• Title/Summary/Keyword: relative $_pL^*$-order

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염화에텐의 환원성 탈염소화 모텔을 이용한 수소 경쟁에 대한 평가

  • ;;Y. Yang;P. L. McCarty
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.117-121
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    • 2002
  • A numerical model that describes the reductive dechlorination of tetrachloroethene(PCE) to ethene via cis-dichloroethene(CDCE) was developed. The model included two separated dehalogenator groups : one for PCE transformation to cDCE via TCE and the other for cDCE dehalogenation to ethene via VC, competitive inhibition between different chloroethene electron accepters, and competition for H$_2$ between dechlorination and methanogens. Model simulations suggest first, that PCE dechlorinators are better competitive with methanogens than cDCE dechlorinators. Second, not only the initial relative population size of dehalogenators and H$_2$-utilizing methanogens but also electron donor delivery strategies used greatly affects the degree of dehalogenation. As a result, all of factors in the above must be considered in order to achieve economical and successful bioremediation of contaminated soil and groundwater with chlorinated solvents.

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Competitive Extraction and Trace Analysis of BTEX and MTBE by Solid-Phase Microextraction (SPME) (고체상미량추출법을 이용한 BTEX와 MTBE의 경쟁적 추출효과 및 미량분석에 관한 연구)

  • An, Sang-Woo;Chun, Suk-Young;Lee, Si-Jin;Park, Jae-Woo;Chang, Soon-Woong
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.622-628
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    • 2010
  • In this study, Solid-phase microextraction (SPME) with GC/FID was studied as a possible alternative to liquid-liquid extraction for the analysis of BTEX and MTBE. Experimental parameters affecting the SPME process (such as kind of fibers, adsorption time, desorption time, volume ratio of sample to headspace, salt addition, and magnetic stirring) were optimized. Experimental parameters such as CAR/PDMS, adsorption time of 20 min, desorption time of 5 min at $250^{\circ}C$, headspace volume of 50 mL, sodium chloride (NaCl) concentration of 25% combined with magnetic stirring were selected in optimal experimental conditions for analysis of BTEX and MTBE. The general affinity of analytes to CAR/PDMS fiber was high in the order p-Xylene>Toluene>Ethylbenzene>MTBE>Benzene. The linearity of $R^2$ for BTEX and MTBE was from 0.970 to 0.999 when analyte concentration ranges from $30{\mu}g/L$ to $500{\mu}g/L$, respectively. The relative standard deviation (% RSD) were from 2.5% to 3.2% for concentration of $100{\mu}g/L$ (n=5), respectively. Finally, the limited of detection (LOD) observed in our study for BTEX and MTBE were from $7.5{\mu}g/L$ to $15{\mu}g/L$, respectively.

Herbicidal and Antifungal Activities of the aqueous extracts of Several Naturalized Plants (수종의 귀화식물 수용성추출물의 제초 및 항균 활성 탐색)

  • Hyoun, Do-Gyoung;Song, Jin-Young;Kim, Tae-Keun;Jung, Dae-Cheon;Song, Sang-Churl;Kang, Young-Sik;Cha, Jin-Woo;Lee, Hee-Sean;Yang, Young-Hoan;Kim, Hyoun-Chol;Song, Chang-Khil
    • Korean Journal of Organic Agriculture
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    • v.22 no.2
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    • pp.303-319
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    • 2014
  • The study researched germination of the plants and growth of experimented bacteria according to concentration of water extract in order to provide basic data for developing natural agricultural resources by using naturalized plants including Solidago altissima, Amaranthus retroflexus and Sida spinosa. As concentration of water extract increased, most of test plants showed a decrease in relative germinability. Sida spinosa(r=-0.540, p<0.01), Physalis wrightii(r=-0.693, p<0.01), Amaranthus retroflexu(r=-0.724, p<0.01), Solidago altissima(r=-0.728, p<0.01) and Eclipta prostrata(r=-0.779, p<0.01) showed tendency of decrease in relative germinative power in order, respectively. For average germination period, as concentration of the processed group increased, the time for germination increased (r = 0.769, p<0.01) and according to donor plants and test plants, there was a little difference. Also, as concentration of water extract of donor plant, length of above-aerial part(r=-0.587, p<0.01), length of underground part(r=-0.741, p<0.01), fresh weight(r=-0.574, p<0.01) and generation of root hair decreased. An then, for growth of test fungi according to concentration of water extract of donor plants, growths of Botrytis cinerea(r=-0.266, p<0.05), Diaporthe citri(r=-0.323 p<0.01), Colletotrichum gloeosporioides(r=-0.512, p<0.01), Pythiumultimum(r=-0.581, p<0.01) and Rhizoctonia solani(r=-0.806, p<0.01) were repressed in order, respectively. For total amount of content of phenol with herbicidal and Antifungal activities, S. altissima $17.3{\pm}0.5mg/g$, A. retroflexus $13.1{\pm}0.3mg/g$, P. wrightii $12.0{\pm}0.4mg/g$, S. spinosa $9.5{\pm}0.1mg/g$ and E. prostrata L. $4.1{\pm}0.1mg/g$ showed in order, respectively. As these results are summarized, donor plants which were naturalized, have competitive advantage because they release phenolic compounds with allelopathic effect and affect on germination, growth and fungi growth on underground flora compared to native plants and they have eligibility for natural herbicide and germicide.

Effect of Cultivar and Tedding Frequency on the Quality of Fall Harvest Oat Hay (품종 및 반전횟수가 추계수확 연맥건초의 사료가치에 미치는 영향)

  • 한건준;김동암
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.2
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    • pp.169-176
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    • 1996
  • An experiment was carried out to determine the effect of cultivar and tedding frequency on changes of moisture content of oat(Avena sativa L.) hay during field drying and on quality of baled oat hay after storage. The experimental design was a split-plot with the four oat cultivm such as 'Magnum', 'Cayuse', 'West' and 'Murray' as main plots and the two tedding frequencies such as 1 or 3 times a day as subplots in three replications. Moisture content of fresh cut oat cultivar was higher in the order of 'Magnum', 'Cayuse', 'West', and 'Murray' and the moisture content difference among the cultivm was maintained to the final curing day(P< 0.05). Moisture loss from the oat hay during the last 3 curing days was greater with 3 tedding a day than I tedding a day. Temperature of baled oat hay began to rise critically from the 6th day of storage and wa5 highest in 'Magnum' oat cultivar($45.3^{\circ}C$). Total nitrogen and ADIN contents of late maturing oat hay 'Magnum' and 'Cayuse' were higher than those of early maturing 'Murray' and 'West'. Tedding frequency did not influence total nitrogen and ADIN contents. ADF and NDF contents of early maturing oat hay were higher than those of late maturing oat hay. Relative feed value (RFV) of 'Magnum' oat hay was the highest(l06) and classified as Grade 2 in forage quality standard. Quality grade difference between early and late maturing oat cultivan was only 1 or 2.

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Effects of Seeding Dates on the Growth Characteristics, Dry Matter Yield and Feed Value of Teosinte New Variety, "Geukdong 6" [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis] (파종시기가 테오신트 [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis] 신품종 "극동 6호"의 생육 특성, 수량 및 사료가치에 미치는 영향)

  • Kim, Gyeong Suk;Lee, Sang Moo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.39 no.1
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    • pp.9-16
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    • 2019
  • This study was carried out to investigate the effects of seeding dates and cultivated period on the growth characteristics, dry matter yield and feed value of Teosinte new variety "Geukdong 6"[Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis]for feed. The experimental design was arranged in a randomized block design with three replications. Treatments consisted of five time seeding dates, 10 May(T1), 25 May(T2), 10 June(T3), 25 June(T4) and 10 July(T5), and same time harvesting, 22 October. Therefore, growing period were 164 days(T1), 149 days(T2), 134 days(T3), 119 days(T4) and 103 days(T5), respectively. In growth stage at harvest time, T1, T2, T3, T4 and T5 were early flowering, end heading, middle heading, early heading and early heading stage, respectively. Plant length and dead leaf were highest in T1, but leaf width and number of leaf were highest in T2 than others (p<0.05). Leaf length, stem diameter and number of tiller were not significantly different among the treatments (p<0.05). Stem hardness was higher in order of T1(2.0)> T2(1.9) > T3=T4(1.7) > T5($1.2kg/cm^2$). Fresh yield and dry matter yield showed significantly higher as the sowing time was faster and the cultivation period was longer (T1 > T2 > T3 > T4 > T5, p<0.05). Crude protein, crude fat and TDN content were highest in T5, but ADF and NDF content were highest in T1 than others (p<0.05). T1, T2 and T3 showed significantly higher crude protein yield compared to T4 and T5 (p<0.05). Total digestible nutrients yield were higher in order of T1 > T2 > T3 > T4 > T5 (p<0.05), and relative feed value were higher in order of T5 > T4 > T3 > T2 > T1 (p<0.05). Based on the above results, seeding dates could be recommended from the early May to the late May, and it is efficient that the cultivation period is over 150 days for dry matter yield, crude protein yield and total digestible nutrients yield.

Effect of Cutting Height on the Feed Value and Drying Rate of Rye (Secale cereale L.) Hay

  • Li, Yu Wei;Kim, Jong Geun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.3
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    • pp.201-207
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    • 2017
  • Hay-making is one of the most common forage preservation practices in livestock operations. The objective of hay-making is to minimize nutrient loss by shortening field drying time. Measuring the impacts of cutting height of forage crop is necessary to optimize hay production balancing yield and quality, in order to obtain substantial biomass increase through harvest of regrowth. This experiment was conducted to investigate the impact of cutting height of rye (Secale cereale L.) on drying rate and hay quality. Heading stage rye was harvested at 8cm or 15cm stubble heights. Hay was daily tedded at 09:00 and sampled at 09:00, 13:00 and 17:00 to determine moisture content (MC). After two month of preservation, CP (crude protein), ADF (acid detergent fiber), NDF (neutral detergent fiber), IVDMD (in vitro dry matter disappearance), TDN (total digestible nutrient), RFV (relative feed value), DM (dry matter) loss, visual scores and total fungi count were determined for estimation of hay quality. Cutting height at 15cm could enhance the drying rate and CP content (p<0.05), but also increases DM loss (p<0.05) compared to cutting at 8cm. Cutting heights did not affect ADF, NDF, IVDMD, TDN and RFV value (p>0.05). Visual scores of rye hays cutting at 8cm and 15cm, ranged from 83 to 85. Cutting at 8cm tended to maintain higher core bale temperature and fungal count than cutting at 15cm during preservation, but there was no significant difference.

The Second-order Scattering of the Interaction of Pd Nanoparticles with Protein and Its Analytical Application

  • Guo, Xiaoyan;He, Baolin;Sun, Chuntao;Zhao, Yanxi;Huang, Tao;Liew, Kongyong;Liu, Hanfan
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1746-1750
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    • 2007
  • The second-order scattering (SOS) phenomenon of the interaction of Pd nanoparticles with protein was reported and a simple, sensitive, palladium nanoparticle-based assay for trace amount of protein with SOS technique was developed. The SOS intensities were significantly enhanced due to the interaction of Pd nanoparticles with bovine serum albumin (BSA) or human serum albumin (HSA) at pH 3.5 or 4.0, respectively. The maximum SOS peak appeared at 260/520 nm (λex/λem). The optimal experiment conditions, affecting factors and the influence of some coexisting substances were checked. The SOS intensity increased proportionally with the increase of Pd concentration below 3.0 × 10?5 mol·L?1, while declined gradually above 4.0 × 10?5 mol·L?1. BSA within the range of 0.01-2.6 μg·mL?1 and HSA of 0.01-1.7 μg·mL?1 can be detected with this method and the detection limits were 2.3 and 11.2 ng·mL?1, respectively. The method was successfully applied to the quantitative detection of total protein content in human serum samples with the maximum relative standard deviation (RSD) lower than 2.6% and the recoveries over the range of 99.5-100.5%.

Kinetics of Removing Nitrogenous and Phosphorus Compounds from Swine Waste by Growth of Microalga, Spirulina platensis

  • Kim, Min-Hoe;Chung, Woo-Taek;Lee, Mi-Kyung;Lee, Jun-Yeup;Ohh, Sang-Jip;Lee, Jin-Ha;Park, Don-Hee;Kim, Dong-Jin;Lee, Hyeon-Yong
    • Journal of Microbiology and Biotechnology
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    • v.10 no.4
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    • pp.455-461
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    • 2000
  • Abstract Spirulina platensis was grown in SWlUe waste to reduce inorganic compowlds and simultaneously produce feed resources. Spirulina platensis prefers nitrogenous compounds in Ibe order: $NH_4^{+}-N>NO_3^{-}-N>simple-N$ such as urea and simple amino acids. It even consumes $NH_4^{+}-N$ first when urea or nitrate are present. Therefore, the content of residual $NH_4^{+}-N$ in Spimlina platensis cultures can be determined by the relative extent of the following processes: (i) algal uptake and assimilation; (ii) ammonia stripping; and (iii) decomposition of urea to NH;-N by urease-positive bacteria. The removal rates of total nitrogen ffild total phosphorus were estimated as an indicator of the treatment effIciency. It was found that Spirulina platensis was able to reduce 70-93% of $P_4^{3-}-P$, 67-93% of inorganic nitrogen, 80-90% of COD, and 37-56% of organic nitrogen in various concentrations of swine waste over 12 days of batch cultivation. The removal of inorganic compounds from swine waste was mainly used for cell growth, however, the organic nitrogen removal was not related to cell growlb. A maximum cell density of 1.52 dry-g/l was maintained with a dilution rate of 0.2l/day in continuous cultivation by adding 30% swine waste. The nitrogen and phosphorus removal rates were correlated to the dilution rates. Based on the amino acid profile, the quality of the proteins in the Spirulina platensis grown in the waste was the same as that in a clean culture.ulture.

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Static impedance functions for monopiles supporting offshore wind turbines in nonhomogeneous soils-emphasis on soil/monopile interface characteristics

  • Abed, Younes;Bouzid, Djillali Amar;Bhattacharya, Subhamoy;Aissa, Mohammed H.
    • Earthquakes and Structures
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    • v.10 no.5
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    • pp.1143-1179
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    • 2016
  • Offshore wind turbines are considered as a fundamental part to develop substantial, alternative energy sources. In this highly flexible structures, monopiles are usually used as support foundations. Since the monopiles are large diameter (3.5 to 7 m) deep foundations, they result in extremely stiff short monopiles where the slenderness (length to diameter) may range between 5 and 10. Consequently, their elastic deformation patterns under lateral loading differ from those of small diameter monopiles usually employed for supporting structures in offshore oil and gas industry. For this reason, design recommendations (API and DNV) are not appropriate for designing foundations for offshore wind turbine structures as they have been established on the basis of full-scale load tests on long, slender and flexible piles. Furthermore, as these facilities are very sensitive to rotations and dynamic changes in the soil-pile system, the accurate prediction of monopile head displacement and rotation constitutes a design criterion of paramount importance. In this paper, the Fourier Series Aided Finite Element Method (FSAFEM) is employed for the determination of static impedance functions of monopiles for OWT subjected to horizontal force and/or to an overturning moment, where a non-homogeneous soil profile has been considered. On the basis of an extensive parametric study, and in order to address the problem of head stiffness of short monopiles, approximate analytical formulae are obtained for lateral stiffness $K_L$, rotational stiffness $K_R$ and cross coupling stiffness $K_{LR}$ for both rough and smooth interfaces. Theses expressions which depend only on the values of the monopile slenderness $L/D_p$ rather than the relative soil/monopile rigidity $E_p/E_s$ usually found in the offshore platforms designing codes (DNV code for example) have been incorporated in the expressions of the OWT natural frequency of four wind farm sites. Excellent agreement has been found between the computed and the measured natural frequencies.

Vitamin D intake, Outdoor Activity Time and Serum 25-OH Vitamin D Concentrations of Korean Postmenopausal Women by Season and by Age (폐경 여성의 비타민 D 섭취량, 옥외활동시간, 혈청 25-OH 비타민 D 수준과 계절 및 연령과의 관련성)

  • Yoon, Jin-Sook;Song, Min-Kyoung
    • Korean Journal of Community Nutrition
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    • v.20 no.2
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    • pp.120-128
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    • 2015
  • Objectives: The purpose of this study was to examine the relative impact of seasonal differences and age on dietary vitamin D intakes, outdoor activity time and serum vitamin D status among Korean postmenopausal women. Methods: A cross-sectional study was conducted with 164 free-living postmenopausal women (mean age=55.4 years) in Daegu, Korea. Dietary intake, daily physical activity patterns and fasting blood samples were collected during summer and winter. We compared the results from 75 women during summer and 89 women during winter. Dietary intake of vitamin D was assessed by 24-hour recall method. Daily outdoor activity time was derived from physical activity diary. Results: The average dietary intake of vitamin D of the participants was $3.7{\mu}g$ during summer, $3.3{\mu}g$ during winter, showing no significant difference between the two seasons. The average time spent on outdoor activities was not significantly different between summer ($=35.1{\pm}75.0min/d$) and winter ($=48.5{\pm}76.8min/d$). The average serum 25-(OH) vitamin D concentrations of participants was $17.5{\pm}7.5ng/mL$ in the summer and $13.4{\pm}4.3ng/mL$ in the winter, showing no significant differences by season. Dietary intake of vitamin D was not related to age. When total subjects were divided into two groups by age, the average serum 25-(OH) vitamin D concentration was significantly higher in older group (p=0.047) and time spent on outdoor activities was also (p=0.018) significantly higher in the older group. Conclusions: In order to improve the current vitamin D status of Korean postmenopausal women, nutrition education programs should focus more on adequate intake of vitamin D, while maintaining enough outdoor activities over the season.