• Title/Summary/Keyword: relative surface area

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Application of Ecosystem Model for Eutrophication Control in Coastal Sea of Saemankeum Area -2. Quantitative Management of Pollutant Loading- (새만금 사업지구의 연안해역에서 부영양화관리를 위한 생태계모델의 적용 -2. 오염부하의 정량적 관리-)

  • Kim Jong Gu;Kim Yang Soo;Cho Eun Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.4
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    • pp.356-365
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    • 2002
  • One of the most important factors that cause eutrophication is nutrient materials containing nitrogen and phosphorus which stem from excreation of terrestial sources and release from sediment. Therefore, to improve water quality, the reduction of these nutrients loads should be indispensible. At this study, the three-dimensional numerical hydrodynamic and ecosystem model, which was developed by Institute for Resources and Environment of Japan, were applied to analyze the processes affecting the eutrophication. The residual currents, which were obtained by integrating the simulated tidal currents over 1 tidal cycle, showed the presence of a typical counterclockwise eddies between Gyewha and Garyuk island. Density driven currents were generated westward at surface and eastward at the bottom in Saemankeum area where the fresh waters are flowing into, The ecosystem model was calibrated with the data surveyed in the field of the study area in annual average. The simulated results were fairly good coincided with the observed values within relative error of $30\%$. The simulations of DIN and DIP concentrations were performed using ecosystem model under the conditions of $40\~100\%$ pollution load reductions from pollution sources. In study area, concentration of DIN and DIP were reduced to $59\%$ and $28\%$ in case of the $80\%$ reduction of the input loads from fresh water respectively. But pollution loads from sediment had hardly affected DIN and DIP concentration, The $95\%$ input load abatement is necessary to meet the DIN and DIP concentration of second grade of ocean water quality criteria.

Natural Regeneration Patten of Pine Seedlings on the Burned Forest Site in Gosung, Korea (고성 산불피해지에서 소나무 치수의 자연복원 패턴)

  • Lim, Joo-Hoon;Kim, Jeong-Hwan;Bae, Sang-Won
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.4
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    • pp.222-228
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    • 2012
  • This study was conducted to determine the natural succession process after forest fire by comparing height, relative growth rates in height (RGH), and tree density of pine seedlings with different fire severity. In the area damaged by surface fire, tree density was highest during the first 5 years after fire. However, in the area damaged by crown fire, tree density rapidly increased during first 5 years after fire. Pine seedlings were found only on the place with ridges, barren soil, and the aspect of north. Annual height growth of pine seedlings was decreased with time in all study sites. The empty space in pine stands gradually decreased by the invasion of Quercus species. The forest fire altered the pine forest into oak forest rapidly. In contrast, pine seedlings invaded steadily on the oak forest in the rocky area or the area with ridges.

The Effect of the Crystalline Phase of Zirconia for the Dehydration of Iso-propanol (이소프로판올의 탈수반응에서 지르코니아 촉매의 결정상에 따른 영향)

  • Sim, Hye-In;Park, Jung-Hyun;Cho, Jun Hee;Ahn, Ji-Hye;Choi, Min-Seok;Shin, Chae-Ho
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.208-213
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    • 2013
  • Zirconium hydroxide was synthesized by varying the aging time of the zirconyl chloride octahydrate at $100^{\circ}C$ in aqueous solution and the resulting hydroxides were calcined at $700^{\circ}C$ for 6 h to obtain the crystalline $ZrO_2$. The materials used in this study were characterized by differential thermal analysis (DTA), X-ray diffraction (XRD), $N_2$-sorption, transmission electron microscopy (TEM), $NH_3$ temperature-programmed desorption ($NH_3$-TPD), $CO_2$-TPD and iso-propanol TPD analyses to correlate with catalytic activity for the dehydration of iso-propanol. The pure tetragonal $ZrO_2$ phase was obtained after 24 h aging of zirconium hydroxide and successive calcination at $700^{\circ}C$. The increase of aging time showed the production of smaller particle size $ZrO_2$ resulting that the higher specific surface area and total pore volume. $NH_3$-TPD results revealed that the relative acidity of the catalysts increased along with the increase of aging time. On the other hand, the results of $CO_2$-TPD showed the reverse trend of $NH_3$-TPD results. The best catalytic activity for the dehydration of iso-propanol to propylene was shown over $ZrO_2$ catalyst aged for 168 h which had the highest $S_{BET}$ ($178\;m^2\;g^{-1}$). The catalytic activity could be correlated with high surface area, relative acidity and easy desorption of iso-propanol.

1H Solid-state NMR Methodology Study for the Quantification of Water Content of Amorphous Silica Nanoparticles Depending on Relative Humidity (상대습도에 따른 비정질 규산염 나노입자의 함수량 정량 분석을 위한 1H 고상 핵자기 공명 분광분석 방법론 연구)

  • Oh, Sol Bi;Kim, Hyun Na
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.1
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    • pp.31-40
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    • 2021
  • The hydrogen in nominally anhydrous mineral is known to be associated with lattice defects, but it also can exist in the form of water and hydroxyl groups on the large surface of the nanoscale particles. In this study, we investigate the effectiveness of 1H solid-state nuclear magnetic resonance (NMR) spectroscopy as a robust experimental method to quantify the hydrogen atomic environments of amorphous silica nanoparticles with varying relative humidity. Amorphous silica nanoparticles were packed into NMR rotors in a temperature-humidity controlled glove box, then stored in different atmospheric conditions with 25% and 70% relative humidity for 2~10 days until 1H NMR experiments, and a slight difference was observed in 1H NMR spectra. These results indicate that amount of hydrous species in the sample packed in the NMR rotor is rarely changed by the external atmosphere. The amount of hydrogen atom, especially the amount of physisorbed water may vary in the range of ~10% due to the temporal and spatial inhomogeneity of relative humidity in the glove box. The quantitative analysis of 1H NMR spectra shows that the amount of hydrogen atom in amorphous silica nanoparticles linearly increases as the relative humidity increases. These results imply that the sample sealing capability of the NMR rotor is sufficient to preserve the hydrous environments of samples, and is suitable for the quantitative measurement of water content of ultrafine nominally anhydrous minerals depending on the atmospheric relative humidity. We expect that 1H solid-state NMR method is suitable to investigate systematically the effect of surface area and crystallinity on the water content of diverse nano-sized nominally anhydrous minerals with varying relative humidity.

Preparation of Activated Carbon Fiber-Ceramic Composites and Its Physical Properties (활성탄소섬유-세라믹복합체의 제조 및 물성)

  • 이재춘;박민진;김병균;신경숙;이덕용
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.56-62
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    • 1997
  • The PAN (Polyacrylonitrile) based carbon fiber-ceramic composites (CFCC) were prepared from mixtures of short carbon fibers, phenolic resin and ceramic binder. The effects of carbonization temperature of a pre-cursor fiber, the stabilized PAN fiber, on the specific surface area and the bending strength of the activated CFCC were studied in this work. The precursor fiber was carbonized at 80$0^{\circ}C$ and 100$0^{\circ}C$, respectively. The CFCC were activated at 85$0^{\circ}C$ in carbon dioxide for 10~90 minutes. As the burn-off of the activated CFCC made of the precursor fiber carbonized at 80$0^{\circ}C$ was increased from 37% to 76%, the specific surface area in-creased from 493m2/g to 1090m2/g, and the bending strength decreased from 4.5MPa to 1.4MPa. These values were about two times larger than those of the activated CFCC of which precursor fiber was car-bonized at 100$0^{\circ}C$. The effects of carbonization temperature of a precursor fiber on the specific surface area and bending strength of the activated CCFC were explained by bonding force between carbon fiber and car-bonized phenolic resin as well as by relative shirnkage between carbon fiber and ceramic film.

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The Effects of Nd:YAG Laser Irradiation on the Root Surface;A Scanning Electron Microscopic Study (Nd:YAG 레이저 조사시 치근면에 미치는 효과에 관한 주사전자현미경적 연구)

  • Lee, Su-Jeong;Kim, Soo-Ah;Seo, Seok-Ran;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
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    • v.27 no.3
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    • pp.495-514
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    • 1997
  • The purpose of this study was to evaluate the in vitro effects of Nd:YAG laser irradiation on removal of a root surface smear layer after root planing in comparison with Tetracycline HCl. The 60 extracted human teeth due to severe periodontal disease were vigorously scaled and root planed with Gracey curet. Thirty specimen($5{\times}5{\times}2mm$) were obtained from root planed surface of 30 human teeth and assigned randomly to one of three groups : root planed group(5 specimen), Tetracycline HCI group(5 specimen, burnished for 5 minutes), and Nd:YAG laser group(25 specimen, German Dental Laser, Fotona Twinlight). Nd:YAG laser group was divided into 4 subgroups according to power of 1W, 1.5W, 2W, 3W at frequency to 10Hz. The specimen were then fixed, and examed by Scanning electron microscopic study. 30 of 60 human teeth used to measurement of the intrapulpal temperature rise during laser irradiation. Laser-irradiated surface exhibited various surface texture from relative flat surface to irregular surface with patent dentinal tubules of various shape and size. In some area, the root surface alteration which are carbonization, pit and crater formation and melting and resolidification were observed. The number of exposed dentinal tubules per unit($100_{\mu}m^2$) on tetracycline HCI group was more than that in the laser group below 1.5W of power(150mJ/pulse) and was significantly less than that in laser group above 2W of power(200mJ/pulse)(P<0.OOl). As power increased the intrapulpal temperature rise also increased. The result suggested that the parameter which effectively remove root surface smear layer than tetracycline HCI may cause thermal damage to pulp and root surface alteration result from laser exposure would indicate need for additional instrumentation. Thus, Nd:YAG laser irradiation in these parameter may not be appropriate for clinical use as adjunct to conventional periodontal therapy.

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Volume measurement of limb edema using three dimensional registration method of depth images based on plane detection (깊이 영상의 평면 검출 기반 3차원 정합 기법을 이용한 상지 부종의 부피 측정 기술)

  • Lee, Wonhee;Kim, Kwang Gi;Chung, Seung Hyun
    • Journal of Korea Multimedia Society
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    • v.17 no.7
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    • pp.818-828
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    • 2014
  • After emerging of Microsoft Kinect, the interest in three-dimensional (3D) depth image was significantly increased. Depth image data of an object can be converted to 3D coordinates by simple arithmetic calculation and then can be reconstructed as a 3D model on computer. However, because the surface coordinates can be acquired only from the front area facing Kinect, total solid which has a closed surface cannot be reconstructed. In this paper, 3D registration method for multiple Kinects was suggested, in which surface information from each Kinect was simultaneously collected and registered in real time to build 3D total solid. To unify relative coordinate system used by each Kinect, 3D perspective transform was adopted. Also, to detect control points which are necessary to generate transformation matrix, 3D randomized Hough transform was used. Once transform matrices were generated, real time 3D reconstruction of various objects was possible. To verify the usefulness of suggested method, human arms were 3D reconstructed and the volumes of them were measured by using four Kinects. This volume measuring system was developed to monitor the level of lymphedema of patients after cancer treatment and the measurement difference with medical CT was lower than 5%, expected CT reconstruction error.

A Study on the Assessment of the Contamination by Acid Mine Drainage in Abandoned Coal Mines (국내폐탄광의 산성폐수 오염도 평가에 관한 연구)

  • 최우진
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.31-38
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    • 1997
  • Temporal and spatial comparisons of acid mine drainage contaminated waters are difficult because of the complex physico-chemical nature of the pollutant. In the present study, an acid mine drainage index has been developed and evaluated for the assessment of surface waters. AMD index is calculated using a modified arithmetic weighted index using seven parameters which are most indicative of AMD contamination, i. e. pH value, sulphate, iron, zinc, aluminum, copper and manganese. Weighting is used to express the relative indicator value of each parameter. The proposed AMD index is used to quantify contamination from acid mine drainage over ten different old mine sites and assess the degree of impact on surface on surface waters. As a result of AMD evaluation, the Sukbong Mine located near the Moonkyung province showed lowest AMD value indicating the worst acid mine drainage quality. In overall, Youngdong mine sites showed higher contaimination compared to the other mine sites including Youngsuh, Choongbu, Suhbu and Nambu area.

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A Study on the Local Climate in the Vicinity of Duckyang Bay , Korea (득량만일원의 국지기상 환경의 특성에 관한 연구)

  • 김유근
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.4
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    • pp.398-411
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    • 1992
  • The characteristics of local climate in the vicinity of Duckyang Bay have been investigated with the analysis of the surface observation data of Gohug District and the aerological data of Kwangju. In principal features of local climate, the annual range in temperature appeared identical with the mean value(24~$25^{\circ}C$) of the south coastal area, and evaporation from April to September was likely less than precipitation. The average speed of surface wind in Summer seemed higher than in other seasons on account of wea breeze. Relative humidity was 74%, annual average. In the mean cloud cover Summer(6.4) showed greater deal of amount than Winter(4.2). Duration of sunshine was the longest in May(268.4hrs), while the shortest in February(188.4hrs). The amount of the precipitable water was the greatest in July, whereas the least in January, and in Summer the greatest, in Autumn the second greatest, and in Spring the third greatest, and in Winter the least in consideration of seasonal orders. The Summer deviation was most remarkable around all sides. The direction of vector wind appeared the most changeable on the earth surface. At an altitude of 300mb all the winds blew west around all months. Moreover, water vapor transport was measured to be the greatest in Summer; while the least in Winter. So was the deviation of water vapor transport. And lastly frequency of occurrence of days in which a little cloud appeared(less than 5/10) was high except for Summer, when northerly winds blew; while frequency of occurrence of day plenty of clouds floated was outstandingly high at the time of strong southerly winds.

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The Geochemical Behaviour and Environmental Pollution of Pb, Zn, Mn and Cd in Interstitial Waters and Sediments from a Retention Pond along the A-71 Highway, France (프랑스 A-71고속도로변에 설치된 침전조에서 채취된 간극수와 퇴적물에 함유된 Pb, Zn, Mn 및 Cd의 지화학적 행동 및 오염에 관한 연구)

  • Lee, Pyeong-Koo
    • Economic and Environmental Geology
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    • v.30 no.4
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    • pp.341-352
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    • 1997
  • Retention ponds have been dug along some of the motorways in France to minimize environmental pollution by keeping pollutants from spreading over the surrounding area. In order to study heavy metal pollution and diagenetic behaviour of sediments, eight core samples were collected from the bottom of a retention pond located along the A-71 motorway in Sologne. The metal concentrations in interstitial waters and extractable metal concentrations in sediment layers using sequential chemical extraction method were determined. The depth distributions of Pb, Zn and Cd concentrations in interstitial water and particulate sediments were studied, and distribution coefficients (KD) were also determined to investigate the environmental mobility of these elements. In addition. the index of geoaccumulation and the Fe-normalized enrichment factor were calculated to differentiate the natural accumulation from the anthropogenic pollution. The vertical concentration profiles of heavy metals in core sediments indicate that surface enrichments (0~2 cm) of Pb, Zn, Cd and organic carbon were always observed at each core sample, due to the early diagenesis. However, the major factor contributing to the accumulation of Cd at the sediment surface is attributed to the dissolution of Cd from polluted roadside soil during periods of rainstorms and its subsequent redeposition on the sediment surface after being carried to the retention pond. A comparison of the KD values indiactes that a decrease in the KD values for Pb and Zn was observed with depth while KD values for Cd increase. According to the KD values. the relative mobility of studied metals was determined as following: Mn>Zn>Cd>Pb, for the upper layer, and Mn>Cd>Zn>Pb, for the lower layers.

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