• 제목/요약/키워드: relative efficient

검색결과 860건 처리시간 0.027초

Very Efficient Nucleophilic Aromatic Fluorination Reaction in Molten Salts: A Mechanistic Study

  • Jang, Sung-Woo;Park, Sung-Woo;Lee, Byoung-Se;Chi, Dae-Yoon;Song, Choong-Eui;Lee, Sung-Yul
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.881-884
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    • 2012
  • We report a quantum chemical study of an extremely efficient nucleophilic aromatic fluorination in molten salts. We describe that the mechanism involves solvent anion interacting with the ion pair nucleophile $M^+F^-$(M = Na, K, Rb, Cs) to accelerate the reaction. We show that our proposed mechanism may well explain the excellent efficiency of molten salts for SNAr reactions, the relative efficacy of the metal cations, and also the observed large difference in rate constants in two molten salts $(n-C_4H_9)_4N^+\;CX_3SO_3^-$, (X=H, F) with slightly different sidechain ($-CH_3$ vs. $-CF_3$).

Numerical Simulation of Unsteady Rotor Flow Using an Unstructured Overset Mesh Flow Solver

  • Jung, Mun-Seung;Kwon, Oh-Joon
    • International Journal of Aeronautical and Space Sciences
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    • 제10권1호
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    • pp.104-111
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    • 2009
  • An unstructured overset mesh method has been developed for the simulation of unsteady flow fields around isolated rotors and rotor-fuselage configurations. The flow solver was parallelized for the efficient calculation of complicated flows requiring a large number of cells. A quasi-unsteady mesh adaptation technique was adopted to enhance the spatial accuracy of the solution and to better resolve the rotor wake. The method has been applied to calculate the flow fields around rotor-alone and rotor-fuselage configurations in forward flight. Validations were made by comparing the predicted results with those of measurements. It was demonstrated that the present method is efficient and robust for the prediction of unsteady time-accurate flow fields involving multiple bodies in relative motion.

Improving buckling response of the square steel tube by using steel foam

  • Moradi, Mohammadreza;Arwade, Sanjay R.
    • Structural Engineering and Mechanics
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    • 제51권6호
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    • pp.1017-1036
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    • 2014
  • Steel tubes have an efficient shape with large second moment of inertia relative to their light weight. One of the main problems of these members is their low buckling resistance caused from having thin walls. In this study, steel foams with high strength over weight ratio is used to fill the steel tube to beneficially modify the response of steel tubes. The linear eigenvalue and plastic collapse FE analysis is done on steel foam filled tube under pure compression and three point bending simulation. It is shown that steel foam improves the maximum strength and the ability of energy absorption of the steel tubes significantly. Different configurations with different volume of steel foam and composite behavior is investigated. It is demonstrated that there are some optimum configurations with more efficient behavior. If composite action between steel foam and steel increases, the strength of the element will improve, in a way that, the failure mode change from local buckling to yielding.

전력수요측의 고효율기기 확산을 고려한 전원개발계획 비교실험 (A Comparative Simulation on Generation Expansion Planning Considering the Diffusion of High Efficient End-Uses)

  • 장승찬;조형준;김발호;김정훈
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 A
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    • pp.328-330
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    • 2000
  • This paper presents an experimental comparison between the conventional generation expansion planning and DSM incorporated one. As a DSM measure, diffusion of high efficient end-uses is considered and its impact will be targeted at the strategic energy conservation. A revised probabilistic production simulation is proposed by modifying the equivalent load duration curve (ELDC) with the capacity deconvolution of DSM end-use. To investigate long-term DSM impacts relative to the conventional planning, WASP model is applied and the effectiveness of DSM planning as an electricity resources is demonstrated.

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3차원 연결선 모형의 효율적인 커패시턴스 추출 방법 (Efficient Capacitance Extraction Method for 3D Interconnect Models)

  • 김정학;성윤모;김석윤
    • 대한전자공학회논문지SD
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    • 제41권11호
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    • pp.53-59
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    • 2004
  • 본 논문은 3차원 연결선 모형을 이용하여 효율적으로 회로 연결선에 기생하는 커패시턴스 성분을 추출하는 방법을 제안한다. 제안한 방법은 경험식에 의한 방법 중 2차원 연결선 모형의 커패시턴스를 추출하는 알고리즘을 이용하여 수행시간을 개선하였고, 정확도의 오차를 줄이기 위하여 3차원 커패시턴스 추출에서 이용되는 모형화 방법을 적용하였다. 이 방법은 FastCap을 이용하여 실험한 결과와 비교하면 1.8%의 오차 범위에서 952배의 시간 이득을 얻을 수 있다. 제안한 방법은 VLSI 시스템의 칩 내 외부 연결선의 전기적 변수 추출에 효과적으로 이용될 수 있을 것이다.

Dynamics of the Macpherson Strut Motor-Vehicle Suspension System in Point and Joint Coordinates

  • Attia, Hazem-Ali
    • Journal of Mechanical Science and Technology
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    • 제17권9호
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    • pp.1287-1296
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    • 2003
  • In this paper the dynamic analysis of the Macpherson strut motor-vehicle suspension system is presented. The equations of motion are formulated using a two-step transformation. Initially, the equations of motion are derived for a dynamically equivalent constrained system of particles that replaces the rigid bodies by applying Newton's second law The equations of motion are then transformed to a reduced set in terms of the relative joint variables. Use of both Cartesian and joint variables produces an efficient set of equations without loss of generality For open chains, this process automatically eliminates all of the non-working constraint forces and leads to an efficient solution and integration of the equations of motion. For closed loops, suitable joints should be cut and few cut-joints constraint equations should be included for each closed chain. The chosen suspension includes open and closed loops with quarter-car model. The results of the simulation indicate the simplicity and generality of the dynamic formulation.

퍼머컬츄어 디자인의 원리 (The Principles of Permaculture Design)

  • Miller, James H.
    • 한국유기농업학회지
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    • 제9권4호
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    • pp.53-69
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    • 2001
  • The word \"permaculture\" is a contraction of \"permanent agriculture\" or \"permanent culture\". Permaculture principles are designed to support (or ensure) the survival of humanity, the earth and all on it, and, to improve our standard of living, Permaculture can be defined as : a design system for creating sustainable human environments that can be (relatively) easily constructed and maintained. The principles of permaculture designs are relative location every element (such as house , rice paddy, road, esc) is placed in relation to each other such that each assists the other : each element performs multiple functions ; each function is supported by many elements : energy efficient planning ; using biological resources rather than fossil fuels : energy cycling on site (both fuel and human energy) : Using and accelerating natural plant succession to establish favourable sites and soils ; poly-culture and diversity of beneficial species for a productive, interactive system ; use of edge and natural patterns for best effect. These principles can be used for any permaculture design, in any climate, and at any scale. There has been very little scientific examination of Permaculture, and as such, it must be viewed as a design philosophy.viewed as a design philosophy.

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A Study on the Optimum Structural Design for Oil Tankers Using Multi-Objective Optimization

  • Jang, Chang-Doo;Shin, Sang-Hun
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1998년도 봄 학술발표회 논문집
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    • pp.245-253
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    • 1998
  • Recently, the importance of multi-objective optimization techniques and stochastic search methods is increasing. The stochastic search methods have the concepts of the survival of the fittest and natural selection such as genetic algorithms(GA), simulated annealing(SA) and evolution strategies (ES). As many accidents of oil tankers cause marine pollution, oil tankers of double hull or mid deck structure are being built to minimize the marine pollution. For the improvement of oil tanker design technique, an efficient optimization technique is proposed in this study. Multi-objective optimization problem of weight and cost of double hull and mid deck tanker is formulated. Discrete design variables are used considering real manufacturing, and the concept of relative production cost is also introduced. The ES method is used as an optimization technique, and the ES algorithm was developed to generate a more efficient Pareto optimal set.

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An Analysis of Container Port Efficiency in ASEAN

  • Seo, Young-Joon;Ryoo, Dong-Keun;Aye, Myo-Nyein
    • 한국항해항만학회지
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    • 제36권7호
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    • pp.535-544
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    • 2012
  • In order to improve the overall ASEAN maritime transport network, each port's efficiency is regarded as a crucial factor that should be calculated periodically. This study evaluated the relative efficiency of container port operations of 32 ports belonging to 9 ASEAN nations using Data Envelopment Analysis (DEA). It found that 2 out of 32 ports in 2010 were measured as efficient ports. This study yielded two major findings. Firstly, the ports assessed as inefficient need to benchmark similar ports in size and structure from the ports that are assessed as efficient to improve their efficiency. Secondly, these results could be used to determine potential candidates and country for an international port development co-operation programme with Korea to improve the performance of the entire ASEAN port network by developing the infrastructures of ill-equipped ports.

TV 가이드 영역에서의 음성기반 멀티모달 사용 유형 분석 (Speech-Oriented Multimodal Usage Pattern Analysis for TV Guide Application Scenarios)

  • 김지영;이경님;홍기형
    • 대한음성학회지:말소리
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    • 제58호
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    • pp.101-117
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    • 2006
  • The development of efficient multimodal interfaces and fusion algorithms requires knowledge of usage patterns that show how people use multiple modalities. We analyzed multimodal usage patterns for TV-guide application scenarios (or tasks). In order to collect usage patterns, we implemented a multimodal usage pattern collection system having two input modalities: speech and touch-gesture. Fifty-four subjects participated in our study. Analysis of the collected usage patterns shows a positive correlation between the task type and multimodal usage patterns. In addition, we analyzed the timing between speech-utterances and their corresponding touch-gestures that shows the touch-gesture occurring time interval relative to the duration of speech utterance. We believe that, for developing efficient multimodal fusion algorithms on an application, the multimodal usage pattern analysis for the given application, similar to our work for TV guide application, have to be done in advance.

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