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The Research about the Correlation Between the Spontaneous Polarization of LuFe2O4 and Behavior of Iron by Mössbauer (뫼스바우어 분광법을 이용한 LuFe2O4의 자발분극과 철 이온의 거동과의 상관관계에 대한 연구)

  • Bang, Bong-Kyu;Kim, Chul-Sung;Kim, Sung-Baek;Cheong, S.W.
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.10-13
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    • 2007
  • Single crystalline, $LuFe_2O_4$, was grown by the floating zone method. The crystal structure was a two-dimensional layered-type rhombohedral($R\={3}mh$) structure, with an $a_0=3.440(2)\;{\AA}\;and\;a\;c_0=25.263(2)\;{\AA}$. The magnetic $N\'{e}el$ temperature($T_N$) was determined to be 250 K. The $M\"{o}ssbauer$ spectrum at 12 K was fitted with four sextet sets which was resulted from the crystal structure. The spectrm at room temperature consisted of three singlets and a doublet with the electric quadrupole splitting. The isomer shift($\delta$) value of the singlet was $0.20{\pm}0.01mm/s$ relative to the Fe metal indicating the $Fe^{3+}$ valence state, and the value of the doublet was $0.70{\pm}0.01mm/s$ indicating $Fe^{2+}$. The $M\"{o}ssbauer$ absorption area ratio between $Fe^{3+}$ and $Fe^{2+}$ at room temperature was 1:1. The doublet phase of spectra gradually disappears by up to 360 K. At 360 K, the spectrum shows the singlet phase. We suggested that the spontaneous polarization effect of $LuFe_2O_4$ was caused by the change of iron behavior.

Risk based policy at big data era: Case study of privacy invasion (빅 데이터 시대 위험기반의 정책 - 개인정보침해 사례를 중심으로 -)

  • Moon, Hyejung;Cho, Hyun Suk
    • Informatization Policy
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    • v.19 no.4
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    • pp.63-82
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    • 2012
  • The world's best level of ICT(Information, Communication and Technology) infrastructure has experienced the world's worst level of ICT accident in Korea. The number of major accidents of privacy invasion has been three times larger than the total number of Internet user of Korea. The cause of the severe accident was due to big data environment. As a result, big data environment has become an important policy agenda. This paper has conducted analyzing the accident case of data spill to study policy issues for ICT security from a social science perspective focusing on risk. The results from case analysis are as follows. First, ICT risk can be categorized 'severe, strong, intensive and individual'from the level of both probability and impact. Second, strategy of risk management can be designated 'avoid, transfer, mitigate, accept' by understanding their own culture type of relative group such as 'hierarchy, egalitarianism, fatalism and individualism'. Third, personal data has contained characteristics of big data such like 'volume, velocity, variety' for each risk situation. Therefore, government needs to establish a standing organization responsible for ICT risk policy and management in a new big data era. And the policy for ICT risk management needs to balance in considering 'technology, norms, laws, and market'in big data era.

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A Theoretical Study of Service Recovery Strategies (서비스실패 회복을 위한 복합적 보상 믹스 연구 : 재서비스와 보상적 할인을 중심으로)

  • Kim, Hyun Sik
    • Journal of Service Research and Studies
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    • v.7 no.4
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    • pp.109-126
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    • 2017
  • Designing cost-effective service recovery strategies mix has been recognized one of important issues by both service researchers and practitioners. In spite of the rising interest in them, there has been scarce studies on them. In this paper, we try to find cost-effective service recovery strategies mix via game-theoretic modeling. Especially, we focus on the possible incentives such as voucher type reward and service re-performance which have different cost structure. We investigated three questions about the topics as follows:(1) Should the service firm use the possible incentive scheme such as voucher and service re-performance for service recovery?, (2) How much voucher and service re-performance is adequate for service recovery under diverse service failure severity level?, (3) How much voucher and service re-performance is adequate for service recovery under diverse threshold level to make the customer repurchase? The results are as follows:(1) The use of both voucher and service re-performance for service recovery results in greater surplus for the service firm. (2) The higher gets the service failure severity level, the higher total incentives are required in the equilibrium. As service failure severity level gets higher, higher level of discount might be more useful to the service firm. However, service re-performance should be cut down above some critical level of service failure severity in the equilibrium. (3) The higher gets the threshold level to make the customer repurchase, the higher incentives are required in the equilibrium, and the higher portion of voucher incentive is required relative to that of service re-performance in the equilibrium.

Petrology of the Syenites in Hapcheon, Korea (경남 합천 지역의 섬장암에 관한 암석학적 연구)

  • Ok, Eun-Young;Kim, Jong-Sun;Lee, Sang-Won
    • The Journal of the Petrological Society of Korea
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    • v.26 no.1
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    • pp.13-43
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    • 2017
  • In the Hapcheon area, hypersthene-bearing monzonite (mangerite) and syenite are recognized. The main minerals of syenite are alkali feldspar, plagioclase, amphibole, biotite, and quartz. Anhedral hornblende and biotite are interstitial between feldspar and quartz, indicating that the hydrous minerals were crystallized later on. Based on petrochemical studies of major elements, syenite is alkaline series, metaluminous, and I-type. The variation patterns in the trace and rare earth elements of mangerite and syenite show the features of subduction-related igneous rock such as depletion of HFSE, relative enrichment in LILE to LREE, and negative Nb-P-Ti anomalies. Based on the experimental data and petrographic characteristics of the syenite, Hapcheon syenitic magma is considered to be formed by partial melting in a dry system. SHRIMP U-Pb zircon data yield the Triassic age as $227.4{\pm}1.4Ma$ in mangerite, $215.3{\pm}1.2Ma$ in syenite, and $217.9{\pm}2.6Ma$ in coarse-grained syenite, respectively. The mangerite age is similar to those of post-collisional plutonic rocks in Hongseong (226~233 Ma), Yangpyeong (227~231 Ma), and Odaesan (231~234 Ma) areas in the Gyeonggi Massif. Syenites were intruded after about 10 Ma. The features seen in the mangereite and syenite rocks can be explained by models such as the continental collision and slab break-off and the lithosphere thinning and asthenosphere upwelling model.

The Observation of Scattering Patterns During Membrane Formation: Spinodal Decomposition and Nucleation Growth (스피노달 분해와 기핵성장에 따른 상분리 과정의 광산란 패턴의 관찰)

  • Kang, Jong-Seok;Huh, Hoon;Lee, Young-Moo
    • Membrane Journal
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    • v.12 no.2
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    • pp.97-106
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    • 2002
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the light scattering patterns with time evolved during water vapor quenching (relative humidity of 53 (${\pm}3)%$ at $26^{\circ}C$ of polysulfone (PSf)/NMP/Alcohol and chlorinated poly(vinyl chloride) (CPVC)/THF/Alcohol, respective1y. Time dependence of the position of the light scattering maximum was observed at PSf dope solutions, confirming spinodal decomposition (SD), while CPVC dope solutions showed a decreased scattered light intensity with an increased q-value, indicating nucleation & growth (NG). For the each system, domain growth rate in the intermediate and late stage of phase separation decreased with increasing the number of carbon of alcohol used as additive (non-solvent). Also, in the early stage for SD, the scattering intensity with time was in accordance with Cahn's linear theory of spinodal decomposition, regardless of types of non-solvent additive. Also, the size scales obtained by SALS were mutually compared to domain sizes gained by FE-SEM measurement. These observations of scattering pattern were much clearly observed for the 20PSf/70NMP/10n-butanol (w/w%) and agreed with the theoretical predictions for scattering patterns of each stage like the early, the intermediate, and the late stage of SD type phase separation. As the scattering maximum was observed at the larger angles (larger q) in the order of n-butanol > n-propanol > methanol > no alcohol, the pore size of final morphology decreased.

The Effects of Solvent and Nonsolvent on Asymmetric Membrane Structure of 6FDA-p-TeMPD Polyimide (6FDA-p-TeMPD 폴리이미드 비대칭막 제조에서 용매와 비용매가 막구조에 미치는 영향)

  • 박노춘;김건중;남세종
    • Membrane Journal
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    • v.8 no.3
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    • pp.157-169
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    • 1998
  • The effects of solvents (DMAc, NMP, 1,4-dioxane) and nonsolvents ($H_2O$, Methanol, n-hexane) on the morphology of 6FDA-p-TeMPD polyimide membrane, prepared by the wet phase inversion method, were studied. In the polymer/solvent/nonsolvent ternary system, the binodal curve, the coagulation value and the relative light transmission were measured, and the solubility parameter difference was calculated. The onset state and rate of liquid-liquid alemixing were predicted and the morphology of membrane was analyzed. It is found that the finger-like pores are formed within discontinuous polymer nodules when the binoclal curve is close to the polymer-solvent (P-S) axis, the coagulation value is small, the reduction of light transmission is easy to occur and the order of solubility parameter difference ($\Delta \delta_{i-j}$) is $\Delta \delta_{S-NS} > \Delta \delta_{P-NS} > \Delta \delta_{P-S}$. The dense skin with small nodules and the sponge type sublayer with macrovoid are formed in the case that the binodal curve is distant from the P-S axis, the onset time of liquid-liquid demixing is long and the order of $\Delta \delta_{i-j}$ is $\Delta \delta_{P-NS} >(\Delta \delta_{S-NS} < > \Delta \delta_{P-S})$. The thick layer of fine nodule coagulation and loosely grown sublayer of nodules appear when the binodal curve is distant from the P-S axis, the onset time of liquid-liquid demixing is very long and the order of $\Delta \delta_{i-j}$$\Delta \delta_{S-NS} > (\Delta \delta_{P-NS}$\lessgtr$ > (\Delta \delta_{P-NS} < >)\Delta \delta_{P-S}$ ).

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Quality Changes of Over-wintering Satsuma Mandarin during Storage by Chitosan and Calcium Treatment and Storage Warehouse (키토산 및 칼슘 처리와 저장고 형태에 따른 월동 온주밀감의 저장 중 품질변화)

  • 고정삼;김성학;고인호
    • Food Science and Preservation
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    • v.9 no.1
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    • pp.85-91
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    • 2002
  • Quality changes of over-wintering satsuma mandarin (Citrus unshiu Marc. var. miyagawa) during storage by chitosan and calcium treatment and type of storage warehouse were investigated. Citrus were treated with 2000-folds diluted iminoctadime-triacetate solution and 1.5% chitosan with 0.5% CaCl$_2$ solutions and were at 30$\^{C}$ far 24 h before storage. The citrus of about 12 kg/26 L plastic container were stored at room temperature, and at 4$\^{C}$ with 87% relative humidity. Chitosan and CaCl$_2$ solution treated citrus fruits were showed lower in decay ratio than the ones without treatment. Also, these chitosan and calcium treated citrus fruits skewed less in weight loss, that seems it also has restraining effect of fruits' transpiration. Decay ratio of citrus with precise temperature and humidity control were lower than the others during storage. Weight loss, moisture content of peel and flesh were decreased slowly during storage. 0.84 ∼0.90% of acid content were decreased on 120 days' storage. Reducing sugar of citrus was decreased rapidly after 90 days, and vitamin C content were also decreased rapidly after 60 days during storage.

Physicochemical Properties of Crosslinked Potato Starch (가교결합 감자 전분의 이화학적 특성)

  • Kim, Hyang-Sook;Lee, Young-Eun
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.573-579
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    • 1996
  • Crosslinked potato starches (XP), from 2,400 to 1,900 anhydroglucose units per crosslinked (AGU/CL), were prepared by reacting with epichlorohydrin. Some of the physicochemical properties of the XPs were then compared with those of native potato and cowpea starches. Crosslinking decreased moisture, protein and ash contents but had no effect on phosphorus content. Water binding capacities of the XPs increased as the degree of crosslinking increased, and that of the XP with 2,100 AGU/CL approached the value of cowpea starch. The absorption maxima of the starch-iodine complex shifted from 594 to 580 nm. Granule size increased slightly and surface appearance of the granule became rough when crosslinked. Both native and crosslinked potato starches showed B type X-ray diffraction pattern, and the relative crystallinity was not affected by crosslinking. Gelatinization temperature and the heat of gelatinization, measured by differential scanning calorimeter (DSC), did not change within the range of crosslinking tested. From X-ray and DSC data, it was concluded that the crosslinking ocurred in the amorphous region of the starch granule.

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Novel Sulfonated Poly(arylene ether sulfone) Composite Membranes Containing Tetraethyl Orthosilicate (TEOS) for PEMFC Applications (고분자 전해질형 연료전지를 위한 TEOS가 함유된 술폰화 폴리아릴렌에테르술폰 복합막의 제조 및 특성)

  • Lee, Keun-Kyu;Kim, Tae-Ho;Hwang, Taek-Sung;Hong, Young-Taik
    • Membrane Journal
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    • v.20 no.4
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    • pp.278-289
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    • 2010
  • A series of composite membranes based on sulfonated poly(arylene ether sulfone) (SPAES) were prepared via addition of tetraethyl orthosilicate (TEOS) and solution casting method. The morphological structure, water uptake, proton conductivity of the resulting composite membranes were extensively investigated as function of the content of TEOS. By the sol-gel reaction, TEOS molecules were not completely converted to $SiO_2$ particles, but formed only oligomer-type. Also, EDS confirms that the resulting silicon dioxide was homogeneously distributed in the composite membranes. As the content of TEOS increased, the prepared membranes increased water uptake and proton conductivity at high temperature and low relative humidity condition. In particular, considerably high proton conductivity (0.015 S/cm) at $120^{\circ}C$ and 48%RH was demonstrated in the composite membrane containing 200% TEOS, which is 10 times greater than that of unmodified SPAES membrane. Also, the composite membranes were found to have enhanced thermal stability compared to the unmodified membrane.

Application of $TiO_2$-Coated Construction Materials for Nicotine Photo-decomposition (니코틴 광분해를 위한 산화티타늄 코팅 건축자재 활용)

  • Jo, Wan-Kuen;Chun, Hee-Dong
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.316-322
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    • 2006
  • The current study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of nocotine which has well known as a representative material of environmental tobacco smoke(ETS). Four different preliminary experiments were performed for the evaluation of nicotine removal using photocatalyst-coated construction materials. The photocatalytic removal of nicotine was investigated for five parameters: dry condition of coating tiles, type of coating sol, number of coatings, relative humidity(RH), and input concentrations. Prior to performing the parameter tests, adsorption of nicotine onto the current experimental system was surveyed. All the variables tested in the present study exhibited to influence the photocatalytic decomposition of Nicotine. A dry condition of high temperature and short dry period presented higher photocatalytic oxidation(PCO) efficiency compared to that of low temperature and long dry period. ST-KO3 sol showed higher decomposition efficiency than E-T Sol. The PCO efficiency increased as the number of coating increased. High humidity and low input concentrations exhibited higher PCO efficiency. Consequently, it is noted that the five parameters tested in the present study should be considered for the application of photocatalyst-coated construction materials in cleaning nicotine in ETS.