• Title/Summary/Keyword: relative effects

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Selectivity of between K+ and Na+ Ions to 12-Crown-4: QSPR Analysis by a Monte Carlo Simulation Study

  • Kim, Hag-Sung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.431-437
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    • 2008
  • The solvent effects on the relative free energies of binding of K+ and Na+ ions to 12-crown-4 and Dlog Ks (the difference of stability constant of binding) have been investigated by a Monte Carlo simulation of statistical perturbation theory (SPT) in several solvents. Comparing the relative free energies of binding of K+ and Na+ ions to 12-crown-4, in CH3OH of this study with experimental works, there is a good agreement among the studies. We have reported here the quantitative solvent-polarity relationships (QSPR) studied on the solvent effects the relative free energies of binding of K+ and Na+ ions to 12-crown-4. We noted that DN(donor number) dominates the differences in relative solvation Gibbs free energies of K+ and Na+ ions and DN dominates the negative values in differences in the stability constant (Dlog Ks) as well as the relative free energies of binding of K+ and Na+ ions to 12-crown-4 and p* (Kamlet-Tafts solvatochromic parameters) dominates the positive values in differences in the stability constant (Dlog Ks) as well as the relative free energies of binding of K+ and Na+ ions to 12-crown-4.

Plastic Deformation Behavior of Sintered Fe-Based Alloys for Light-Weight Automotive Components

  • Kang, Yohan;Yoon, Suchul;Kim, Minwook;Lee, Seok-Jae
    • Applied Science and Convergence Technology
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    • v.23 no.3
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    • pp.151-159
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    • 2014
  • We investigated the effects of the chemical composition and the relative density on the plastic deformation behavior of sintered Fe-based alloys by means of compressive tests. Overall compressive stresses increased as the amount of alloying elements and the relative density were respectively increased. Addition of alloying elements except for Mo increased the yield stress regardless of the relative density. The relationship between the effects of the chemical composition and the relative density and the mean rate of the stress increase was analyzed. A constitutive equation based on the Ludwik equation with the regressed parameters was proposed to predict the compressive true stress-true strain curves of the sintered Fe-based alloys. The K and n values used in the proposed equation were regressed as a function of the alloying elements and the relative density based on the individual K and n values. The plastic deformation behavior predicted using the proposed constitutive equation showed reliable accuracy compared with experimental data.

The Relative Effects of Human Capital and Social Capital on the Economic Well-being of the Late Middle-aged in Korea (중년기의 경제적 복지에 대한 인적자본과 사회자본의 상대적 효과)

  • Seo, Ji-Won
    • Journal of Families and Better Life
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    • v.26 no.5
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    • pp.315-332
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    • 2008
  • The purpose of this study was to investigate the relative effects of human capital and social capital on the economic well-being of late middle-aged Koreans. The data from the first wave of KLoSA (Korean Longitudinal Study of Aging) aged 50-64 were used (n=4,040). The major findings were as follows: First, human capital and social capital are both resources that can contribute to increasing the economic well-being of the middle-aged. Second, the relative contribution of human capital to the economic well-being of the middle-aged varied by the level of social capital, including formal network and informal network. Third, the relative contribution of social capital to the economic well-being of the middle-aged varied by the level of human capital, including employment type and educational attainment. Based on empirical results, the implications for social investment in human capital and social capital were provided.

QFPR Analysis for Selectivity of between Na+ and Li+ Ions to 12-Crown-4: by a Monte Carlo Simulation Study

  • Kim, Hag-Sung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2823-2829
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    • 2010
  • We investigated the solvent effects on the relative free energies of binding of $Na^+$ and $Li^+$ ions to 12-crown-4 and ${\Delta}log\;K_s$ (the difference of stability constant of binding) by a Monte Carlo simulation of statistical perturbation theory (SPT) in several solvents. Comparing the relative free energies of binding of $Na^+$ and $Li^+$ ions to 12-crown-4, in $CH_3OH$ of this study with experimental works, there is a good agreement among the studies. We have reported the quantitative free energy polarity (of solvent) relationships (QFPR) of the relationship between the relative free energies and solvent polarity studied on the solvent effects on the relative free energies of binding of $Na^+$ and $Li^+$ ions to 12-crown-4.

Effects of relative humidity on comfort sensation by comparison between the young and the aged (여름철 냉방시 상대습도가 쾌적감에 미치는 영향(청년과 고령자의 비교를 중심으로))

  • 김동규;금종수;최광환;박희욱;김종열;주익성
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.4
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    • pp.381-388
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    • 1998
  • Hot and humid weather in summer generally brings about discomfort. Experiments on which relative humidity makes effects on the comfort sensation were performed to the young and the aged using sensation vote. From July to October 1996, seven college students and eleven aged people were exposed for 2 hours under six different conditions in the Pukyong National University test chamber so as to determine the effects of relative humidity on thermal and comfort sensations. Subjects were wearing same clothes, and the mean clo value was 0.5. The mean radiant temperature was equal to the air temperature and air velocity in the occupied zone around 0.lm/s. In the experiments, it was found that discomfort could be largely reduced when the humidity is controlled to low values in the settled high temperature.

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Effects of Storage Environmental Conditions on Weight Loss, Whiteness Change, and Microbial Activity of Mushrooms (Agaricus bisporus)

  • Pai, Tongkun
    • Journal of Applied Biological Chemistry
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    • v.43 no.3
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    • pp.161-164
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    • 2000
  • The effects of storage temperature and high relative humidity (RH) on the weight loss, color change, and microbial activity of a mushroom ('Sylvan' hybrid white) were investigated. The experiment was performed at three temperature (5, 10 and $15^{\circ}C$) and four different relative humidity levels (91, 94, 97 and 99%). The weight loss of the tested samples had a highly correlated linear relationship with storage time at each RH level during storage. Both the storage temperature and RH levels in the experiment had signigicant effects (p<0.05) on the weight-loss rate of the tested samples. The loss whiteness of mushrooms was not significantly affected (p>0.05) by RH ranges at the same temperature. No visible damage was caused by either bacteria or fungi in all samples during storage.

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Dynamic Behaviors of the Simply Supported Bridge System under Seismic Excitations Considering Pounding Effects (충돌을 고려한 지진하중을 받는 교량의 거동특성분석)

  • 김상효
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1999.04a
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    • pp.231-238
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    • 1999
  • The longitudinal dynamic behaviors of the bridge system consisting of multiple simply supported spans under seismic excitations are examined considering pounding effects. The pounding phenomena between adjacent girders which may consequently result in the span collapses are modeled by using the multi-degree-of-freedom system, The inelastic behavior of the RC pier is also considered by adopting the hysteresis loop model and the p-$\delta$ effect. Motions of the foundation and abutment are also considered but the local damage resulting from the girder pounding assumed to be neligible. The developed model is found to give the appropriate information of the dynamic characteristics of the bridge behavior. It is observed that the pounding effect becomes significant as the peak acceleration of the seismic excitation increases. Under minor earthquakes the pounding tends to increase the relative displacements while under strong earthquakes it tends to decrease the relative displacements by restricting the longitudinal girder motions, therefore it is suggested that the pounding effects should be considered in the analysis of the relative displacements of the longitudinally adjacent girder motions.

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A Study on the Complex Effects of Streetscape Components on Visual Preference (도시가로경관요소가 시각적 선호에 미치는 복합적 영향에 관한 연구)

  • 변재상;정수정;임승빈
    • Journal of the Korean Institute of Landscape Architecture
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    • v.27 no.2
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    • pp.9-18
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    • 1999
  • In this study the relative effects among trees, cars, wires and building facades on visual preference are measured with the photo-montage scenes, which were synthesized by computer graphic programs. In addition to these experiments, the interaction of each elements of streetscapes have been investigated. The results of this study can be summarized as follows ; (1) It was found that trees had a remarkable positive effect on preference for streetscapes, wires had a moderate negative effect, cars had a trivial effect and the effects of building facades were medium. (2) It was investigated that the building of residential type was most preferred among commercial, residential, and office building types. The next preferred building facade was the commercial type. (3) The interaction of each element of streetscapes also have effects on preference. Especially, it was found that the combined effects of building-wire and building-cars were more notable than other combined effects of two elements.

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SIMULATION OF RELATIVE MOTION OF FLOATING BODIES INCLUDING EFFECTS OF A FENDER AND A HAWSER (방현재와 계류삭 효과를 고려한 부유체의 상대운동 모사)

  • Shin, Sangmook
    • Journal of computational fluids engineering
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    • v.20 no.1
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    • pp.1-9
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    • 2015
  • A developed code is applied to simulate relative motion of floating bodies in a side-by-side arrangement, including effects of a fender and a hawser. The developed code is based on the flux-difference splitting scheme for immiscible incompressible fluids and the hybrid Cartesian/immersed boundary method. To validate the developed code for free surface flows around deforming boundaries, the water wave generation is simulated, which is caused by bed movement. The computed wave profile and time histories of wave elevation are compared with other experimental and computational results. The effects of a fender and a hawser are modeled by asymmetric force acting on the floating bodies according to a relative displacement with the bounds, in which the fender and the hawser exert no force on the bodies. It has been observed that the floating body can be accelerated by a gap flow due to a phase difference caused by the free surface. Grid independency is established for the computed time history of the body velocity, based on three different size grids.

Effects of Inorganic Aerosols on the Gas-Phase Reactions of the Hydroxyl Radical with Selected Aliphatic Alkanes

  • Oh, Sewon;Andino, Jean M.
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E3
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    • pp.129-136
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    • 2003
  • Effects of inorganic aerosols on the kinetics of the hydroxyl radical reactions with selected aliphatic alkanes have been investigated using the relative rate technique. The relative rates in the absence and presence of aerosols were determined for n-butane, n-pentane, n-hexane, n-octane, and n-decane. P-xylene was used as a reference compound. Inorganic aerosols including (NH$_4$)$_2$SO$_4$, NH$_4$NO$_3$, and NaCl aerosols at two different aerosol concentrations that are typical of polluted urban conditions were tested. Total surface areas of aerosols were 1400 (Condition I) and 3400 $\mu$$m^2$ cm$^{-3}$ (Condition II). Significant changes in the relative rates in the presence of the inorganic aerosols were not observed for the n-butanel/$.$OH, n-pentanel/$.$OH, n-hexanel/$.$OH, n-octanel/$.$OH, and n-decanel/$.$OH reactions versus p-xylenel/$.$OH reaction. These results suggest that the promoting effects depend on the semiconducting property of the aerosols and the nature of the organic compounds.