• 제목/요약/키워드: regular solution theory

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이항분포의 특정 상호작용을 갖는 이성분 용액에서의 부분혼합도 (Partial Miscibility of Binary Solution with Specific Interaction of Binomial Distribution)

  • 정해영
    • 대한화학회지
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    • 제58권6호
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    • pp.528-534
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    • 2014
  • 어떤 이성분계용액에서는 상한임계용액온도와 하한임계용액온도가 동시에 나타나는 원형모양의 온도-조성 상도를 보인다. 이러한 현상은 분자간 특정상호작용이 존재하는 경우 나타나는 것으로 알려져 있다. 특정상호작용을 묘사하는 방법에는 여러 가지가 있다. 본 연구에서는 특정상호작용의 총수가 이항분포에 따라 분포한다고 가정하였다. 이 경우 특정상호작용을 Regular 용액이론, Quasichemical 이론 그리고 Flory-Huggins 격자이론에 적용하였을 때 원형모양의 온도-조성 상도를 보이는 경우에 대한 정확한 수학적인 조건을 유도하였다. 그리고 매개변수들이 온도-조성상도에 미치는 영향을 조사하였고, 물-니코틴에 대한 온도-조성상도를 계산하여 실험값과 비교하여 보았다.

Use of the Thermodynamic Solution Properties of Xenon in n-Alkanes for the Examination of Models for the Cavity Formation Process

  • Park, Jung-Hag;Brady, James E.;Carr, Peter W.
    • Bulletin of the Korean Chemical Society
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    • 제10권3호
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    • pp.309-314
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    • 1989
  • The interaction energies of Xenon in n-alkanes were estimated by using three models for the cavity formation process, Hildebrand's regular solution theory, Pierotti's scaled particle theory and Sinanoglu-Reiss-Moura-Ramos' solvophobic theory in an attempt to examine the validity of three models. It appears that Pierotti's implementation of scaled particle theory yields a reasonable estimate of cavity formation energy over a considerable range in solvent size provided that the solute is spherical enough as are the inert gases.

Computational Investigation of Seakeeping Performance of a Surfaced Submarine in Regular Waves

  • Jung, Doojin;Kim, Sanghyun
    • 한국해양공학회지
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    • 제36권5호
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    • pp.303-312
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    • 2022
  • A submarine is optimized to operate below the water surface because it spends most of its time in a submerged condition. However, the performance in free surface conditions is also important because it is unavoidable for port departure and arrival. Generally, potential flow theory is used for seakeeping analysis of a surface ship and is known for excellent numerical accuracy. In the case of a submarine, the accuracy of potential theory is high underwater but is low in free surface conditions because of the nonlinearity near the free surface area. In this study, the seakeeping performance of a Canadian Victoria Class submarine in regular waves was investigated to improve the numerical accuracy in free surface conditions by using computational fluid dynamics (CFD). The results were compared to those of model tests. In addition, the potential theory software Hydrostar developed by Bureau Veritas was also used for seakeeping performance to compare with CFD results. From the calculation results, it was found that the seakeeping analysis by using CFD gives good results compared with those of potential theory. In conclusion, seakeeping analysis based on CFD can be a good solution for estimating the seakeeping performance of submarines in free surface conditions.

OPTIMAL IMPULSE AND REGULAR CONTROL STRATEGIES FOR PROPORTIONAL REINSURANCE PROBLEM

  • RUI-CHENG YANG;KUN-HUI LIU;BING XIA
    • Journal of applied mathematics & informatics
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    • 제18권1_2호
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    • pp.145-158
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    • 2005
  • We formulate a stochastic control problem on proportional reinsurance that includes impulse and regular control strategies. For the first time we combine impulse control with regular control, and derive the expected total discount pay-out (return function) from present to bankruptcy. By relying on both stochastic calculus and the classical theory of impulse and regular controls, we state a set of sufficient conditions for its solution in terms of optimal return function. Moreover, we also derive its explicit form and corresponding impulse and regular control strategies.

음이온/비이온 계면활성제의 미셀상승 효과 (Synergistic Effect of Mixed Anionic/Nonionic Surfactant Micelles)

  • 권순일;곽광수;남기대
    • 한국응용과학기술학회지
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    • 제18권4호
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    • pp.249-253
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    • 2001
  • A proposed method of determining the composition of mixed micelles in equilibrium with monomer of known composition is described. The systems were sodium ${\alpha}-sulfonated$ dodecanoyl ethyl esther (${\alpha}-SR_{12}Et$) or sodium dodecyl sulfate(SDS)-polyoxyethylene 23 lauryl ether (Brij 35) un water and in 0.1M sodium chloride solution at $25^{\circ}C$. This technique applies the Gibbs-Duhem equation to the mixed micelles, which is treated as a pseudophase. This proposed methodology, which needs only critical micelle concentration data as a function of monomer composition, is applied to an anionic/nonionic surfactant pair. The calculated monomer-micelle equilibrium is found to be very similar to the much-used regular solution for nonideal systems.

3차원 조파수조에서 바닥 조파장치에 의해 재현된 규칙파에 대한 해석적 연구 (An Analytical Study of Regular Waves Generated by Bottom Wave Makers in a 3-Dimensional Wave Basin)

  • 정재상;이창훈
    • 한국해안·해양공학회논문집
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    • 제34권4호
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    • pp.93-99
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    • 2022
  • 본 연구에서는 바닥 조파장치가 설치된 3차원 조파수조에서 재현된 규칙파에 대한 해석해를 유도하였다. 바닥 조파장치로 삼각형 형상, 사각형 형상 및 두 형상이 복합된 형상이 적용되었다. 선형파 이론과 움직이는 바닥에 대한 경계조건, 동역학적 및 운동학적 자유수면 경계조건을 이용하여 조파수조 내의 3차원 속도포텐셜을 유도하였다. 그리고, 이로부터 각 방향 성분의 유속과 자유수면변위에 대한 해석해를 구하였다. 유도된 해석해는 바닥 조파장치가 설치된 조파수조에서 규칙파의 전파 특성에 대해 물리적으로 타당한 결과를 보였다. 바닥 조파장치가 snake 형태로 움직이는 경우의 비스듬히 전파하는 파랑의 조파에 대해서도 해석해를 유도하였으며, 해석 결과는 이론적으로 예측한 결과와 일치하였다.

복식사 연구 방법에 있어서 양식 및 그 변화에 관한 연구 (A New Perspective on style and its change in the historical Met-hodology on Dress.)

  • 최윤미;김민자
    • 복식
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    • 제20권
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    • pp.63-72
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    • 1993
  • The concept of style provides a useful structure in history of Art. In aspect of formative art, dress and art work are alike, so style is a useful concept in the historical methodology on dress. The main purpose of this study was to apply the art criticism to the historical methodology on dress. For this purpose, documentary studies about style as a tool of historical research were proceeded. The results were as follows : 1. The concept of style consists of the external form and the internal meaning as double roots. Therefore, it's indispensable that the two asp-ects of style, form and meaning, must to be harmonized to describe the historical phenomena in dress. 2. The change pattern of style in dress is not always predeterminate and regular according to the cyclical theory. From the alternative point of view, the change pattern of style could be to describe the continuous theory proposed by kroeber, Brodsky. The whole change of style is considered "liked solution" by this theory.is theory.

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바닥 조파장치가 설치된 수로에서 규칙파의 유속장에 관한 해석해 개발 (Development of Analytical Solutions on Velocities of Regular Waves Generated by Bottom Wave Makers in a Flume)

  • 정재상;이창훈
    • 한국해안·해양공학회논문집
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    • 제34권3호
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    • pp.58-71
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    • 2022
  • 본 연구에서는 바닥 조파장치가 설치된 수로에서 재현된 규칙파의 2차원 유속장에 대한 해석해를 유도하였다. 바닥 조파장치로 삼각형 및 사각형 형상이 적용되었다. 선형파 이론과 움직이는 바닥에 대한 경계조건, 동역학적 및 운동학적 자유수면 경계조건을 이용하여 속도포텐셜을 유도하였으며, 이로부터 각 방향 성분의 유속에 대한 해석해를 구하였다. 적분식 형태로 유도된 속도포텐셜 및 유속에 대한 해석해를 수치해석으로 계산하였다. 유도된 해석해는 바닥 조파장치가 설치된 조파수로에서 규칙파의 유속 특성에 대해 물리적으로 타당한 결과를 보였다.

Development of a Secure Routing Protocol using Game Theory Model in Mobile Ad Hoc Networks

  • Paramasivan, Balasubramanian;Viju Prakash, Maria Johan;Kaliappan, Madasamy
    • Journal of Communications and Networks
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    • 제17권1호
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    • pp.75-83
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    • 2015
  • In mobile ad-hoc networks (MANETs), nodes are mobile in nature. Collaboration between mobile nodes is more significant in MANETs, which have as their greatest challenges vulnerabilities to various security attacks and an inability to operate securely while preserving its resources and performing secure routing among nodes. Therefore, it is essential to develop an effective secure routing protocol to protect the nodes from anonymous behaviors. Currently, game theory is a tool that analyzes, formulates and solves selfishness issues. It is seldom applied to detect malicious behavior in networks. It deals, instead, with the strategic and rational behavior of each node. In our study,we used the dynamic Bayesian signaling game to analyze the strategy profile for regular and malicious nodes. This game also revealed the best actions of individual strategies for each node. Perfect Bayesian equilibrium (PBE) provides a prominent solution for signaling games to solve incomplete information by combining strategies and payoff of players that constitute equilibrium. Using PBE strategies of nodes are private information of regular and malicious nodes. Regular nodes should be cooperative during routing and update their payoff, while malicious nodes take sophisticated risks by evaluating their risk of being identified to decide when to decline. This approach minimizes the utility of malicious nodes and it motivates better cooperation between nodes by using the reputation system. Regular nodes monitor continuously to evaluate their neighbors using belief updating systems of the Bayes rule.

정현파중에서의 잠수된 원형실린더의 비선형 운동에 관한 연구 (A Study on Nonlinear Motions of Submerged Circular Cylinder in Regular Wave)

  • 이호영;황종흘
    • 대한조선학회논문집
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    • 제35권1호
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    • pp.32-39
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    • 1998
  • 잠수된 원형실린더의 대진폭운동에 대한 수치해석이 제시된다. 방법은 포텐셜이론에 근간을 두고 정현파중에서 2차원 운동은 초기치 문제로 귀결된다. 완전한 비선형자유표면 조건은 수치 계산영역에서 적용되고, 비선형 수치해는 수치계산의 임의의 가정된 경계를 따라 외부영역에서의 선형해로서 부과된다. 잠수된 원형실린더의 대진폭운동의 계산은 직접적으로 시간영역에서 시뮬레이션된다. 계산결과로 부터 물체와 유체입자의 상호 운동은 부양운동과 표류운동에 중요한 효과를 준다.

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