• Title/Summary/Keyword: relative error

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Coincidence Summing Corrections in HPGe Gamma Ray Spectrometry in Marinelli-beakers with Efficiency (효율을 적용한 마리넬리 비이커에서 HPGe 감마선 분광분석법의 동시합성보정)

  • Jang, Eun-Sung;Lee, Hyo-Yeong
    • Journal of the Korean Society of Radiology
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    • v.12 no.5
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    • pp.557-563
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    • 2018
  • Coincidence summing correction effects are known to be greater as the efficiency of the detector increases and as the distance between the source and the detector increases. A point source($^{60}Co$) was used to vary the distance in the direction of the detector's center axis and in the radial direction to obtain the P/T ratio for Coincidence summing correction calibration. In this study, values for coincidence summing corrected calibration of the values in the central and radial directions were applied to the mixed volume source(450 ml CRM source) to compare the overall peak efficiency change according to P/T with Geant4. In addition, the efficiency obtained from the mapping method is applied to the seaweed, a marine sample, and the compatibility of the P/T ratio with the detector and sample very dose together. The efficiency corrected to 1,836 keV was applied to the energy zone affected by the efficiency of 500 keV and the relative error of the measured and corrected values was well matcched by the 3.2 % peak efficiency correction. As with 450 mL CRM source, the larger the volume, the lower the P/T ratio was by ${\pm}5%$. This is due to the increased scattering of gamma-rays emitted as the source becomes farther away from the detector, and this change in P/T has been confirmed to affect the Coincidence summing corrected peak efficiency.

Cloud Detection Using HIMAWARI-8/AHI Based Reflectance Spectral Library Over Ocean (Himawari-8/AHI 기반 반사도 분광 라이브러리를 이용한 해양 구름 탐지)

  • Kwon, Chaeyoung;Seo, Minji;Han, Kyung-Soo
    • Korean Journal of Remote Sensing
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    • v.33 no.5_1
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    • pp.599-605
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    • 2017
  • Accurate cloud discrimination in satellite images strongly affects accuracy of remotely sensed parameter produced using it. Especially, cloud contaminated pixel over ocean is one of the major error factors such as Sea Surface Temperature (SST), ocean color, and chlorophyll-a retrievals,so accurate cloud detection is essential process and it can lead to understand ocean circulation. However, static threshold method using real-time algorithm such as Moderate Resolution Imaging Spectroradiometer (MODIS), Advanced Himawari Imager (AHI) can't fully explained reflectance variability over ocean as a function of relative positions between the sun - sea surface - satellite. In this paper, we assembled a reflectance spectral library as a function of Solar Zenith Angle (SZA) and Viewing Zenith Angle (VZA) from ocean surface reflectance with clear sky condition of Advanced Himawari Imager (AHI) identified by NOAA's cloud products and spectral library is used for applying the Dynamic Time Warping (DTW) to detect cloud pixels. We compared qualitatively between AHI cloud property and our results and it showed that AHI cloud property had general tendency toward overestimation and wrongly detected clear as unknown at high SZA. We validated by visual inspection with coincident imagery and it is generally appropriate.

A Study of New Modified Neyman-Scott Rectangular Pulse Model Development Using Direct Parameter Estimation (직접적인 매개변수 추정방법을 이용한 새로운 수정된 Neyman-Scott 구형펄스모형 개발 연구)

  • Shin, Ju-Young;Joo, Kyoung-Won;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.44 no.2
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    • pp.135-144
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    • 2011
  • Direct parameter estimation method is verified with various models based on Neyman-Scott rectangular pulse model (NSRPM). Also, newly modified NSRPM (NMSRPM) that uses normal distribution is developed. Precipitation data observed by Korea Meteorological Administration (KMA) for 47 years is applied for parameter estimation. For model performance verification, we used statistics, wet ratio and precipitation accumulate distribution of precipitation generated. The comparison of statistics indicates that absolute relative error (ARE)s of the results from NSRPM and modified NSRPM (MNSRPM) are increasing on July, August, and September and ARE of NMNSRPM shows 10.11% that is the smallest ARE among the three models. NMNSRPM simulates the characteristics of precipitation statistics well. By comparing the wet ratio, MNSRPM shows the smallest ARE that is 16.35% and by using the graphical analysis, we found that these three models underestimate the wet ratio. The three models show about 2% of ARE of precipitation accumulate probability. Those results show that the three models simulate precipitation accumulate probability well. As the results, it is found that the parameters of NSRPM, MNSRPM and NMNSRPM are able to be estimated by the direct parameter estimation method. From the results listed above, we concluded that the direct parameter estimation is able to be applied to various models based on NSRPM. NMNSRPM shows good performance compared with developed model-NSRPM and MNSRPM and the models based on NSRPM can be developed by the direct parameter estimation method.

DETERMINATION OF MOISTURE AND NITROGEN ON UNDRIED FORAGES BY NEAR INFRARED REFLECTANCE SPECTROSCOPY(NIRS)

  • Cozzolino, D.;Labandera, M.;Inia La Estanzuela
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1620-1620
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    • 2001
  • Forages, both grazed and conserved, provide the basis of ruminant production systems throughout the world. More than 90 per cent of the feed energy consumed by herbivorous animals world - wide were provided by forages. With such world - wide dependence on forages, the economic and nutritional necessity of been able to characterize them in a meaningful way is vital. The characterization of forages for productive animals is becoming important for several reasons. Relative to conventional laboratory procedures, Near Infrared Reflectance Spectroscopy (NIRS) offers advantages of simplicity, speed, reduced chemical waste, and more cost-effective prediction of product functionality. NIR spectroscopy represents a radical departure from conventional analytical methods, in that entire sample of forage is characterized in terms of its absorption properties in the near infrared region, rather than separate subsamples being treated with various chemicals to isolate specific components. This forces the analyst to abandon his/her traditional narrow focus on the sample (one analyte at a time) and to take a broader view of the relationship between components within the sample and between the sample and the population from which it comes. forage is usually analysed by NIRS in dry and ground presentation. Initial success of NIRS analysis of coarse forages suggest a need to better understand the potential for analysis of minimally processed samples. Preparation costs and possible compositional alterations could be reduced by samples presented to the instrument in undried and unground conditions. NIRS has gained widespread acceptance for the analysis of forage quality constituents on dry material, however little attention has been given to the use of NIRS for chemical determinations on undried and unground forages. Relatively few works reported the use of NIRS to determine quality parameters on undried materials, most of them on both grass and corn silage. Only two works have been found on the determination of quality parameters on fresh forages. The objectives of this paper were (1) to evaluate the use of NIRS for determination of nitrogen and moisture on undried and unground forage samples and (2) to explore two mathematical treatments and two NIR regions to predict chemical parameters on fresh forage. Four hundred forage samples (n: 400) were analysed in a NIRS 6500 instrument (NIR Systems, PA, USA) in reflectance mode. Two mathematical treatments were applied: 1,4,4,1 and 2,5,5,2. Predictive equations were developed using modified partial least squares (MPLS) with internal cross - validation. Coefficient of determination in calibration (${R^2}_{CAL}$) and standard error in cross-validation (SECV) for moisture were 0.92 (12.4) and 0.92 (12.4) for 1,4,4,1 and 2,5,5,2 respectively, on g $kg^{-1}$ dry weight. For crude protein NIRS calibration statistics yield a (${R^2}_{CAL}$) and (SECV) of 0.85 (19.8) and 0.85 (19.6) for 1,4,4,1 and 2,5,5,2 respectively, on a dry weight. It was concluded that NIRS is a suitable method to predict moisture and nitrogen on fresh forage without samples preparation.

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APPLICATION STUDY OF CHEMOINFOMETRICAL NEAR-INFRARED SPECTROSCOPY IN PHARMACEUTICAL INDUSTRY

  • Otsuka, Makoto;Kato, Fumie;Matsuda, Yoshihisa
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.2111-2111
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    • 2001
  • A chemoinfometrical method for evaluating the quantitative determination of crystallinity one polymorphs based on fourie-transformed near-infrared (FT-NIR) spectroscopy was established. A direct comparison of the data with the ones collected from using the and compared with the conventional powder X-ray diffraction method was performed. [Method] The pPure a and g forms of indomethacin (IMC) were prepared by reportedusing published methods. Six kinds of standard samples obtained by physically mixing of a and g forms. After the powder X-ray diffraction profiles of samples have been measured, the intensity values were normalized to against the intensity of silicon powder as the as an external standard. The calibration curves for quantification of crystal content were based upon the total relative intensity of four diffraction peaks from of the form g crystal. FT-NIR spectra of six calibration sample sets were recorded 5 times with the NIR spectrometer (BRAN+LUEBBE). Chemoinfometric analysis was performed on the NIR spectral data sets by applying the principal component regression (PCR). [Results] The relation between the actual and predicted polymorphic contents of form g IMC measured using by the X-ray diffraction method shows a good straight linen linear relation., and it has slope of 0.023, an intercept of 0.131 and a correlation coefficient of 0.986. PCR analyses wereis was performed based on normalized NIR spectra sets offer standard samples of known content of IMC g form. IMC. A calibration equation was determined to minimize the root mean square error of the predictionthe prediction. Figure 1 shows a plot of the calibration data obtained by NIR method between the actual and predicted contents of form g IMC. The predicted values were reproducible and had a smaller standard deviation. Figure 2 shows that the plot for the predicted transformation rate (%) of form a IMC to form g as measured by X-ray diffractomeoy against to those as measured by NIR method. The plot has a slope of 1.296, an intercept of 1,109, and a correlation coefficient of 0.992. The line represents a satisfactory correlation between the two predicted values of form g IMC content. Thus NIR spectroscopy is an effective method for the evaluation to the pharmaceutical products of quantitative of polymorph.

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COMPARISON OF LINEAR AND NON-LINEAR NIR CALIBRATION METHODS USING LARGE FORAGE DATABASES

  • Berzaghi, Paolo;Flinn, Peter C.;Dardenne, Pierre;Lagerholm, Martin;Shenk, John S.;Westerhaus, Mark O.;Cowe, Ian A.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1141-1141
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    • 2001
  • The aim of the study was to evaluate the performance of 3 calibration methods, modified partial least squares (MPLS), local PLS (LOCAL) and artificial neural network (ANN) on the prediction of chemical composition of forages, using a large NIR database. The study used forage samples (n=25,977) from Australia, Europe (Belgium, Germany, Italy and Sweden) and North America (Canada and U.S.A) with information relative to moisture, crude protein and neutral detergent fibre content. The spectra of the samples were collected with 10 different Foss NIR Systems instruments, which were either standardized or not standardized to one master instrument. The spectra were trimmed to a wavelength range between 1100 and 2498 nm. Two data sets, one standardized (IVAL) and the other not standardized (SVAL) were used as independent validation sets, but 10% of both sets were omitted and kept for later expansion of the calibration database. The remaining samples were combined into one database (n=21,696), which was split into 75% calibration (CALBASE) and 25% validation (VALBASE). The chemical components in the 3 validation data sets were predicted with each model derived from CALBASE using the calibration database before and after it was expanded with 10% of the samples from IVAL and SVAL data sets. Calibration performance was evaluated using standard error of prediction corrected for bias (SEP(C)), bias, slope and R2. None of the models appeared to be consistently better across all validation sets. VALBASE was predicted well by all models, with smaller SEP(C) and bias values than for IVAL and SVAL. This was not surprising as VALBASE was selected from the calibration database and it had a sample population similar to CALBASE, whereas IVAL and SVAL were completely independent validation sets. In most cases, Local and ANN models, but not modified PLS, showed considerable improvement in the prediction of IVAL and SVAL after the calibration database had been expanded with the 10% samples of IVAL and SVAL reserved for calibration expansion. The effects of sample processing, instrument standardization and differences in reference procedure were partially confounded in the validation sets, so it was not possible to determine which factors were most important. Further work on the development of large databases must address the problems of standardization of instruments, harmonization and standardization of laboratory procedures and even more importantly, the definition of the database population.

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Geocoding of the Free Stereo Mosaic Image Generated from Video Sequences (비디오 프레임 영상으로부터 제작된 자유 입체 모자이크 영상의 실좌표 등록)

  • Noh, Myoung-Jong;Cho, Woo-Sug;Park, Jun-Ku;Kim, Jung-Sub;Koh, Jin-Woo
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.29 no.3
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    • pp.249-255
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    • 2011
  • The free-stereo mosaics image without GPS/INS and ground control data can be generated by using relative orientation parameters on the 3D model coordinate system. Its origin is located in one reference frame image. A 3D coordinate calculated by conjugate points on the free-stereo mosaic images is represented on the 3D model coordinate system. For determining 3D coordinate on the 3D absolute coordinate system utilizing conjugate points on the free-stereo mosaic images, transformation methodology is required for transforming 3D model coordinate into 3D absolute coordinate. Generally, the 3D similarity transformation is used for transforming each other 3D coordinates. Error of 3D model coordinates used in the free-stereo mosaic images is non-linearly increased according to distance from 3D model coordinate and origin point. For this reason, 3D model coordinates used in the free-stereo mosaic images are difficult to transform into 3D absolute coordinates by using linear transformation. Therefore, methodology for transforming nonlinear 3D model coordinate into 3D absolute coordinate is needed. Also methodology for resampling the free-stereo mosaic image to the geo-stereo mosaic image is needed for overlapping digital map on absolute coordinate and stereo mosaic images. In this paper, we propose a 3D non-linear transformation for converting 3D model coordinate in the free-stereo mosaic image to 3D absolute coordinate, and a 2D non-linear transformation based on 3D non-linear transformation converting the free-stereo mosaic image to the geo-stereo mosaic image.

Sensitivity Analysis of Surface Reflectance Retrieved from 6SV LUT for Each Channel of KOMPSAT-3/3A (KOMPSAT-3/3A 채널별 6SV 조견표의 지표반사도 민감도 분석)

  • Jung, Daeseong;Jin, Donghyun;Seong, Noh-Hun;Lee, Kyeong-Sang;Seo, Minji;Choi, Sungwon;Sim, Suyoung;Han, Kyung-Soo;Kim, Bo-Ram
    • Korean Journal of Remote Sensing
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    • v.36 no.5_1
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    • pp.785-791
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    • 2020
  • The radiance measured from satellite has noise due to atmospheric effect. Atmospheric correction is the process of calculating surface reflectance by removing atmospheric effect and surface reflectance is calculated by the Radiative Transfer Model (RTM)-based Look-Up Table (LUT). In general, studies using a LUT make LUT for each channel with the same atmospheric and geometric conditions. However, atmospheric effect of atmospheric factors do not react sensitively in the same channel. In this study, the LUT for each channel of Korea Multi-Purpose SATellite (KOMPSAT)-3/3A was made under the same atmospheric·geometric conditions. And, the accuracy of the LUT was verified by using the simulated Top of Atmosphere radiation and surface reflectance in the RTM. As a result, the relative error of the surface reflectance in the blue channel that sensitive to the aerosol optical depth was 81.14% at the maximum, and 42.67% in the NIR (Near Infrared) channel.

Wearable wireless respiratory monitoring system (의복착용형 무선 호흡모니터 시스템)

  • Lee, In-Kwang;Kim, Seong-Sik;Jang, Jong-Chan;Kim, Koon-Jin;Kim, Kyung-Ah;Lee, Tae-Soo;Cha, Eun-Jong
    • Journal of Sensor Science and Technology
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    • v.17 no.2
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    • pp.133-142
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    • 2008
  • Respiration is induced by muscular contraction of the chest and abdomen, resulting in the abdominal volume change. Thus, continuous measurement of the abdominal dimension enables to monitor breathing activity. Conductive rubber cord has been previously introduced and tested to develop wearable application for respiratory measurements. The present study implemented wireless wearable respiratory monitoring system with the conductive rubber cord in the patient's pants. Signal extraction circuitry was developed to obtain the abdominal circumference changes reflecting the lung volume variation caused by respiratory activity. Wireless transmission was followed based on the zigbee communication protocol in a size of 65mm${\times}$105mm easily put in pocket. Successful wireless monitoring of respiration was performed in that breathing frequency was accurately estimated as well as different breathing patterns were easily recognized from the abdominal signal. $CO_2$ inhalation experiment was additionally performed in purpose of quantitative estimation of tidal volume. Air mixed with $0{\sim}5%\;CO_2$was inhaled by 4 normal males and the respiratory air flow rate, abdominal dimension change, and end tidal $CO_2$ concentration were simultaneously measured in steady state. $CO_2$ inhalation increased the tidal volume in normal physiological state with a correlation coefficient of 0.90 between the tidal volume and the end tidal $CO_2$ concentration. The tidal volume estimated from the abdominal signal linearly correlated with the accurate tidal volume measured by pneumotachometer with a correlation coefficient of 0.88 with mean relative error of approximately 8%. Therefore, the tidal volume was accurately estimated by measuring the abdominal dimension change.

Real-time Upstream Inflow Forecasting for Flood Management of Estuary Dam (담수호 홍수관리를 위한 상류 유입량 실시간 예측)

  • Kang, Min-Goo;Park, Seung-Woo;Kang, Moon-Seong
    • Journal of Korea Water Resources Association
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    • v.38 no.12 s.161
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    • pp.1061-1072
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    • 2005
  • A hydrological grey model is developed to forecast short-term river runoff from the Naju watershed located at upstream of the Youngsan estuary dam in Korea. The runoff of the Naju watershed is measured in real time at the Naju streamflow gauge station, which is a key station for forecasting the upstream inflow and operating the gates of the estuary dam in flood period. The model's governing equation is formulated on the basis of the grey system theory. The model parameters are reparameterized in combination with the grey system parameters and estimated with the annealing-simplex method In conjunction with an objective function, HMLE. To forecast accurately runoff, the fifth order differential equation was adopted as the governing equation of the model in consideration of the statistic values between the observed and forecast runoff. In calibration, RMSE values between the observed and simulated runoff of two and six Hours ahead using the model range from 3.1 to 290.5 $m^{3}/s,\;R^2$ values range from 0.909 to 0.999. In verification, RMSE values range from 26.4 to 147.4 $m^{3}/s,\;R^2$ values range from 0.940 to 0.998, compared to the observed data. In forecasting runoff in real time, the relative error values with lead-time and river stage range from -23.4 to $14.3\%$ and increase as the lead time increases. The results in this study demonstrate that the proposed model can reasonably and efficiently forecast runoff for one to six Hours ahead.