • As a fundamental study to apply high pressure injection system to direct injection diesel engine, fuel injection system and constant volume combustion chamber were made and the behaviors of evaporating spray with the variation of injection pressure and the ambient gas temperature were observed by using high speed camera, and the combusion characteristics with the variation of injection pressure and A/F ratio were analyzed. As injection pressure increases, spray tip penetration and spray angle increase and, as a results spray volume increases. This helps an uniform mixing of fuel and air. Spray liquid core length decreases as ambient gas temperature increases, while it decreases as injection pressure increases but the effect of ambient gas temperature is dorminant. As injection pressure increases, ignition delay is shortened and combustion rate being raised, maximum heat release rate increases. It become clear that High injection pressure has high level of potential to improve the performance of DI-diesel engine.

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케이블 화재의 화염전파 해석을 위한 FDS 모델의 격자민감도 평가 (Assessment of Grid Sensitivity in the FDS Field Model to Simulate the Flame Propagation of an Electric Cable Fire)

  • 김성찬;이성혁
    • 한국안전학회지
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    • 제23권4호
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    • pp.30-35
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    • 2008
  • The present study has been conducted to examine the effect of grid resolution on the predicted results for electric cable fire using pyrolysis model in FDS(Fire Dynamics Simulator, version 5). The grid independent test for different grid resolutions has been performed for a PE coating cable and the grid resolution is defined by the non-dimensional characteristic length of fire and mean grid size. The calculated maximum heat release rate and mean flame spread rate were almost constant for higher grid resolution of 20${\sim}$25 and the computing time for the grid resolution takes approximately 20hours to solve flame propagation with pyrolysis model. The geometrical simplification of a electric cable dose not greatly affect on the maximum heat release rate and flame spread rate and the rectangular approximation of cable shape gives acceptable result comparing with the round cable with stepwise grid.

디젤기관에서 경유/부탄올 혼합연료의 기관성능 및 연소특성 해석 (Analysis of performance and combustion characteristics of D.O./butanol blended fuels in a diesel engine)

  • 김상암;왕우경
    • 수산해양기술연구
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    • 제55권4호
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    • pp.411-418
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    • 2019
  • In this study, to investigate the effect of physical and chemical properties of butanol on the engine performance and combustion characteristics, the coefficient of variations of IMEP (indicated mean effective pressure) and fuel conversion efficiency were obtained by measuring the combustion pressure and the fuel consumption quantity according to the engine load and the mixing ratio of diesel oil and butanol. In addition, the combustion pressure was analyzed to obtain the pressure increasing rate and heat release rate, and then the combustion temperature was calculated using a single zone combustion model. The experimental and analysis results of butanol blending oil were compared with the those of diesel oil under the similar operation conditions to determine the performance of the engine and combustion characteristics. As a result, the combustion stabilities of D.O. and butanol blending oil were good in this experimental range, and the indicated fuel conversion efficiency of butanol blending oil was slightly higher at low load but that of D.O. was higher above medium load. The premixed combustion period of D.O. was almost constant regardless of the load. As the load was lower and the butanol blending ratio was higher, the premixed combustion period of butanol blending oil was longer and the premixed combustion period was almost constant at high load regardless of butanol blending ratio. The average heat release rate was higher with increasing loads; especially as butanol blending ratio was increased at high load, the average heat release rate of butanol blending oil was higher than that of D.O. In addition, the calculated maximum. combustion temperature of butanol blending oil was higher than that of D.O. at all loads.

영동지역 주요 침엽수종 및 활엽수종 생엽의 연소특성에 관한 연구 (A Study on Combustion of Living Leaves for Various Coniferous Trees and Broadleaf Trees in Youngdong Areas)

  • 이해평;이시영;박영주
    • 한국안전학회지
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    • 제24권4호
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    • pp.96-103
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    • 2009
  • This study was fulfilled to investigate the forest fire risk of forest fuels based on the combustion characteristics of living leaves of coniferous trees and broadleaf trees naturally growing in Youngdong areas of Gangwon Province by using cone calorimeter and smoke density chamber. According to the result, Pinus densiflora and Pinus rigida among coniferous trees released a greater amount of heat release than other kinds. The total smoke release varied depending on the species, whereas Pinus koraiensis showed the largest amount of smoke release. With regard to maximum smoke density, it was much higher in coniferous trees than in broadleaf trees. With regard to smoke temperature, Pinus densiflora showed the lowest compared to other kinds up until 200s from the ignition, but all most trees uniformly maintained constant temperature of about $70^{\circ}C$ after 200s. The concentrations of CO and $CO_2$ release were drastically increased at about 150s and then gradually decreased thereafter. Pinus densiflora showed a bit higher CO release than broadleaf trees, but there was no distinct difference in $CO_2$ release among tress.

Development of Controlled Release Oral Drug Delivery System by Membrane-Coating Method-I - Preparation and pharmaceutical evaluation of controlled release acetaminophen tablets-

  • Shim, Chang-Koo;Kim, Ki-Man;Kim, Young-Il;Kim, Chong-Kook
    • Archives of Pharmacal Research
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    • 제13권2호
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    • pp.151-160
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    • 1990
  • In order to develop a controlled-release oral drug delivery system (DDS) which sustains the plasma acetaminophen (AAP) concentration for a certain period of time, microporous membrane-coated tablets were prepared and evaluated in vitro. Firstly, highly water-soluble core tablet of AAP were prepared with various formulations by wet granulation and compression technique. Then the core tablets were coated with polyvinychloride (PVC) in which micronized sucrose particles were dispersed. Effect of formula compositions of core tablets and coating suspensions on the pharmaceutical characteristics such as drug release kinetics and membrane stability of the coated tablets was investigated in vitro. AAP was released from the coated tablets as a zero-order rate in a pH-independent manner. This independency of AAP release to pH change from 1.2 to 7.2 is favorable for the controlled oral drug delivery, since it will produce a constant drug release in the stomach and intestine regardless of the pH change in the GI tract. Drug release could be extended upto 10 h according to the coating condition. The release rate could be controlled by changing the formula compositions of the core tablets and coating suspensions, coat weight per each tablet, and especially PVC/sucrose ratio and particle size of the sucrose in the coating suspension. The coated tablets prepared in this study had a fairly good pharmaceutical characteristics in vitro, however, overall evaluation of the coated tablet should await in vivo absorption study in man.

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정용연소기에 있어서 어유의 연소특성 (Combustion Characteristics of Fish Oil in a Constant Volume Combustion Bomb)

  • 서정주
    • 수산해양기술연구
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    • 제28권2호
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    • pp.184-190
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    • 1992
  • The combustion characteristics, ignition delay, p-t, dp/dt, Q-t of diesel oil and fish oil blended diesel oils was investigated according to pressure and temperature in a constant volume combustion bomb. The results are as follows: 1) The influence of temperature and pressure on the ignition delay was almost constant in high temperature, regardless of the blending rates, and the ignition delay was shortest in the 60% blend. 2) The maximum pressure was high in order of with pure diesel oil, with the 20% blend and the 60% blend. 3) The rate of pressure rise was high in order of with pure diesel oil, with the 20% blend and the 60% blend. The rate of maximum pressure rise was significantly higher with pure diesel oil than with two blends. 4) The amount of accumulative heat release was large in order of with pure diesel oil, with the 20% blend and the 60% blend.

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